Tricarbonylchlorido(6'7'-dihydro-5’H-spiro[cyclopentane-1,6'-dipyrido-[3,2-d:2',3'-f][1,3]diazepine]-κ2N1,N11)-rhenium(I)

In the title compound, [ReCl(C15H16N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclopentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (001)

Radiometric responsivity determination for Feature Identification and Location Experiment (FILE) flown on space shuttle mission

A procedure was developed to obtain the radiometric (radiance) responsivity of the Feature Identification and Local Experiment (FILE) instrument in preparation for its flight on Space Shuttle Mission 41-G (November 1984). This instrument was designed to obtain Earth feature radiance data in spectral bands centered at 0.65 and 0.85 microns, along with corroborative color and color-infrared photographs, and to collect data to evaluate a technique for in-orbit autonomous classification of the Earth's primary features. The calibration process incorporated both solar radiance measurements and radiative transfer model predictions in estimating expected radiance inputs to the FILE on the Shuttle. The measured data are compared with the model predictions, and the differences observed are discussed. Application of the calibration procedure to the FILE over an 18-month period indicated a constant responsivity characteristic. This report documents the calibration procedure and the associated radiometric measurements and predictions that were part of the instrument preparation for flight

Tricarbonylchlorido(6’,7’-dihydro-5’H-spiro[cyclohexane-1,6’-dipyrido[3,2-d :2’,3’-f][1,3]diazepine]-κ2N1,N11)rhenium(I)

In the title compound, [ReCl(C16H18N4)(CO)3], the ReI ion is coordinated in a distorted octahedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclohexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H...Cl hydrogen bonds link complex molecules, forming a two-dimensional network parallel to (100)

System analysis approach to deriving design criteria (loads) for Space Shuttle and its payloads. Volume 1: General statement of approach

Space shuttle, the most complex transportation system designed to date, illustrates the requirement for an analysis approach that considers all major disciplines simultaneously. Its unique cross coupling and high sensitivity to aerodynamic uncertainties and high performance requirements dictated a less conservative approach than those taken in programs. Analyses performed for the space shuttle and certain payloads, Space Telescope and Spacelab, are used a examples. These illustrate the requirements for system analysis approaches and criteria, including dynamic modeling requirements, test requirements control requirements and the resulting design verification approaches. A survey of the problem, potential approaches available as solutions, implications for future systems, and projected technology development areas are addressed

System analysis approach to deriving design criteria (Loads) for Space Shuttle and its payloads. Volume 2: Typical examples

The achievement of an optimized design from the system standpoint under the low cost, high risk constraints of the present day environment was analyzed. Space Shuttle illustrates the requirement for an analysis approach that considers all major disciplines (coupling between structures control, propulsion, thermal, aeroelastic, and performance), simultaneously. The Space Shuttle and certain payloads, Space Telescope and Spacelab, are examined. The requirements for system analysis approaches and criteria, including dynamic modeling requirements, test requirements, control requirements, and the resulting design verification approaches are illustrated. A survey of the problem, potential approaches available as solutions, implications for future systems, and projected technology development areas are addressed

Efficient decomposition of quantum gates

Optimal implementation of quantum gates is crucial for designing a quantum computer. We consider the matrix representation of an arbitrary multiqubit gate. By ordering the basis vectors using the Gray code, we construct the quantum circuit which is optimal in the sense of fully controlled single-qubit gates and yet is equivalent with the multiqubit gate. In the second step of the optimization, superfluous control bits are eliminated, which eventually results in a smaller total number of the elementary gates. In our scheme the number of controlled NOT gates is $O(4^n)$ which coincides with the theoretical lower bound.Comment: 4 pages, 2 figure

Hybrid Reactions to Phytotoxic Effects of The Corn Herbicide, Eradicane Extra

Although corn hybrids are primarily evaluated only for yield performance in the Kentucky Hybrid Corn Performance Test, the 1984 test (Poneleit and Evans, 1985) provided a unique opportunity to evaluate hybrid reactions to an unusual hybrid-herbicide interacting Of seven non-virus test locations, four were treated with Eradicane Extra or Eradicane for weed control. At the Princeton location Eradicane Extra, at 8 pints/acre, was used for johnsongrass rhizome suppression and seedling control. In late July, a routine check revealed that numerous plants had unusual appearances that were similar to abnormalities reported earlier as caused by Eptam and Eradicane (Poneleit et aI, 1975). Subsequent observations confirmed the severity of damage at the Princeton test site and reports of similar hybrid reactions from farmer fields prompted the collection of apparent herbicide damage data from the replicated Princeton test. The other performance test sites where Eradicane Extra or Eradicane was applied did not show significant plant abnormalities. Apparently the appearance of phytotoxic effects owing to Eradicane Extra are sporadic and strongly influenced by specific interaction of environmental factors. It was postulated that this injury occurrence in 1984 was the result of excessive rainfall four to six weeks after planting. Dichlormid (safener) is very water soluble and could have been leached away from the corn roots, and thus not available to protect the corn from EPTC

Redefining the Missing Satellites Problem

Numerical simulations of Milky-Way size Cold Dark Matter (CDM) halos predict a steeply rising mass function of small dark matter subhalos and a substructure count that greatly outnumbers the observed satellites of the Milky Way. Several proposed explanations exist, but detailed comparison between theory and observation in terms of the maximum circular velocity (Vmax) of the subhalos is hampered by the fact that Vmax for satellite halos is poorly constrained. We present comprehensive mass models for the well-known Milky Way dwarf satellites, and derive likelihood functions to show that their masses within 0.6 kpc (M_0.6) are strongly constrained by the present data. We show that the M_0.6 mass function of luminous satellite halos is flat between ~ 10^7 and 10^8 M_\odot. We use the ``Via Lactea'' N-body simulation to show that the M_0.6 mass function of CDM subhalos is steeply rising over this range. We rule out the hypothesis that the 11 well-known satellites of the Milky Way are hosted by the 11 most massive subhalos. We show that models where the brightest satellites correspond to the earliest forming subhalos or the most massive accreted objects both reproduce the observed mass function. A similar analysis with the newly-discovered dwarf satellites will further test these scenarios and provide powerful constraints on the CDM small-scale power spectrum and warm dark matter models.Comment: 8 pages, 6 figure