4 research outputs found

    Pasantía internacional Universidad Nacional Autónoma de México 2016

    Get PDF
    CD-T 624.25 O1; 49 pLa presente investigación científica hace referencia a un proyecto ejecutado en el municipio de Pereira, Risaralda; el cual tuvo como Objetivo principal, realizar un diagnóstico de las patologías y posibles mecanismos de falla que se presentan, actualmente, en el puente de concreto ubicado en la vía que comunica los barrios Pedregales y Parque Industrial de este municipio. La Metodología empleada fue de tipo Cuantitativo con visitas de campo y registro fotográfico en diferentes zonas y perspectivas del puente. Los Resultados mostraron un deterioro significativo en la estructura de concreto, que se agrava con el pasar de los días, el tráfico habitual y las condiciones medio ambientales de la zona. Las principales Conclusiones del estudio determinaron una intervención inmediata del puente; así como una correcta canalización del nacimiento de agua cercano, debido a que el afluente permanente de lixiviados genera daño irreparable y debilitamiento en la estructura, con evidencia en las eflorescencias.Universidad Libre Seccional Pereir

    Degradation of hexacyanoferrate (III) ion by the coupling of the ultraviolet light and the activation of persulfate at basic pH

    Get PDF
    The ultraviolet light activation of persulfate (PS) under alkaline conditions was evaluated for treating hexacyanoferrate (III) ion ([Fe(CN)6]3-). The effect of the wavelength type (i.e., UVA and UVC), initial PS concentration (0.3, 0.6, and 0.9 g L−1), and pH value (11 and 13) on the degradation of 50 mg L−1 of [Fe(CN)6]3- were studied. Finally, the role of the main degrading agents (SO4•-, O2•-, or HO•) involved in the degradation process was determined using scavengers and a degradation pathway for [Fe(CN)6]3- was proposed. Results show that [Fe(CN)6]3- can be decomposed by UVC light, while UVA is not effective neither in [Fe(CN)6]3- photolysis nor in the activation of PS. Alkaline activation alone at pH 13 can also not degrade the cyanocomplex. However, the combination of UVC with PS (0.3 g L−1) at pH 13 showed high efficiency in the elimination of [Fe(CN)6]3-, achieving 93.3% of removal after 125 min of treatment. The highest CN- release and Fe dissolved removal also occurs at pH 13 and 0.3 g L−1 PS. Further increases in initial PS concentrations may lead to an excess of radicals in solution, resulting in detrimental recombination reactions that affect the efficiency of the process. Quenching tests showed that the importance of radicals involved in the degradation of [Fe(CN)6]3- follows the order: HO• > O2•- >>> 1O2 or SO4•-, and allowed to demonstrate that singlet oxygen could participate in the UVC photolysis of [Fe(CN)6]3-. All these results suggest the feasibility of this technology to treat this type of industrial wastewater efficiently

    Evolution over Time of Ventilatory Management and Outcome of Patients with Neurologic Disease∗

    No full text
    OBJECTIVES: To describe the changes in ventilator management over time in patients with neurologic disease at ICU admission and to estimate factors associated with 28-day hospital mortality. DESIGN: Secondary analysis of three prospective, observational, multicenter studies. SETTING: Cohort studies conducted in 2004, 2010, and 2016. PATIENTS: Adult patients who received mechanical ventilation for more than 12 hours. INTERVENTIONS: None. MEASUREMENTS AND MAIN RESULTS: Among the 20,929 patients enrolled, we included 4,152 (20%) mechanically ventilated patients due to different neurologic diseases. Hemorrhagic stroke and brain trauma were the most common pathologies associated with the need for mechanical ventilation. Although volume-cycled ventilation remained the preferred ventilation mode, there was a significant (p < 0.001) increment in the use of pressure support ventilation. The proportion of patients receiving a protective lung ventilation strategy was increased over time: 47% in 2004, 63% in 2010, and 65% in 2016 (p < 0.001), as well as the duration of protective ventilation strategies: 406 days per 1,000 mechanical ventilation days in 2004, 523 days per 1,000 mechanical ventilation days in 2010, and 585 days per 1,000 mechanical ventilation days in 2016 (p < 0.001). There were no differences in the length of stay in the ICU, mortality in the ICU, and mortality in hospital from 2004 to 2016. Independent risk factors for 28-day mortality were age greater than 75 years, Simplified Acute Physiology Score II greater than 50, the occurrence of organ dysfunction within first 48 hours after brain injury, and specific neurologic diseases such as hemorrhagic stroke, ischemic stroke, and brain trauma. CONCLUSIONS: More lung-protective ventilatory strategies have been implemented over years in neurologic patients with no effect on pulmonary complications or on survival. We found several prognostic factors on mortality such as advanced age, the severity of the disease, organ dysfunctions, and the etiology of neurologic disease
    corecore