Kinetic Investigation of Polyurethane Rubber Formation from CO2‐Containing Polyols

A novel CO2 utilization technology allows for the inclusion of CO2 as carbonate units and double bond moieties to give additional functionality in polyether polyols. This study examines the chain‐elongation kinetics of these diols with diisocyanates to polyurethane rubbers by means of thermal analysis. A reaction order of 1 indicates a strong influence of the chains' mobility on the reaction rate. Spectrometry and comparison with non‐double‐bond polyols reveal that the effect cannot be attributed to a substantial occurrence of side reactions but is rather due to the intertwining of lengthy chains.BMBF, 033R350A‐D, Production DreamsTU Berlin, Open-Access-Mittel - 202

Oncological impact of perioperative blood transfusion in bladder cancer patients undergoing radical cystectomy: Do we need to consider storage time of blood units, donor age, or gender matching?

Background The oncological impact of perioperative blood transfusions (PBTs) of patients undergoing radical cystectomy (RC) because of bladder cancer (BCa) has been a controversial topic discussed in recent years. The main cause for the contradictory findings of existing studies might be the missing consideration of the storage time of red blood cell units (BUs), donor age, and gender matching. Study Design and Methods We retrospectively analyzed BCa patients who underwent RC in our department between 2004 and 2021. We excluded patients receiving BUs before RC, >10 BUs, or RC in a palliative setting. We assessed the effect of blood donor characteristics and storage time on overall survival (OS) and cancer-specific survival (CSS) through univariate and multivariable Cox regression analysis. We also performed a propensity score matching with patients who received BUs and patients who did not on a 1:1 ratio. Results We screened 1692 patients and included 676 patients for the propensity score matching. In the multivariable analysis, PBT was independently associated with worse OS and CSS (p < .001). Postoperative transfusions were associated with better OS (p = .004) and CSS (p = .008) compared to intraoperative or mixed transfusions. However, there was no influence of blood donor age, storage time, or gender matching on prognosis. Discussion In our study of BCa patients undergoing RC, we demonstrate that PBT, especially if administered intraoperatively, is an independent risk factor for a worse prognosis. However, storage time, donor age, or gender matching did not negatively affect oncological outcomes. Therefore, the specific selection of blood products does not promise any benefits

Techno-Economic Assessment & Life-Cycle Assessment Guidelines for CO2 Utilization

NOTE: Updated version 1.1 available at http://hdl.handle.net/2027.42/162573 Climate change is one of the largest challenges of our time. One of the major causes of anthropogenic climate change, carbon dioxide, also leads to ocean acidification. Left unaddressed, these two challenges will alter ecosystems and fundamentally change life, as we know it. Under the auspices of the UN Framework Convention on Climate Change and through the Paris Agreement, there is a commitment to keep global temperature increase to well below two degrees Celsius. This will require a variety of strategies including increased renewable power generation and broad scale electrification, increased energy efficiency, and carbon-negative technologies. We believe that Life Cycle Assessment (LCA) is necessary to prove that a technology could contribute to the mitigation of environmental impacts and that Techno-Economic Assessment (TEA) will show how the technology could be competitively delivered in the market. Together the guidelines for LCA and TEA that are presented in this document are a valuable toolkit for promoting carbon capture and utilization (CCU) technology development.Development of standardized CO2 Life Cycle and Techno-economic Assessment Guidelines was commissioned by CO2 Sciences, Inc., with the support of 3M, EIT Climate-KIC, CO2 Value Europe, Emissions Reduction Alberta, Grantham Foundation for the Protection of the Environment, R. K. Mellon Foundation, Cynthia and George Mitchell Foundation, National Institute of Clean and Low Carbon Energy, Praxair, Inc., XPRIZE and generous individuals who are committed to action to address climate change.https://deepblue.lib.umich.edu/bitstream/2027.42/145436/3/Global_CO2_Initiative_TEA_LCA_Guidelines-2018.pdf-

Methanol Worked Examples for the TEA and LCA Guidelines for CO2 Utilization

This document contains worked examples of how to apply the accompanying “Guideline for Techno-Economic Assessment of CO2 Utilization” and “Guideline for Life Cycle Assessment of CO2 Utilization”. The Guidelines can be downloaded via http://hdl.handle.net/2027.42/145436. These worked examples are not intended to be a definitive TEA or LCA report on the process described, but are provided as supporting material to show how the TEA and LCA methodologies described in the guidelines can be specifically applied to tackle the issues surrounding CO2 utilization. This document describes techno-economic assessment and life cycle assessment for methanol production. As methanol production via hydrogenation and PEM electrolysis of water to produce hydrogen are both at high technology readiness levels (TRL7+); a CO2 capture technology currently at a lower TRL (membrane separation at TRL3 or 4) was selected to demonstrate the differences that can be observed in the interpretation phase when working on TEA and LCA studies of processes with lower TRLs. It is acknowledged that there are many unknown variables with membrane capture, and it is not within the remit of this work to draw conclusions on their application. However, it is known that organizations wish to conduct TEA and LCA studies across a range of TRLs and therefore we hope to demonstrate here how this could affect the results. This document is one of several application examples that accompany the parent document “Techno-Economic Assessment & Life-Cycle Assessment Guidelines for CO2 Utilization”.Development of standardized CO2 Life Cycle and Techno-economic Assessment Guidelines was commissioned by CO2 Sciences, Inc., with the support of 3M, EIT Climate-KIC, CO2 Value Europe, Emissions Reduction Alberta, Grantham Foundation for the Protection of the Environment, R. K. Mellon Foundation, Cynthia and George Mitchell Foundation, National Institute of Clean and Low Carbon Energy, Praxair, Inc., XPRIZE and generous individuals who are committed to action to address climate change.https://deepblue.lib.umich.edu/bitstream/2027.42/145723/5/Global CO2 Initiative Complete Methanol Study 2018.pd

The eROSITA extragalactic CalPV serendipitous catalog

Context. The eROSITA X-ray telescope on board the Spectrum-Roentgen-Gamma (SRG) observatory performed calibration and performance verification (CalPV) observations between September 2019 and December 2019, ahead of the planned 4-yr all-sky surveys. Most of them were deep, pointing-mode observations. Aims. We present here the X-ray catalog detected from the set of extra-galactic CalPV observations released to the public by the German eROSITA consortium, and the multiband counterparts of these X-ray sources. Methods. We developed a source detection method optimized for point-like X-ray sources by including extended X-ray emission in the background measurement. The multiband counterparts were identified using a Bayesian method from the CatWISE catalog. Results. Combining 11 CalPV fields, we present a catalog containing 9515 X-ray sources, whose X-ray fluxes were measured through spectral fitting. CatWISE counterparts are presented for 77% of the sources. Significant variabilities are found in 99 of the sources, which are also presented with this paper. Most of these fields show similar number counts of point sources as typical extragalactic fields, and a few harbor particular stellar populations

Techno-Economic Assessment & Life Cycle Assessment Guidelines for CO2 Utilization (Version 1.1)

Climate change is one of the greatest challenges of our time. Under the auspices of the UN Framework Convention on Climate Change and through the Paris Agreement, there is a commitment to keep global temperature rise this century to well below two degrees Celsius compared with pre-industrial levels. This will require a variety of strategies, including increased renewable power generation, broad-scale electrification, greater energy efficiency, and carbon-negative technologies. With increasing support worldwide, innovations in carbon capture and utilization (CCU) technologies are now widely acknowledged to contribute to achieving climate mitigation targets while creating economic opportunities. To assess the environmental impacts and commercial competitiveness of these innovations, Life Cycle Assessment (LCA) and Techno-Economic Assessment (TEA) are needed. Against this background, guidelines (Version 1.0) on LCA and TEA were published in 2018 as a valuable toolkit for evaluating CCU technology development. Ever since, an open community of practitioners, commissioners, and users of such assessments has been involved in gathering feedback on the initial document. That feedback has informed the improvements incorporated in this updated Version 1.1 of the Guidelines. The revisions take into account recent publications in this evolving field of research; correct minor inconsistencies and errors; and provide better alignment of TEA with LCA. Compared to Version 1.0, some sections have been restructured to be more reader-friendly, and the specific guideline recommendations are renamed ‘provisions.’ Based on the feedback, these provisions have been revised and expanded to be more instructive.Global CO2 Initiative at the University of MichiganEIT Climate-KIChttp://deepblue.lib.umich.edu/bitstream/2027.42/162573/5/TEA&LCA Guidelines for CO2 Utilization v1.1.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/162573/7/ESI reference scenario data_Corrected.xlsxSEL

Woyzeck

Exposición gráfica y audiovisual "La Permanencia de lo efímero. Testimonio Documental del Teatro en la Universidad de AntioquiaACTORES: Faber Londoño; Jorge Blandón; Nelson Pérez; Oscar Salazar; Carlos Zapata; Chinca Jiménez; Argenis Mesa; Elkín Holguín. ASISTENTE DE DIRECCIÓN: Olga Osori