Reaction Textures and Metamorphic Evolution of Sapphirine-bearing Granulites from the Gruf Complex, Italian Central Alps

Mineral chemistries and textures are described from a suite of sapphirine-bearing granulites from the Gruf Complex of the Italian Central Alps. The granulites contain combinations of garnet, orthopyroxene, sapphirine, sillimanite, cordierite, biotite, quartz, spinel, corundum, staurolite, plagioclase, K-feldspar, ilmenite and rutile, in assemblages with low (usually negative) variance. They are outstanding in that they preserve a textural and chemical record of a protracted metamorphic evolution. Reaction textures are common and include: (i) pseudomorphs (e.g. of sillimanite after kyanite); (ii) relatively coarse-grained monomineralic reaction rims (e.g. of cordierite between sapphirine and quartz); (iii) fine-grained symplectitic coronas (e.g. of orthopyroxene + sapphirine round garnet); (iv) inclusions, in garnet cores, of minerals (e.g. staurolite) not found elsewhere in the rocks. Detailed microprobe study has revealed large chemical variations within each phase. Different textural types of each phase have different compositions, and strong zoning is preserved in garnet (Mg/(Mg + Fe) from 0.30 to 0.61) and coarse sapphirine. Inclusion populations in garnet correlate with host composition. The textural and chemical features are interpreted in terms of successive equilibrium assemblages and reactions. Metamorphic conditions operative at each stage in the evolution are calculated using published geothermometers and geobarometers as well as thermodynamically calibrated MAS and FASH equilibria. The results are used to construct a P—T-time path for the sapphirine-granulites, which can be summarized as follows: (i) Increasing T at high P (>7 kb). Partial melting. (ii) A maximum T of ∼830 °C attained at ∼10 kb. (iii) Almost isothermal decompression, reaching 750 °C at ∼5 kb, under conditions of low μH2O. (iv) Further cooling, and decompression. Localized hydration. Rocks exposed. The P—T-time path is interpreted as the product of a single metamorphic cycle (the tertiary ‘Lepontine' event) and is extrapolated to the Gruf Complex as a whole. When combined with published geochronological data, the results indicate an average uplift rate in excess of 2 mm/yr for the Gruf Complex between 38 and 30 Ma ago. An in situ partial melting origin for the sapphirine-granulites is favoured. Extraction of an iron-rich granitic liquid from a normal pelitic palaeosome could generate a refractory residue with the required Mg, Al-rich composition. The change in bulk solid composition during partial melting is thought to account for the extraordinarity strong zoning in the garnet

Hybrid dialog: Dialogic learning in large lecture classes

Attendance at classical lectures usually leads to rather poor learning success. A wide variety of studies show that while lectures are as effective as any other method for transmitting information, they are inferior in many other dimensions. Lectures are not as effective as discussion methods in promoting thought and they are ineffective at teaching behavioral skills and subject-related values as well as at awakening interest in a subject. Still ex-cathedra teaching is a favored way to cope with a high student-to-teacher ratio. To solve this conflict between organizational and pedagogical requirements, a group of researchers at the Institute of Teacher Education at the University of Zurich has developed a hybrid course setting using an online learning platform. Their setting incorporates a dialog among students within a large lecture class. Furthermore a feedback loop enables the lecturer to continuously adjust the content of the lecture to the learning process of the students. In this article, the authors first present the structure of this setting and then illustrate how to implement it by the web-based open source learning management system OLAT (Online Learning and Training). Based on their research, they focus on key components for the success of their hybrid dialog. They show how individual and group learning can be fostered with corresponding assignments, assessments, and assigned roles such as moderators. Thus, the authors will define their position that the challenge of a large lecture class can be met while successfully implementing social learning and process-oriented assessments of academic achievement

The fake food buffet - a new method in nutrition behaviour research

Experimental research in behavioural nutrition is often limited by practical applicability. In the present study, we assess the reproducibility and validity of a new experimental method using food replicas. A total of fifty-seven people were invited on two separate occasions with an interval of 2 weeks to serve themselves a meal from a fake food buffet (FFB) containing replica carrots, beans, pasta and chicken. The external validity of the FFB was assessed in a second study by comparing meals served from replica foods (beans, pasta, chicken) with meals served from a corresponding real food buffet (RFB). For the second study, forty-eight participants were invited on two separate occasions; first to serve themselves a meal from the FFB or an RFB and 2 weeks later from the other buffet. The amounts of food items served and (theoretical) energy content were compared. Correlation coefficients between the amounts of fake foods served were 0·77 (95% CI 0·68, 0·86) for chicken, 0·79 (95% CI 0·68, 0·87) for carrots, 0·81 (95% CI 0·69, 0·89) for beans and 0·89 (95% CI 0·82, 0·93) for pasta. For the FFB meal and the RFB meal, the correlations ranged between 0·76 (95% CI 0·73, 0·91) for chicken and 0·87 (95% CI 0·77, 0·92) for beans. The theoretical energy of the fake meal was 132kJ (32kcal) lower compared to the energy of the real meal. Results suggest that the FFB can be a valuable tool for the experimental assessment of relative effects of environmental influences on portion sizes and food choice under well-controlled condition

Self Excitation of the Tunneling Scalar Field in False Vacuum Decay

A method to determine the quantum state of a scalar field after $O(4)$-symmetric bubble nucleation has been developed recently. The method has an advantage that it concisely gives us a clear picture of the resultant quantum state. In particular, one may interpret the excitations as a particle creation phenomenon just as in the case of particle creation in curved spacetime. As an application, we investigate in detail the spectrum of quantum excitations of the tunneling field when it undergoes false vacuum decay. We consider a tunneling potential which is piece-wise quadratic, hence is simple enough to allow us an analytical treatment. We find a strong dependence of the excitation spectrum upon the shape of the potential on the true vacuum side. We then discuss features of the excitation spectrum common to general tunneling potentials not restricted to our simple model.Comment: 24 pages, uuencoded compressed postscript fil

Gravity Waves from Instantons

We perform a first principles computation of the spectrum of gravity waves produced in open inflationary universes. The background spacetime is taken to be the continuation of an instanton saddle point of the Euclidean no boundary path integral. The two-point tensor correlator is computed directly from the path integral and is shown to be unique and well behaved in the infrared. We discuss the tensor contribution to the cosmic microwave background anisotropy and show how it may provide an observational discriminant between different types of primordial instantons.Comment: 19 pages, RevTex file, including two postscript figure file

Quantized gravitational waves in the Milne universe

The quantization of gravitational waves in the Milne universe is discussed. The relation between positive frequency functions of the gravitational waves in the Milne universe and those in the Minkowski universe is clarified. Implications to the one-bubble open inflation scenario are also discussed.Comment: 26 pages, 1 figure, revtex. submitted to Phys. Rev. D1

On the use of Li isotopes as a proxy for water–rock interaction in fractured crystalline rocks: A case study from the Gotthard rail base tunnel

We present Li isotope measurements of groundwater samples collected during drilling of the 57 km long Gotthard rail base tunnel in Switzerland, to explore the use of Li isotope measurements for tracking water–rock interactions in fractured crystalline rocks at temperatures of up to 43 °C. The 17 groundwater samples originate from water-conducting fractures within two specific crystalline rock units, which are characterized by a similar rock mineralogy, but significantly different fluid composition. In particular, the aqueous Li concentrations observed in samples from the two units vary from 1–4 mg/L to 0.01–0.02 mg/L. Whereas δ7Li values from the unit with high Li concentrations are basically constant (δ7Li = 8.5–9.1‰), prominent variations are recorded for the samples from the unit with low Li concentrations (δ7Li = 10–41‰). This observation demonstrates that Li isotope fractionation can be highly sensitive to aqueous Li concentrations. Moreover, δ7Li values from the unit with low Li concentrations correlate well with reaction progress parameters such as pH and [Li]/[Na] ratios, suggesting that δ7Li values are mainly controlled by the residence time of the fracture groundwater. Consequently, 1D reactive transport modeling was performed to simulate mineral reactions and associated Li isotope fractionation along a water-conducting fracture system using the code TOUGHREACT. Modeling results confirm the residence time hypothesis and demonstrate that the absence of δ7Li variation at high Li concentrations can be well explained by limitation of the amount of Li that is incorporated into secondary minerals. Modeling results also suggest that Li uptake by kaolinite forms the key process to cause Li isotope fractionation in the investigated alkaline system (pH >9), and that under slow flow conditions (<10 m/year), this process is associated with a very large Li isotope fractionation factor (ε ≈ −50‰). Moreover, our simulations demonstrate that for simple and well-defined systems with known residence times and low Li concentrations, δ7Li values may help to quantify mineral reaction rates if more thermodynamic data about the temperature-dependent incorporation of Li in secondary minerals as well as corresponding fractionation factors become available in the future. In conclusion, δ7Li values may be a powerful tool to track water–rock interaction in fractured crystalline rocks at temperature higher than those at the Earth’s surface, although their use is restricted to low Li concentrations and well defined flow systems

Magnetic Behavior in RRhX (R = rare earths; X=B, C) Compounds

We report on the magnetic behavior of RRhB (R = La, Ce, Pr, Nd, Gd, Tb and Tm) and RRhC (R = La, Ce, Pr and Gd) compounds crystallizing in the cubic perovskite type structure with space group Pm3m. The heat capacity data on Pauli-paramagnetic LaRhB and LaRhC indicate a high frequency vibrating motion of boron and carbon atoms in the unit cell. Ce is in -like nonmagnetic state in both the compounds. Pr compounds show a dominant crystal field effect with a nonmagnetic singlet ground state in PrRhB and a nonmagnetic quadrupolar doublet in PrRhC. Compounds with other rare earths order ferromagnetically at low temperatures except TmRhB in which the zero field evolution of magnetic interactions is relatively more complicated. The electrical resistivity of GdRhB decreases with increasing temperature in the paramagnetic state in the vicinity of T, which is rarely seen in ferromagnets. The behavior is discussed to be arising due to the short range spin fluctuation and a possible contribution from Fermi surface geometry.Comment: 14 Figs and a text fil