Effect of cyclic loading on hydrogen diffusion in low carbon steels

Carbon steels or low-alloyed steels may be affected by damaging phenomena due to Hydrogen Embrittlement (HE), which is a particular form of Environmental Assisted Cracking (EAC). The insurgence of HE depends on the intrinsic susceptibility of the steel, the applied stress, and the concentration of hydrogen inside the metal. It occurs by a mechanism of absorption and subsequent diffusion of atomic hydrogen through the metal lattice. On steels with a yield strength lower than 700 MPa, HE occurs in the plastic deformation field, in the presence of dynamic loading at slow strain rates or cyclic fatigue loading at very low frequencies. Although several important studies were carried out on the effect of loading conditions on hydrogen diffusion into the metal and HE mechanism, HE phenomena are not fully understood. In this work, the effect of the application of cyclic loads on hydrogen diffusion parameters was studied both in the elastic and in the plastic deformation field. The influence of mean load and amplitude was analyzed. Hydrogen permeation tests were performed on API 5L X65 steel, in accordance with ISO 17081:2014. The specimen behaved as bi-electrode between the two compartments of a Devanathan-Stachurski cell. The anodic side of the specimen was polarized at +340 mV vs Ag/AgCl in a 0.1 M NaOH aerated solution, while the cathodic compartment was filled with an aerated borate solution. A controller enabled temperature adjustment at 20±0.5°C. Once the passivity current registered in the anodic side reached values of 0.05 µA/cm2, a cathodic current density of 0.50 mA/cm2 was applied to charging cathodic side. The study included tests with sine waveform cycling loading, with a maximum level equal to 110% TYS, at a frequency of 10-2 Hz. The results confirmed the values of hydrogen diffusion coefficient usually indicated for low-alloyed steels with a sorbitic microstructure. Strain hardened specimens - stretched above yield strength - showed an increase of steady state current and an extension of the time lag, denoting a slight decrease in the apparent hydrogen diffusion coefficient due to traps effect in the cold deformed steel matrix. Under cyclic loading, an instantaneous peak of current with a subsequent significant transient decrease occurred after cyclic load application, whereas no relevant variation of permeation curve compared to unloaded specimens was observed if specimens were already loaded before hydrogen charging. The instantaneous current peak reached values much higher than the steady state current. This is ascribed to the rupture of the passive film – caused by loading – and its subsequent reformation; in fact, this can also be noted during tests performed on specimens without hydrogen permeation. The following transient, in which the permeation current decreases below the steady state and then returns to it, denotes a relevant trapping effect that causes the instantaneous reduction of mobile hydrogen concentration in the lattice. This becomes more significant for loads closer and closer to the yield strength, mainly beyond this, and can only be noted at the first loading step. Subsequent unloading and loading step at the same mean value showed no transient in the permeation curren

Recurrence of Mitotically Active Cellular Fibroma of the Ovary

Background. 10% of ovarian fibromatous tumours typically exhibit increased cellularity, mitotic activity, and less frequently nuclear atypia. Therefore, the classification within the group of fibromatous tumours may represent some difficulties, thus, one or several of these features should appear. Case. We introduce the clinical and pathologic features based on one case of recurrence of a mitotically active cellular ovarian fibroma (MACF) in the pararectal fossa. This recurrence took place six years after primary surgery. Macroscopically, the tumour was firm, fibrous, well delimited, yellow-white without gross necrosis. On microscopic examination, it was composed of a densely cellular proliferation of fibrolastic-like cells with bland nuclear features and arranged in a fascicular pattern. There was no sign of significant atypia or necrosis. Conclusion. Recently, this case is the first report of a recurrence of MACF, following primary surgery with no tumoral rupture or surgical difficulty. The clinical outcome of ovarian cellular fibromas (CFs) and MACFs is typically uneventful. This case, however, strongly suggests maintaining a long-term clinical follow-up even though the principal tumour was surgically treated without tumour rupture or in the absence of adherence or any surgical difficulty

Detecting Gluino-Containing Hadrons

When SUSY breaking produces only dimension-2 operators, gluino and photino masses are of order 1 GeV or less. The gluon-gluino bound state has mass 1.3-2.2 GeV and lifetime > 10^{-5} - 10^{-10} s. This range of mass and lifetime is largely unconstrained because missing energy and beam dump techniques are ineffective. With only small modifications, upcoming K^0 decay experiments can study most of the interesting range. The lightest gluino-containing baryon (uds-gluino) is long-lived or stable; experiments to find it and the uud-gluino are also discussed.Comment: 13 pp, 1 figure (uuencoded). Descendant of hep-ph/9504295, hep-ph/9508291, and hep-ph/9508292, focused on experimental search techniques. To be published in Phys Rev Let

Tattoo-Paper Transfer as a Versatile Platform for All-Printed Organic Edible Electronics

The use of natural or bioinspired materials to develop edible electronic devices is a potentially disruptive technology that can boost point-of-care testing. The technology exploits devices which can be safely ingested, along with pills or even food, and operated from within the gastrointestinal tract. Ingestible electronics could potentially target a significant number of biomedical applications, both as therapeutic and diagnostic tool, and this technology may also impact the food industry, by providing ingestible or food-compatible electronic tags that can smart track goods and monitor their quality along the distribution chain. We hereby propose temporary tattoo-paper as a simple and versatile platform for the integration of electronics onto food and pharmaceutical capsules. In particular, we demonstrate the fabrication of all-printed Organic Field-Effect Transistors (OFETs) on untreated commercial tattoo-paper, and their subsequent transfer and operation on edible substrates with a complex non-planar geometry

Nanoscale effects on the ionic conductivity of highly doped bulk nanometric cerium oxide

Nanometric ceria powders doped with 30 mol % samaria are consolidated by a high-pressure spark plasma sintering (HP-SPS) method to form > 99 % dense samples with a crystallite size as small as 16.5 nm. A conductivity dependence on grain size was noted: when the grain size was less than 20 nm, only one semicircle in the AC impedance spectra was observed and was attributed to bulk conductivity. In contrast to previous observations on pure ceria, the disappearance of the grain-boundary blocking effect is not associated with mixed conductivity. With annealing and concomitant grain growth, the samples show the presence of a grain-boundary effect

Impact of D0-D0bar mixing on the experimental determination of gamma

Several methods have been devised to measure the weak phase gamma using decays of the type B+- --> D K+-, where it is assumed that there is no mixing in the D0-D0bar system. However, when using these methods to uncover new physics, one must entertain the real possibility that the measurements are affected by new physics effects in the D0-D0bar system. We show that even values of x_D and/or y_D around 10^{-2} can have a significant impact in the measurement of sin^2{gamma}. We discuss the errors incurred in neglecting this effect, how the effect can be checked, and how to include it in the analysis.Comment: 18 pages, Latex with epsfig, 8 figure

Hydrogen Embrittlement and Diffusion in High Strength Low Alloyed Steels with Different Microstructures

The paper deals with the effect of microstructure on the hydrogen diffusion in traditional ferritic-pearlitic HSLA steels and new high strength steels, with tempered martensite microstructures or banded ferritic-bainitic-martensitic microstructures. Diffusivity was correlated to the hydrogen embrittlement resistance of steels, evaluated by means of slow strain rate tests. </p

Tau and Charm physics highlights

In tau physics, we are at the frontier between the completion of the LEP program and the start of analyses from b-factories, which are expected to produce results in the coming years. Nice results from CLEO are steadily delivered in the meantime. For charm, impressive progress have been achieved by fixed target experiments in the search for CP violation and D^0 - \bar D^0 oscillations. First results from b-factories demonstrate the power of these facilities in such areas. The novel measurement of the D* width by CLEO happens to be rather different from current expectations. The absence of a charm factory explains the lack or the very slow progress in the absolute scale determinations for charm decays.Comment: "Typos corrected and references added

Experiments to Find or Exclude a Long-Lived, Light Gluino

Gluinos in the mass range ~1 1/2 - 3 1/2 GeV are absolutely excluded. Lighter gluinos are allowed, except for certain ranges of lifetime. Only small parts of the mass-lifetime parameter space are excluded for larger masses unless the lifetime is shorter than ~ 2 10^{-11} (m_{gluino}/ GeV) sec. Refined mass and lifetime estimates for R-hadrons are given, present direct and indirect experimental constraints are reviewed, and experiments to find or definitively exclude these possibilities are suggested.Comment: 27 pp, latex with 1 uufiled figure, RU-94-35. New version amplifies discussion of some points and corresponds to version for Phys. Rev.

Leptogenesis and low energy observables in left-right symmetric models

In the context of left-right symmetric models we study the connection of leptogenesis and low energy parameters such as neutrinoless double beta decay and leptonic CP violation. Upon imposition of a unitarity constraint, the neutrino parameters are significantly restricted and the Majorana phases are determined within a narrow range, depending on the kind of solar solution. One of the Majorana phases gets determined to a good accuracy and thereby the second phase can be probed from the results of neutrinoless double beta decay experiments. We examine the contributions of the solar and atmospheric mass squared differences to the asymmetry and find that in general the solar scale dominates. In order to let the atmospheric scale dominate, some finetuning between one of the Majorana phases and the Dirac CP phase is required. In this case, one of the Majorana phases is determined by the amount of CP violation in oscillation experiments.Comment: 18 pages, 6 figures. Matches version to appear in PR