Geomorphology of Canyon Outlets in Zrmanja River Estuary and Its Effect on the Holocene Flooding of Semi-enclosed Basins (the Novigrad and Karin Seas, Eastern Adriatic)

Detailed multi-beam bathymetry, sub-bottom acoustic, and side-scan sonar observations of submerged canyons with tufa barriers were used to characterize the Zrmanja River karst estuary on the eastern Adriatic coast, Croatia. This unique karst environment consists of two submerged karst basins (Novigrad Sea and Karin Sea) that are connected with river canyons named Novsko Ždrilo and Karinsko Ždrilo. The combined use of high-resolution geophysical data with legacy topography and bathymetry data in a GIS environment allowed for the description and interpretation of this geomorphological setting in relation to the Holocene sea-level rise. The tufa barriers had a predominant influence on the Holocene flooding dynamics of the canyons and karst basins. Here, we describe the possible river pathways from the basins during the lowstand and the formation of a lengthening estuary during the Holocene sea-level rise. Based on the analyzed morphologies and the relative sea-level curve for the Adriatic Sea, the flooding of the Novsko Ždrilo occurred 9200 years before present (BP) and Karinsko Ždrilo was flooded after 8400 years BP. The combination of high-resolution geophysical methods gave an accurate representation of the karst estuarine seafloor and the flooding of semi-isolated basins due to sea-level rise

A compositional approach to the reconstruction of geochemical processes involved in the evolution of Holocene marine flooded coastal karst basins (Mljet Island, Croatia)

Geochemical patterns in the environment are always the result of certain processes. Therefore, it is essential to decipher a process to properly evaluate the environmental role and potential of chemical elements/compounds. This allows the distinction between natural and anthropogenic influence on elemental concentrations. However, if the compositional nature of geochemical data is neglected, erroneous or misleading conclusions regarding the processes involved are probable. In this study the reconstruction of depositional environments and processes through the Holocene in two sediment cores obtained from submerged sinkholes located on the island of Mljet, Croatia, was performed by taking into account the compositional nature of geochemical, mineralogical and grainsize data. Problems involving compositional data are always multivariate; for example, the concentration of a single element does not carry any interpretative information, as only the ratios between elements do. This has led to the discovery of a large number of geochemical proxies based on elemental ratios, which describe certain environmental conditions and processes involved. Nevertheless, some proxies have been found to be restricted to only some specific environments, thus preventing them from being used in general; therefore, some kind of relation between different proxies is necessary to obtain final conclusions. However, when using simple elemental ratios, those correlations cannot be obtained due to the nature of compositional data. With a sequential binary partition of a compositional vector, orthonormal log ratio (olr) coordinates (proxies) can be constructed. When based on expert knowledge, those proxies fully acknowledge the geochemical properties of the chosen elements with one major difference - that the correlation between newly obtained variables is mathematically well grounded. As a result, the final conclusion is more accurate. In this research, geochemical proxies obtained as a representation in olr coordinates of the elements that are enriched compared to the local soil were used to perform principal component analyses. It helped to unravel the evolution of sedimentary environments. Mineralogical (XRD and heavy mineral data) and grain size analyses supported the conclusions obtained based solely on geochemical data. Furthermore, data analysis suggests that the proxies for redox conditions described in the literature should be used with caution, as their use is somewhat limited

Late Pleistocene and Holocene paleoenvironmental reconstruction of a drowned karst isolation basin (Lošinj Channel, NE Adriatic Sea)

The results of a comprehensive study of submerged paleoenvironments developed along the karstified eastern Adriatic coast during the Late Quaternary are presented in this study. The Lošinj Channel is a drowned karst basin filled with sediments. A multi-proxy analysis of two sediment cores (LK-12 and LK-15) recovered from water depths of 62 and 64 m was conducted. We used magnetic susceptibility, grain size, mineralogy, XRF core scanning, organic and inorganic carbon, total nitrogen, and paleontological data, supplemented with AMS 14C dating results and high-resolution seismic data, to reconstruct the infill history of the Lošinj basin during the Late Pleistocene and Holocene. Our findings include the first detailed description of the presumed Marine Isotope Stage (MIS) 5a marine sediment succession along the eastern Adriatic coast. Deposition in the brackish-to-freshwater lacustrine body (Lošinj paleolake) occurred during MIS 3. Sea level lowstand that followed caused the formation of environmental conditions typical of a karst polje. The post-Last Glacial Maximum (LGM) sea level rise led to the establishment of a brackish marine lake with seawater seepage through the karstified sill at 13.7 cal kyr B.P. The transition to the present-day marine conditions commenced at 10.5 cal kyr B.P. Paleoenvironmental changes in the investigated area can be linked to the presence of a sill at −50 m depth that separates the Lošinj basin from the Kvarnerić Bay. The sill depth determines the isolation or inundation of the investigated basin in response to the changes in sea level. Paleoenvironments reacted sensitively to these changes, and therefore, the study area represents an ideal setting to track regional sea level and climate variabilty

Holocene foraminiferal and geochemical records in the coastal karst dolines of Cres Island, Croatia

Numerous karst dolines have been formed along the Croatian coast and many have been submerged during the Late Glacial and Holocene sea level rise. The coastal area of Cres Island in the Northern Adriatic is a typical example of this geomorphological setting, where transitional forms from subaerial to submerged dolines are present. Once dolines are formed they can accumulate soil, water and sediments due to their morphology. Sediments are an especially valuable source of environmental data. This paper presents the results of the study of foraminiferal assemblages and sediment geochemistry, supplemented with grain-size and mineralogical data, from the marine ponds developed in the karst dolines on Cres Island. Obtained data is correlated with the sediment core record from submerged dolines in the present-day embayments along the coastal zone of Cres Island. In total, 3 sediment cores were collected in the marine ponds Marinska, Arcij and Podbrajde, while 2 longer sediment cores have been extracted from the Jaz and Sonte embayments. The Marinska, Arcij and Podbrajde marine ponds have distinct geochemical and mineralogical sediment compositions, with monospecific foraminiferal assemblages and generally differ from each other. The common characteristics are their high N and P concentrations and the algal origin of organic matter. Agglutinated foraminiferal taxa (Haplophragmoides canariensis and Trochammina inflata), typical for intertidal environments, are abundant in the brackish-water Marinska pond, while stress-tolerant species Ammonia tepida has been identified in the Arcij marine pond. Environmental conditions in the Podbrajde marine pond did not facilitate the development of a rich foraminiferal fauna. Results from the present-day marine ponds enabled recognition of similar environments in the sediment cores collected in the Jaz and Sonte embayments that were progressively inundated during the Holocene sea level rise. A palaeo-marine pond existed in the Sonte embayment until 6610 cal BP, when the sea flooded the investigated area. A marine pond in the Jaz embayment was formed at 711 cal BP. Low-diversity foraminiferal assemblages in these palaeo-ponds are similar to those recognized in the present-day Arcij marine pond on Cres Island. However, differences in the geochemical composition of palaeo-marine ponds, in comparison to the present-day ponds, exist. They might be attributed to climate variability over time and variations in the geological setting of each environment. High Mo concentrations and abundant organic matter content are the main sediment characteristics of the recognized palaeo-marine ponds in the Jaz and Sonte embayments