On the maximal ionization of atoms in strong magnetic fields

We give upper bounds for the number of spin 1/2 particles that can be bound to a nucleus of charge Z in the presence of a magnetic field B, including the spin-field coupling. We use Lieb's strategy, which is known to yield N_c<2Z+1 for magnetic fields that go to zero at infinity, ignoring the spin-field interaction. For particles with fermionic statistics in a homogeneous magnetic field our upper bound has an additional term of order $Z\times\min{(B/Z^3)^{2/5},1+|\ln(B/Z^3)|^2}$.Comment: LaTeX2e, 8 page

H2 molecule in strong magnetic fields

The Pauli-Hamiltonian of a molecule with fixed nuclei in a strong constant magnetic field is asymptotic, in norm-resolvent sense, to an effective Hamiltonian which has the form of a multi-particle Schr\"odinger operator with interactions given by one-dimensional \delta-potentials. We study this effective Hamiltonian in the case of the H2 -molecule and establish existence of the ground state. We also show that the inter-nuclear equilibrium distance tends to 0 as the field-strength tends to infinity

Auto-tail dependence coefficients for stationary solutions of linear stochastic recurrence equations and for GARCH(1,1)

We examine the auto-dependence structure of strictly stationary solutions of linear stochastic recurrence equations and of strictly stationary GARCH(1, 1) processes from the point of view of ordinary and generalized tail dependence coefficients. Since such processes can easily be of infinite variance, a substitute for the usual auto-correlation function is needed

Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran

The title compound has been prepared from Cp-2*LaCl2K(THF)(2) and 1-PhC3H4K-(THF)(0.5) in THF suspension, forming yellow single crystals from hexane solution which were characterized in solid state and in solution by elementary analysis, IR, C-13- and variable temperature H-1-NMR spectroscopy and a crystal structure determination. Space group P1, Z = 2, T = 130 K, a = 8.595(1), b = 10.770(1), c = 17.903(5) angstrom, alpha = 93.54(1)degrees, beta = 98.30(1)degrees, gamma = 112.42(1)degrees, R = 0.0249

Continuum theory of vacancy-mediated diffusion

We present and solve a continuum theory of vacancy-mediated diffusion (as evidenced, for example, in the vacancy driven motion of tracers in crystals). Results are obtained for all spatial dimensions, and reveal the strongly non-gaussian nature of the tracer fluctuations. In integer dimensions, our results are in complete agreement with those from previous exact lattice calculations. We also extend our model to describe the vacancy-driven fluctuations of a slaved flux line.Comment: 25 Latex pages, subm. to Physical Review

Quantitative uniqueness for elliptic equations with singular lower order terms

We use a Carleman type inequality of Koch and Tataru to obtain quantitative estimates of unique continuation for solutions of second order elliptic equations with singular lower order terms. First we prove a three sphere inequality and then describe two methods of propagation of smallness from sets of positive measure.Comment: 23 pages, v2 small changes are done and some mistakes are correcte

The Atomic Slide Puzzle: Self-Diffusion of an Impure Atom

In a series of recent papers van Gastel et al have presented first experimental evidence that impure, Indium atoms, embedded into the first layer of a Cu(001) surface, are not localized within the close-packed surface layers but make concerted, long excursions visualized in a series of STM images. Such excursions occur due to continuous reshuffling of the surface following the position exchanges of both impure and host atoms with the naturally occuring surface vacancies. Van Gastel et al have also formulated an original lattice-gas type model with asymmetric exchange probabilities, whose numerical solution is in a good agreement with the experimental data. In this paper we propose an exact lattice solution of several versions of this model.Comment: Latex, 4 pages, 2 figures, to appear in Phys. Rev. E (RC

H^+_2$ in a strong magnetic field described via a solvable model

We consider the hydrogen molecular ion $H^+_2$ in the presence of a strong homogeneous magnetic field. In this regime, the effective Hamiltonian is almost one dimensional with a potential energy which looks like a sum of two Dirac delta functions. This model is solvable, but not close enough to our exact Hamiltonian for relevant strenght of the magnnetic field. However we show that the correct values of the equilibrium distance as well as the binding energy of the ground state of the ion, can be obtained when incorporating perturbative corrections up to second order. Finally, we show that $He_2^{3+}$ exists for sufficiently large magnetic fields

Ultra-Slow Vacancy-Mediated Tracer Diffusion in Two Dimensions: The Einstein Relation Verified

We study the dynamics of a charged tracer particle (TP) on a two-dimensional lattice all sites of which except one (a vacancy) are filled with identical neutral, hard-core particles. The particles move randomly by exchanging their positions with the vacancy, subject to the hard-core exclusion. In case when the charged TP experiences a bias due to external electric field ${\bf E}$, (which favors its jumps in the preferential direction), we determine exactly the limiting probability distribution of the TP position in terms of appropriate scaling variables and the leading large-N ($n$ being the discrete time) behavior of the TP mean displacement $\bar{{\bf X}}_n$; the latter is shown to obey an anomalous, logarithmic law $|\bar{{\bf X}}_n| = \alpha_0(|{\bf E}|) \ln(n)$. On comparing our results with earlier predictions by Brummelhuis and Hilhorst (J. Stat. Phys. {\bf 53}, 249 (1988)) for the TP diffusivity $D_n$ in the unbiased case, we infer that the Einstein relation $\mu_n = \beta D_n$ between the TP diffusivity and the mobility $\mu_n = \lim_{|{\bf E}| \to 0}(|\bar{{\bf X}}_n|/| {\bf E} |n)$ holds in the leading in $n$ order, despite the fact that both $D_n$ and $\mu_n$ are not constant but vanish as $n \to \infty$. We also generalize our approach to the situation with very small but finite vacancy concentration $\rho$, in which case we find a ballistic-type law $|\bar{{\bf X}}_n| = \pi \alpha_0(|{\bf E}|) \rho n$. We demonstrate that here, again, both $D_n$ and $\mu_n$, calculated in the linear in $\rho$ approximation, do obey the Einstein relation.Comment: 25 pages, one figure, TeX, submitted to J. Stat. Phy

A One-Dimensional Model for Many-Electron Atoms in Extremely Strong Magnetic Fields: Maximum Negative Ionization

We consider a one-dimensional model for many-electron atoms in strong magnetic fields in which the Coulomb potential and interactions are replaced by one-dimensional regularizations associated with the lowest Landau level. For this model we show that the maximum number of electrons is bounded above by 2Z+1 + c sqrt{B}. We follow Lieb's strategy in which convexity plays a critical role. For the case of two electrons and fractional nuclear charge, we also discuss the critical value at which the nuclear charge becomes too weak to bind two electrons.Comment: 23 pages, 5 figures. J. Phys. A: Math and General (in press) 199