Snow depth measurement via time lapse photography and automated image recognition

January 2019.Includes bibliographical references.Seasonal snow is a crucial component of water supply in Colorado and the western United States. Measurement of snow accumulation through the winter and spring allows water managers to forecast water supply for the growing season and take actions to ease flooding and drought. The Natural Resources Conservation Service’s (NRCS) snow telemetry (SNOTEL) network provides real-time data at a high cost per station and at single points. An evaluation of existing field measurements of snow depth taken in 2009 and 2010 was undertaken to determine if fine resolution depth measurements are justified. Fassnacht et al. (in press) showed that the snow depth variability can be substantial even at fine resolution. However, these data required extensive labor to collect and only represented one measurement in time. A low-cost method to measure snow variability around these stations or in underrepresented areas could improve snow forecasts by quantifying the representativeness of data from the current network. To this end, we trialed a method combining time lapse photography and computer vision techniques to find snow depth at five sites in Colorado during water year 2018. Different site configurations were trialed, and a best operating procedure was determined. The data gathered were not more accurate than current ultrasonic or laser snow depth measurement technologies. However, the low cost and versatility of this method may make it more applicable in certain situations

Nighttime chemistry at a high altitude site above Hong Kong

Nighttime reactions of nitrogen oxides influence ozone, volatile organic compounds, and aerosol and are thus important to the understanding of regional air quality. Despite large emissions and rapid recent growth of nitrogen oxide concentrations, there are few studies of nighttime chemistry in China. Here we present measurements of nighttime nitrogen oxides, NO3 and N2O5, from a coastal mountaintop site in Hong Kong adjacent to the megacities of the Pearl River Delta region. This is the first study of nighttime chemistry from a site within the residual layer in China. Key findings include the following. First, highly concentrated urban NOx outflow from the Pearl River Delta region was sampled infrequently at night, with N2O5 mixing ratios up to 8 ppbv (1 min average) or 12 ppbv (1 s average) in nighttime aged air masses. Second, the average N2O5 uptake coefficient was determined from a best fit to the available steady state lifetime data as γ(N2O5) = 0.014 ± 0.007. Although this determination is uncertain due to the difficulty of separating N2O5 losses from those of NO3, this value is in the range of previous residual layer determinations of N2O5 uptake coefficients in polluted air in North America. Third, there was a significant contribution of biogenic hydrocarbons to NO3 loss inferred from canister samples taken during daytime. Finally, daytime N2O5 mixing ratios were in accord with their predicted photochemical steady state. Heterogeneous uptake of N2O5 in fog is determined to be an important production mechanism for soluble nitrate, even during daytime. Key Points Large (up to 12 ppbv N2O5) but infrequent nocturnal NOx outflow from the Pearl River Delta Average N2O5 uptake coefficients 0.014 ± 0.007, in line with residual layer measurements in the U.S. Daytime N2O5 follows predicted steady state but rapidly produces soluble nitrate in fog.Department of Civil and Environmental Engineerin

Surface pinning of fluctuating charge order: an "extraordinary" surface phase transition

We study the mean-field theory of charge-density wave (CDW) order in a layered system, including the effect of the long-range Coulomb interaction and of screening by uncondensed electrons. We particularly focus on the conditions necessary for an ``extraordinary'' transition, in which the surface orders at a higher temperature, and is more likely to be commensurate, than the bulk. We interpret recent experiments on NaCCOC as indicating the presence of commensurate CDW at the surface that is not present in the bulk. More generally, we show that poor screening of the Coulomb interaction tends to stabilize incommensurate order, possibly explaining why the CDW order in LSCO and NbSe2 remains incommensurate to T -> 0, despite the small magnitude of the incommensurability.Comment: 9 pages, no figures, 31 references; 1 new figure and minor editing of the tex

Evolution of NO3 reactivity during the oxidation of isoprene

In a series of experiments in an atmospheric simulation chamber (SAPHIR,1 Forschungszentrum J&uuml;lich, Germany), NO3 reactivity (kNO3) resulting from the reaction of NO3 with isoprene and stable trace gases formed as products was measured directly using a flow tube reactor coupled to a cavity ring-down spectrometer (FT-CRDS). The experiments were carried out in both dry and humid air with variation of the initial mixing ratios of ozone (50&ndash;100&thinsp;ppbv), isoprene (3&ndash;22&thinsp;ppbv) and NO2 (5&ndash;30&thinsp;ppbv). kNO3 was in excellent agreement with values calculated from the isoprene mixing ratio and the rate coefficient for the reaction of NO3 with isoprene. This result serves to confirm that the FT-CRDS returns accurate values of kNO3 even at elevated NO2 concentrations and to show that reactions of NO3 with stable reaction products like non-radical organic nitrates do not contribute significantly to NO3 reactivity during the oxidation of isoprene. A comparison of kNO3 with NO3 reactivities calculated from NO3 mixing ratios and NO3 production rates suggests that organic peroxy radicals and HO2 account for &sim;50&thinsp;% of NO3 losses. This contradicts predictions based on numerical simulations using the Master Chemical Mechanism (MCM version 3.3.1) unless the rate coefficient for reaction between NO3 and isoprene-derived RO2 is roughly doubled to &sim;5&times;10&minus;12&thinsp;cm3&thinsp;molecule&minus;1&thinsp;s&minus;1. &nbsp; Full List of Authors and Affiliations: Patrick Dewald1, Jonathan M. Liebmann1, Nils Friedrich1, Justin Shenolikar1, Jan Schuladen1, Franz Rohrer2, David Reimer2, Ralf Tillmann2, Anna Novelli2, Changmin Cho2, Kangming Xu3, Rupert Holzinger3, Fran&ccedil;ois Bernard4,a, Li Zhou4, Wahid Mellouki4, Steven S. Brown5,6, Hendrik Fuchs2, Jos Lelieveld1, and John N. Crowley1 1Atmospheric Chemistry Department, Max-Planck-Institut f&uuml;r Chemie, 55128 Mainz, Germany 2Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum J&uuml;lich GmbH, 52428 J&uuml;lich, Germany 3Institute for Marine and Atmospheric Research, IMAU, Utrecht University, Utrecht, the Netherlands 4Institut de Combustion, A&eacute;rothermique, R&eacute;activit&eacute; et Environnement (ICARE), CNRS (UPR 3021)/OSUC, 1C Avenue de la Recherche Scientifique, 45071 Orl&eacute;ans CEDEX 2, France 5NOAA Chemical Sciences Laboratory, 325 Broadway, Boulder, CO 80305, USA 6Department of Chemistry, University of Colorado Boulder, Boulder, CO 80209, USA anow at: Laboratoire de Physique et Chimie de l'Environnement et de l'Espace (LPC2E), Centre National de la Recherche Scientifique (CNRS), Universit&eacute; d'Orl&eacute;ans, Observatoire des Sciences de l'Univers en r&eacute;gion Centre &ndash; Val de Loire (OSUC), Orl&eacute;ans, France </ul

Periodic Solutions of the Einstein Equations for Binary Systems

This revision includes clarified exposition and simplified analysis. Solutions of the Einstein equations which are periodic and have standing gravitational waves are valuable approximations to more physically realistic solutions with outgoing waves. A variational principle is found which has the power to provide an accurate estimate of the relationship between the mass and angular momentum of the system, the masses and angular momenta of the components, the rotational frequency of the frame of reference in which the system is periodic, the frequency of the periodicity of the system, and the amplitude and phase of each multipole component of gravitational radiation. Examination of the boundary terms of the variational principle leads to definitions of the effective mass and effective angular momentum of a periodic geometry which capture the concepts of mass and angular momentum of the source alone with no contribution from the gravitational radiation. These effective quantities are surface integrals in the weak-field zone which are independent of the surface over which they are evaluated, through second order in the deviations of the metric from flat space.Comment: 18 pages, RevTeX 3.0, UF-RAP-93-1

Complete Genomic Sequences of Three Salmonella enterica subsp. enterica Serovar Muenchen Strains from an Orchard in San Joaquin County, California.

We present here the complete genome sequences of three Salmonella enterica subsp. enterica serovar Muenchen strains, LG24, LG25, and LG26. All three strains were isolated from almond drupes grown in an orchard in San Joaquin County, California, in 2016. These genomic sequences are nonidentical and will contribute to our understanding of S. enterica genomics

Observations of nitryl chloride and modeling its source and effect on ozone in the planetary boundary layer of southern China

Nitryl chloride (ClNO2) plays potentially important roles in atmospheric chemistry, but its abundance and effect are not fully understood due to the small number of ambient observations of ClNO2 to date. In late autumn 2013, ClNO2 was measured with a chemical ionization mass spectrometer (CIMS) at a mountain top (957 m above sea level) in Hong Kong. During 12 nights with continuous CIMS data, elevated mixing ratios of ClNO2 (&gt;400 parts per trillion by volume) or its precursor N2O5 (&gt;1000 pptv) were observed on six nights, with the highest ever reported ClNO2 (4.7 ppbv, 1 min average) and N2O5 (7.7 ppbv, 1 min average) in one case. Backward particle dispersion calculations driven by winds simulated with a mesoscale meteorological model show that the ClNO2/N2O5-laden air at the high-elevation site was due to transport of urban/industrial pollution north of the site. The highest ClNO2/N2O5 case was observed in a later period of the night and was characterized with extensively processed air and with the presence of nonoceanic chloride. A chemical box model with detailed chlorine chemistry was used to assess the possible impact of the ClNO2 in the well-processed regional plume on next day ozone, as the air mass continued to downwind locations. The results show that the ClNO2 could enhance ozone by 5-16% at the ozone peak or 11-41% daytime ozone production in the following day. This study highlights varying importance of the ClNO2 chemistry in polluted environments and the need to consider this process in photochemical models for prediction of ground-level ozone and haze. Key Points First observation of ClNO2 in the planetary boundary layer of China Combined high-resolution meteorological and measurement-constrained chemical models in data analysis ClNO2 enhances daytime ozone peak by 5-16% in well-processed PRD air.Department of Civil and Environmental Engineerin

Benthic-Pelagic Coupling in Northern Gulf of Mexico Estuaries: Do Benthos Feed Directly on Phytoplankton?

Few of the dominant benthic taxa of the northern Gulf of Mexico feed directly on phytoplankton. Rather, most of them feed on near-bottom seston and detritus. This is in contrast to models for Chesapeake Bay and San Francisco Bay. We found that detritivores represented over 80% of the macrobenthic organisms and over 90% of the biomass in Gulf of Mexico estuaries. The paucity of benthos that consumed phytoplankton led us to hypothesize that macrobenthos in Gulf of Mexico estuaries had less effect on plankton communities than was documented in U.S. east coast and west coast estuaries, where benthic communities consumed much of the water-column production. We provided as evidence gut-contents analyses of dominant taxa, the feeding morphology of suspension feeders (especially clams), and the lack of vertical mixing or strong turbulent flow that is necessary for benthos to remove substantial portions of the phytoplankton

The Zymomonas mobilis regulator hfq contributes to tolerance against multiple lignocellulosic pretreatment inhibitors

<p>Abstract</p> <p>Background</p> <p><it>Zymomonas mobilis </it>produces near theoretical yields of ethanol and recombinant strains are candidate industrial microorganisms. To date, few studies have examined its responses to various stresses at the gene level. Hfq is a conserved bacterial member of the Sm-like family of RNA-binding proteins, coordinating a broad array of responses including multiple stress responses. In a previous study, we observed <it>Z. mobilis </it>ZM4 gene ZMO0347 showed higher expression under anaerobic, stationary phase compared to that of aerobic, stationary conditions.</p> <p>Results</p> <p>We generated a <it>Z. mobilis hfq </it>insertion mutant AcRIM0347 in an acetate tolerant strain (AcR) background and investigated its role in model lignocellulosic pretreatment inhibitors including acetate, vanillin, furfural and hydroxymethylfurfural (HMF). <it>Saccharomyces cerevisiae </it>Lsm protein (Hfq homologue) mutants and Lsm protein overexpression strains were also assayed for their inhibitor phenotypes. Our results indicated that all the pretreatment inhibitors tested in this study had a detrimental effect on both <it>Z. mobilis </it>and <it>S. cerevisiae</it>, and vanillin had the most inhibitory effect followed by furfural and then HMF for both <it>Z. mobilis </it>and <it>S. cerevisiae</it>. AcRIM0347 was more sensitive than the parental strain to the inhibitors and had an increased lag phase duration and/or slower growth depending upon the conditions. The <it>hfq </it>mutation in AcRIM0347 was complemented partially by trans-acting <it>hfq </it>gene expression. We also assayed growth phenotypes for <it>S. cerevisiae </it>Lsm protein mutant and overexpression phenotypes. Lsm1, 6, and 7 mutants showed reduced tolerance to acetate and other pretreatment inhibitors. <it>S. cerevisiae </it>Lsm protein overexpression strains showed increased acetate and HMF resistance as compared to the wild-type, while the overexpression strains showed greater inhibition under vanillin stress conditions.</p> <p>Conclusions</p> <p>We have shown the utility of the pKNOCK suicide plasmid for mutant construction in <it>Z. mobilis</it>, and constructed a Gateway compatible expression plasmid for use in <it>Z. mobilis </it>for the first time. We have also used genetics to show <it>Z. mobilis </it>Hfq and <it>S. cerevisiae </it>Lsm proteins play important roles in resisting multiple, important industrially relevant inhibitors. The conserved nature of this global regulator offers the potential to apply insights from these fundamental studies for further industrial strain development.</p