Synthesis of elastomers for use with liquid fluorine Quarterly letter report, 1 Sep. - 30 Nov. 1968

Phosphines as initiators of polymerization of hexafluorobutyne-

Synthesis of elastomers for use with liquid fluorine Final report

Synthesis and chemical properties of elastomeric polymers resistant to effects of fluorine, oxygen difluoride, nitrogen tetroxide, and similar agent

Radial segregation induced by natural convection and melt/solid interface shape in vertical Bridgman growth

The roles of natural convection in the melt and the shape of the melt/solid interface on radial dopant segregation are analyzed for a prototype of vertical Bridgman crystal growth system by finite element methods that solve simultaneously for the velocity field in the melt, the shape of the solidification isotherm, and the temperature distribution in both phases. Results are presented for crystal and melt with thermophysical properties similar to those of gallium-doped germanium in Bridgman configurations with melt below (thermally destabilizing) and above (stabilizing) the crystal. Steady axisymmetric flow are classified according to Rayleigh number as either being nearly the growth velocity, having a weak cellular structure or having large amplitude cellular convention. The flows in the two Bridgman configurations are driven by different temperature gradients and are in opposite directions. Finite element calculations for the transport of a dilute dopant by these flow fields reveal radial segregation levels as large as sixty percent of the mean concentration. Segregation is found most severe at an intermediate value of Rayleigh number above which the dopant distribution along the interface levels as the intensity of the flow increases

Synthesis of elastomers for use with liquid fluorine Annual interim report

Elastomer synthesis for copolymerization with liquid fluorin

Permutation groups, simple groups and sieve methods

We show that the number of integers n ≤ x which occur as indices of subgroups of nonabelian finite simple groups, excluding that of An-1 in An, is ∼ hx/log x, for some given constant h. This might be regarded as a noncommutative analogue of the Prime Number Theorem (which counts indices n ≤ x of subgroups of abelian simple groups). We conclude that for most positive integers n, the only quasiprimitive permutation groups of degree n are Sn and An in their natural action. This extends a similar result for primitive permutation groups obtained by Cameron, Neumann and Teague in 1982. Our proof combines group-theoretic and number-theoretic methods. In particular, we use the classification of finite simple groups, and we also apply sieve methods to estimate the size of some interesting sets of primes

Multiple buoyancy driven flows in a vertical cylinder heated from below

The structure of axisymmetric buoyancy-driven convection in a vertical cylinder heated from below is probed by finite element solution of the Boussinesq equations coupled with computed-implemented perturbation techniques for detecting and tracking multiple flows and for determining flow stability. Results are reported for fluids with Prandtl number of one and for cylinders with aspect ratio (Lambda) (defined as the height to radius of the cylinder) between 0.5 and 2.25. Extensive calculations of the neutral stability curve for the static solution and of the nonlinear motions along the bifurcating flow families show a continuous evolution of the primary cellular motion from a single toroidal cell to two and three cells nested radially in the cylinder, instead of the sharp transitions found for a cylinder with shear-free sidewalls. The smooth transitions in flow structure with Rayleigh number and lambda are explained by nonlinear connectivity between the first two bifurcating flow families formed either by a secondary bifurcation point for Lambda or = Lambda * approximately 0.80 or by a limit point for Lambda Lambda *. The transition between these two modes may be described by the theory of multiple limit point bifurcation

Three-Dimensional Structure of the Magnetic Field in the Disk of the Milky Way

We present Rotation Measures (RM) of the diffuse Galactic synchrotron emission from the Canadian Galactic Plane Survey (CGPS) and compare them to RMs of extragalactic sources in order to study the large-scale reversal in the Galactic magnetic field (GMF). Using Stokes Q, U and I measurements of the Galactic disk collected with the Synthesis Telescope at the Dominion Radio Astrophysical Observatory, we calculate RMs over an extended region of the sky, focusing on the low longitude range of the CGPS (l=52deg to l=72deg). We note the similarity in the structures traced by the compact sources and the extended emission and highlight the presence of a gradient in the RM map across an approximately diagonal line, which we identify with the well-known field reversal of the Sagittarius-Carina arm. We suggest that the orientation of this reversal is a geometric effect resulting from our location within a GMF structure arising from current sheets that are not perpendicular to the Galactic plane, as is required for a strictly radial field reversal, but that have at least some component parallel to the disk. Examples of models that fit this description are the three-dimensional dynamo-based model of Gressel et al. (2013) and a Galactic scale Parker spiral (Akasofu & Hakamada 1982), although the latter may be problematic in terms of Galactic dynamics. We emphasize the importance of constructing three-dimensional models of the GMF to account for structures like the diagonal RM gradient observed in this dataset.Comment: Published in Astronomy and Astrophysics, Accepted 23 April, 201

Importance of including small body spin effects in the modelling of intermediate mass-ratio inspirals. II Accurate parameter extraction of strong sources using higher-order spin effects

We improve the numerical kludge waveform model introduced in [1] in two ways. We extend the equations of motion for spinning black hole binaries derived by Saijo et al. [2] using spin-orbit and spin-spin couplings taken from perturbative and post-Newtonian (PN) calculations at the highest order available. We also include first-order conservative self-force corrections for spin-orbit and spin-spin couplings, which are derived by comparison to PN results. We generate the inspiral evolution using fluxes that include the most recent calculations of small body spin corrections, spin-spin and spin-orbit couplings and higher-order fits to solutions of the Teukolsky equation. Using a simplified version of this model in [1], we found that small body spin effects could be measured through gravitational wave observations from intermediate-mass ratio inspirals (IMRIs) with mass ratio eta ~ 0.001, when both binary components are rapidly rotating. In this paper we study in detail how the spin of the small/big body affects parameter measurement using a variety of mass and spin combinations for typical IMRIs sources. We find that for IMRI events of a moderately rotating intermediate mass black hole (IMBH) of ten thousand solar masses, and a rapidly rotating central supermassive black hole (SMBH) of one million solar masses, gravitational wave observations made with LISA at a fixed signal-to-noise ratio (SNR) of 1000 will be able to determine the inspiralling IMBH mass, the central SMBH mass, the SMBH spin magnitude, and the IMBH spin magnitude to within fractional errors of ~0.001, 0.001, 0.0001, and 9%, respectively. LISA can also determine the location of the source in the sky and the SMBH spin orientation to within ~0.0001 steradians. We show that by including conservative corrections up to 2.5PN order, systematic errors no longer dominate over statistical errors for IMRIs with typical SNR ~1000.Comment: 21 pages, 7 figures. v2: three references added, edits in Sections II-V, including additional results in Section V to address comments by the referee. v3: mirrors version accepted to PR

Boundary States and Black Hole Entropy

Black hole entropy is derived from a sum over boundary states. The boundary states are labeled by energy and momentum surface densities, and parametrized by the boundary metric. The sum over state labels is expressed as a functional integral with measure determined by the density of states. The sum over metrics is expressed as a functional integral with measure determined by the universal expression for the inverse temperature gradient at the horizon. The analysis applies to any stationary, nonextreme black hole in any theory of gravitational and matter fields.Comment: 4 pages, Revte