Inverse Geometry for Stereolithographic Manufacturing

As parts produced by stereolithography form and cure, they warp and shrink to produce Pitrts that are not quite the san~ ~ as those originally specified. This research attempts to solve the inverse geomptry problem, that is, what shape should be specified initially so that the she pe produced is the desired one. Assuming that 'the process is repeatable, we ~neasure the difference between the ideal and actua). part dimensions. A finite-element based model is built which mirrors the distortion from the ideal geometry. A "pre-deformed" geometry is then built so that it deforms to the ideal geometry under the conditions imposed on the finite element model. This pre-warped geometry is the geometry we seek.Mechanical Engineerin

Molecular simulations of entangled defect structures around nanoparticles in nematic liquid crystals

We investigate the defect structures forming around two nanoparticles in a Gay-Berne nematic liquid crystal using molecular simulations. For small separations, disclinations entangle both particles forming the figure of eight, the figure of omega and the figure of theta. These defect structures are similar in shape and occur with a comparable frequency to micron-sized particles studied in experiments. The simulations reveal fast transitions from one defect structure to another suggesting that particles of nanometre size cannot be bound together effectively. We identify the 'three-ring' structure observed in previous molecular simulations as a superposition of the different entangled and non-entangled states over time and conclude that it is not itself a stable defect structure.Comment: keywords: molecular-simulation, defects, nematic, disclination, algorithmic classification ; 8 pages, 7 figures, 1 tabl

No. 06: The Urban Food System of Nairobi, Kenya

Nairobi is a city of stark contrasts. Nearly half a million of its three million residents live in abject poverty in some of Africa’s largest slums, yet the Kenyan capital is also an international and regional hub. In East Africa, rapid urbanization is stretching existing food and agriculture systems as growing cities struggle to provide food and nutrition security for their inhabitants. Nairobi is no exception; it is a dynamically growing city and its food supply chains are constantly adapting and responding to changing local conditions. It is also an international city and the extent to which it is food secure is increasingly predicated on food imports from the regional East African Community and other international sources. Informal traditional value chains have a variety of actors and intermediaries that increase transaction costs and create an inefficient post-harvest procurement network, thereby pushing food products out of the reach of those who need them most. The majority of Nairobi’s food purchases are from informal food vendors. The city’s urban poor rely on the informal food sector for several reasons including that it provides food close to where they live and work, credit and barter are often available, small quantities can be purchased, and many items are sold more cheaply than at formal outlets. The leading income-generating activity for women in Nairobi’s poor communities is selling fruit and vegetables

Zeroing in on more photons and gluons

We discuss radiation zeros that are found in gauge tree amplitudes for processes involving multi-photon emission. Previous results are clarified by examples and by further elaboration. The conditions under which such amplitude zeros occur are identical in form to those for the single-photon zeros, and all radiated photons must travel parallel to each other. Any other neutral particle likewise must be massless (e.g. gluon) and travel in that common direction. The relevance to questions like gluon jet identification and computational checks is considered. We use examples to show how certain multi-photon amplitudes evade the zeros, and to demonstrate the connection to a more general result, the decoupling of an external electromagnetic plane wave in the ``null zone". Brief comments are made about zeros associated with other gauge-boson emission.Comment: 26 page

Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPh

Ortho-lithiation of Ph3P NPh followed by reaction with HgCl2 gave good yields of [Hg{C6H4(PPh2 NPh)-2}Cl], 3, which was characterised spectroscopically and by an X-ray crystal structure determination. This is an isomer of the product of direct mercuration of Ph3P NPh which occurs on the N-bonded phenyl ring [J. Vicente, J.A. Abad, R. Clemente, J. Lopez-Serrano, M.C. Ramirez de Arellano, P.G. Jones, D. Bautista, Organometallics, 22 (2003) 4248]. Transmetallation of 3 with [AuCl4]− gave the corresponding cycloaurated complex [Au{κ2-C,N-C6H4(PPh2 NPh)-2}Cl2], with a five-membered metallocyclic ring incorporating four different elements

Electronic Health Record Simulator

The Electronic Health Record Simulator is exactly that; it is meant to simulate an EHR (like those found in hospitals and clinics) for use in an academic setting. Its purpose is to familiarize students with the operation of real-world EHRs in order to better prepare them for the workforce. It allows instructors to create fictional patients (with full lab values), and allows students to fill in information as in a real EHR

Doctor of Philosophy

dissertationAccurate interpretation of seismic travel times and amplitudes in both the exploration and global scales is complicated by the band-limited nature of seismic data. We present a stochastic method, Viterbi sparse spike detection (VSSD), to reduce a seismic waveform into a most probable constituent spike train. Model waveforms are constructed from a set of candidate spike trains convolved with a source wavelet estimate. For each model waveform, a profile hidden Markov model (HMM) is constructed to represent the waveform as a stochastic generative model with a linear topology corresponding to a sequence of samples. The Viterbi algorithm is employed to simultaneously find the optimal nonlinear alignment between a model waveform and the seismic data, and to assign a score to each candidate spike train. The most probable travel times and amplitudes are inferred from the alignments of the highest scoring models. Our analyses show that the method can resolve closely spaced arrivals below traditional resolution limits and that travel time estimates are robust in the presence of random noise and source wavelet errors. We applied the VSSD method to constrain the elastic properties of a ultralow- velocity zone (ULVZ) at the core-mantle boundary beneath the Coral Sea. We analyzed vertical component short period ScP waveforms for 16 earthquakes occurring in the Tonga-Fiji trench recorded at the Alice Springs Array (ASAR) in central Australia. These waveforms show strong pre and postcursory seismic arrivals consistent with ULVZ layering. We used the VSSD method to measure differential travel-times and amplitudes of the post-cursor arrival ScSP and the precursor arrival SPcP relative to ScP. We compare our measurements to a database of approximately 340,000 synthetic seismograms finding that these data are best fit by a ULVZ model with an S-wave velocity reduction of 24%, a P-wave velocity reduction of 23%, a thickness of 8.5 km, and a density increase of 6%. We simultaneously constrain both P- and S-wave velocity reductions as a 1:1 ratio inside this ULVZ. This 1:1 ratio is not consistent with a partial melt origin to ULVZs. Rather, we demonstrate that a compositional origin is more likely