2,434 research outputs found
Multiple Rieske/cytb complexes in a single organism
AbstractMost organisms contain a single Rieske/cytb complex. This enzyme can be integrated in any respiratory or photosynthetic electron transfer chain that is quinone-based and sufficiently energy rich to allow for the turnover of three enzymes — a quinol reductase, a Rieske/cytb complex and a terminal oxidase. Despite this universal usability of the enzyme a variety of phylogenetically distant organisms have multiple copies thereof and no reason for this redundancy is obvious. In this review we present an overview of the distribution of multiple copies among species and describe their properties from the scarce experimental results, analysis of their amino acid sequences and genomic context. We discuss the predicted redox properties of the Rieske cluster in relation to the nature of the pool quinone. It appears that acidophilic iron-oxidizing bacteria specialized one of their two copies for reverse electron transfer, archaeal Thermoprotei adapted their three copies to the interaction with different oxidases and several, phylogenetically unrelated species imported a second complex with a putative heme ci that may confer some yet to be determined properties to the complex. These hypothesis and all the more the so far completely unexplained cases call for further studies and we put forward a number of suggestions for future research that we hope to be stimulating for the field. This article is part of a Special Issue entitled: Respiratory complex III and related bc complexes
Orbital excitations in LaMnO
We study the recently observed orbital excitations, orbitons, and treat
electron-electron correlations and lattice dynamics on equal footing. It is
shown that the orbiton energy and dispersion are determined by both
correlations and lattice-vibrations. The electron-phonon coupling causes
satellite structures in the orbiton spectral function and the elementary
excitations of the system are mixed modes with both orbital and phonon
character. It is proposed that the satellite structures observed in recent
Raman-scattering experiments on LaMnO are actually orbiton derived
satellites in the phonon spectral function, caused by the phonon-orbiton
interaction.Comment: 4 pages, 3 figures embedde
Shape Invariance in the Calogero and Calogero-Sutherland Models
We show that the Calogero and Calogero-Sutherland models possess an N-body
generalization of shape invariance. We obtain the operator representation that
gives rise to this result, and discuss the implications of this result,
including the possibility of solving these models using algebraic methods based
on this shape invariance. Our representation gives us a natural way to
construct supersymmetric generalizations of these models, which are interesting
both in their own right and for the insights they offer in connection with the
exact solubility of these models.Comment: Latex file, 23 pages, no picture
Photoemission spectra of LaMnO3 controlled by orbital excitations
We investigate the spectral function of a hole moving in the orbital-ordered
ferromagnetic planes of LaMnO, and show that it depends critically on the
type of orbital ordering. While the hole does not couple to the spin
excitations, it interacts strongly with the excitations of orbitals
(orbitons), leading to new type of quasiparticles with a dispersion on the
orbiton energy scale and with strongly enhanced mass and reduced weight.
Therefore we predict a large redistribution of spectral weight with respect to
the bands found in local density approximation (LDA) or in LDA+U.Comment: 4 pages, 4 figures, 3 figures embedded, figure 3 correcte
Green's Function for Nonlocal Potentials
The single-particle nuclear potential is intrinsically nonlocal. In this
paper, we consider nonlocalities which arise from the many-body and fermionic
nature of the nucleus. We investigate the effects of nonlocality in the nuclear
potential by developing the Green's function for nonlocal potentials. The
formal Green's function integral is solved analytically in two different limits
of the wavelength as compared to the scale of nonlocality. Both results are
studied in a quasi-free limit. The results illuminate some of the basic effects
of nonlocality in the nuclear medium.Comment: Accepted for publication in J. Phys.
Resonant Inelastic X-ray Scattering Studies of Elementary Excitations
In the past decade, Resonant Inelastic X-ray Scattering (RIXS) has made
remarkable progress as a spectroscopic technique. This is a direct result of
the availability of high-brilliance synchrotron X-ray radiation sources and of
advanced photon detection instrumentation. The technique's unique capability to
probe elementary excitations in complex materials by measuring their energy-,
momentum-, and polarization-dependence has brought RIXS to the forefront of
experimental photon science. We review both the experimental and theoretical
RIXS investigations of the past decade, focusing on those determining the
low-energy charge, spin, orbital and lattice excitations of solids. We present
the fundamentals of RIXS as an experimental method and then review the
theoretical state of affairs, its recent developments and discuss the different
(approximate) methods to compute the dynamical RIXS response. The last decade's
body of experimental RIXS data and its interpretation is surveyed, with an
emphasis on RIXS studies of correlated electron systems, especially transition
metal compounds. Finally, we discuss the promise that RIXS holds for the near
future, particularly in view of the advent of x-ray laser photon sources.Comment: Review, 67 pages, 44 figure
Subcritical Superstrings
We introduce the Liouville mode into the Green-Schwarz superstring. Like
massive supersymmetry without central charges, there is no kappa symmetry.
However, the second-class constraints (and corresponding Wess-Zumino term)
remain, and can be solved by (twisted) chiral superspace in dimensions D=4 and
6. The matter conformal anomaly is c = 4-D < 1. It thus can be canceled for
physical dimensions by the usual Liouville methods, unlike the bosonic string
(for which the consistency condition is c = D <= 1).Comment: 9 pg., compressed postscript file (.ps.Z), other formats (.dvi, .ps,
.ps.Z, 8-bit .tex) available at
http://insti.physics.sunysb.edu/~siegel/preprints/ or at
ftp://max.physics.sunysb.edu/preprints/siege
Green-Schwarz Formulation of Self-Dual Superstring
The self-dual superstring has been described previously in a
Neveu-Schwarz-Ramond formulation with local N=2 or 4 world-sheet supersymmetry.
We present a Green-Schwarz-type formulation, with manifest spacetime
supersymmetry.Comment: 11 pg., (uuencoded dvi file) ITP-SB-92-5
Evidence for weak electronic correlations in Fe-pnictides
Using x-ray absorption and resonant inelastic x-ray scattering, charge
dynamics at and near the Fe edges is investigated in Fe pnictide materials,
and contrasted to that measured in other Fe compounds. It is shown that the XAS
and RIXS spectra for 122 and 1111 Fe pnictides are each qualitatively similar
to Fe metal. Cluster diagonalization, multiplet, and density-functional
calculations show that Coulomb correlations are much smaller than in the
cuprates, highlighting the role of Fe metallicity and strong covalency in these
materials. Best agreement with experiment is obtained using Hubbard parameters
eV and eV.Comment: 11 pages, 12 figure
Effect of magnetic frustration on single-hole spectral function in the t-t'-t''-J model
We examine the effect of the magnetic frustration J' on the single-hole
spectral function in the t-t'-t''-J model. At zero temperature, the exact
diagonalization (ED) and the self-consistent Born approximation (SCBA) methods
are used. We find that the frustration suppresses the quasiparticle (QP) weight
at small momentum k, whereas the QP peak at k=(pi/2,pi/2) remains sharp. We
also show the temperature dependence of the single-hole spectral function by
using the ED method. It is found that the lineshapes at (pi/2,0) and
(pi/2,pi/2) show different temperature dependence. These findings are
consistent with the angle-resolved photoemission data on Sr2CuO2Cl2, and
indicate the importance of the magnetic frustration on the electronic states of
the insulating cuprates.Comment: 5 pages, 3 EPS figures, REVTeX, To be published in Phys. Rev. B, Vol.
59, Num. 3 (15 Jan. 1999
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