Nonlinear oscillations of compact stars in the vicinity of the maximum mass configuration

We solve the dynamical GR equations for the spherically symmetric evolution of compact stars in the vicinity of the maximum mass, for which instability sets in according to linear perturbation theory. The calculations are done with the analytical Zeldovich-like EOS P=a(rho-rho_0) and with the TM1 parametrisation of the RMF model. The initial configurations for the dynamical calculations are represented by spherical stars with equilibrium density profile, which are perturbed by either (i) an artificially added inward velocity field proportional to the radial coordinate, or (ii) a rarefaction corresponding to a static and expanded star. These configurations are evolved using a one-dimensional GR hydro code for ideal and barotropic fluids. Depending on the initial conditions we obtain either stable oscillations or the collapse to a black hole. The minimal amplitude of the perturbation, needed to trigger gravitational collapse is evaluated. The approximate independence of this energy on the type of perturbation is pointed out. At the threshold we find type I critical behaviour for all stellar models considered and discuss the dependence of the time scaling exponent on the baryon mass and EOS.Comment: 15 pages, 8 figures, accepted for publication in EP

Radial oscillations of neutral and charged hybrid stars

We construct stellar models of hadron stars and hybrid stars and calculate the frequencies of their lowest radial mode of vibration. Chandrasekhar's equation for radial oscillations is generalized for stars with internal electric fields and earlier versions of that generalization are simplified. For the hybrid stars a Gibbs construction is employed. It is found that the softening of the equation of state associated with the presence of deconfined quarks reduces the oscillation frequency. We show that a slight charge inbalance should lead to increased maximum mass, decreased central density and lower oscillation frequencies

A new type of neutral-ionic interface in mixed-stack organic charge-tranfer crystals: Temperature induced ionicity change in ClMePD-DMeDCNQI

Raman and polarized infrared spectra of the mixed stack charge transfer crystal 2-chloro-5methyl-p-phenylendiamine- -2,5-dimethyl-dicyanoquinonediimine (ClMePD-DMeDCNQI) are reported as a function of temperature. A detailed spectral interpretation allows us to gain new insight into the temperature induced neutral-ionic transition in this compound. In particular, the crossing of the neutral-ionic borderline appears to be quite different from that of the few known temperature induced neutral-ionic phase transitions. First of all, the ionicity change is continuous. Furthermore, the onset of stack dimerization precedes, rather than accompanies, the neutral-ionic crossing. The (second order) phase transition is then driven by the dimerization, but the extent of dimerization is in turn affected by the ionicity change.Comment: LaTex (revTeX), 6 figures. Yields 10 pages postscript (including figures

Finding your place in this world: a quantitative study exploring the geo-literacy skills and content knowledge taught to students with disabilities educated in segregated special education classrooms.

This study was designed to investigate if there was (a) a statistically significant relationship between the different classroom placements special education students were educated in, and instruction in the core subject area of geography and (b) gather the reported beliefs of special education teachers who are teaching in segregated classrooms, about the importance of geographic skills and content knowledge in order for students with disabilities to be able to self-advocate in the future. The results of this study identified that there were statistically significant relationships found across all of the standards highlighting the difference of where a student was educated and their access to the same amount of geography related books and materials as their typically developing peers. It was reported by the teachers that students educated outside of schools where typical peers were present had far less access to these material than their typical peers as compared to students in segregated classrooms in schools with typically developing peers were present. There were also statistically significant relationships found across all of the standards as teachers reported that students educated in schools without typically developing peers made far less progress made towards geography standards as compared to their typical peers as did students educated in segregated classrooms in schools with typically developing peers were present. In the area of participation in activities and instruction in geography topics, most of the standards did not show a statistical significance between placements in schools with typical peers and without, but most instances that data showed that none of the students educated outside of the general education classroom were participating in instruction in geography topics. Additionally, special education teachers teaching in segregated settings reported that they did not feel that the majority of the geography skills and knowledge presented in the survey were very important or essential for students with disabilities to know in order to be able to self-advocate and live as independently as possible in the future

Pressure driven neutral-ionic transition in ClMePD-DMeDCNQI

Application of about 0.8 GPa pressure is sufficient to induce the neutral-ionic transition in the mixed stack charge-transfer crystal 2-chloro-5-methyl-$p$-phenylenediamine--2,5-dimethyl-dicyanoquinonediimine ({\CD}). The ionicity increases continuously from $\sim$ 0.35 at ambient conditions to $\sim$ 0.65 when the pressure is raised up to 2 GPa. Moreover, stack dimerization begins well before the crossing of the neutral-ionic interface. The evolution of the transition is similar to what observed in the temperature induced phase change in the same compound. (cond-mat/0101179) A distinguishing feature is represented by the simultaneous presence of domains of molecules with slightly different ionicities across the transition pressure. A comparison of the present example of pressure driven neutral-ionic transition with the well studied cases of tetrathiafulvalene--chloranil and of tetrathiafulvalene--2,5-dichloro-p-benzoquinone puts in evidence the remarkably different evolution of the three transitions.Comment: 6 pages in *.PS format, 5 figure

A new type of neutral-ionic interface in mixed-stack organic charge-tranfer crystals: Temperature induced ionicity change in ClMePD-DMeDCNQI

Raman and polarized infrared spectra of the mixed stack charge transfer crystal 2-chloro-5methyl-p-phenylendiamine- -2,5-dimethyl-dicyanoquinonediimine (ClMePD-DMeDCNQI) are reported as a function of temperature. A detailed spectral interpretation allows us to gain new insight into the temperature induced neutral-ionic transition in this compound. In particular, the crossing of the neutral-ionic borderline appears to be quite different from that of the few known temperature induced neutral-ionic phase transitions. First of all, the ionicity change is continuous. Furthermore, the onset of stack dimerization precedes, rather than accompanies, the neutral-ionic crossing. The (second order) phase transition is then driven by the dimerization, but the extent of dimerization is in turn affected by the ionicity change.Comment: LaTex (revTeX), 6 figures. Yields 10 pages postscript (including figures

A New Approach to Polymorphism in Molecular Crystals: Substrate-Mediated Structures Revealed by Lattice Phonon Dynamics

The issue of polymorphism in molecular crystals is discussed, taking into account the substrate-mediated structures, that is, structures grown at the interface of different substrates. Bulk and thin films of a compound both share the potentiality to display different crystal forms. However, unlike bulk polymorphs, whose structures are determined by their different molecular packing, thin film structures depend very much on the molecular organization of the organic layers on the substrate, which may, or may not, lead to an ordered structure, depending on the nature of the interface and on the growth conditions. Based on large part in some of the authors' recent works, these thin film structures are classified as distorted bulk, substrate-selected and substrate-stabilized polymorphs, with some subtle differences which may yield a polymorph to belong not exclusively to a single one of these categories. Some experiments are then focused upon, involving charge transport at the interface, as well as how far the effect of the surface goes. Furthermore, the authors comment on how the surface-mediated structures evolve to the single crystal phase in the cases of pentacene and alpha-sexithiophene. Finally, the transition from a 3- to a 2D regime of growth is shortly discussed in terms of low-dimensional disorder

Polymorphism, phonon dynamics and carrier-phonon coupling in pentacene

The crystal structure and phonon dynamics of pentacene is computed with the Quasi Harmonic Lattice Dynamics (QHLD) method, based on atom-atom potential. We show that two crystalline phases of pentacene exist, rather similar in thermodynamic stability and in molecular density. The two phases can be easily distinguished by Raman spectroscopy in the 10-100 cm-1 spectral region. We have not found any temperature induced phase transition, whereas a sluggish phase change to the denser phase is induced by pressure. The bandwidths of the two phases are slightly different. The charge carrier coupling to low-frequency phonons is calculated.Comment: 6 pages, 3 figures. Presented at ICFPAM-