Electrically driven spin resonance in a bent disordered carbon nanotube

Resonant manipulation of carbon nanotube valley-spin qubits by an electric field is investigated theoretically. We develop a new analysis of electrically driven spin resonance exploiting fixed physical characteristics of the nanotube: a bend and inhomogeneous disorder. The spectrum is simulated for an electron valley-spin qubit coupled to a hole valley-spin qubit and an impurity electron spin, and features that coincide with a recent measurement are identified. We show that the same mechanism allows resonant control of the full four-dimensional spin-valley space.Comment: 11 pages, 7 figure

Quantum sensors based on weak-value amplification cannot overcome decoherence

Sensors that harness exclusively quantum phenomena (such as entanglement) can achieve superior performance compared to those employing only classical principles. Recently, a technique based on postselected, weakly-performed measurements has emerged as a method of overcoming technical noise in the detection and estimation of small interaction parameters, particularly in optical systems. The question of which other types of noise may be combatted remains open. We here analyze whether the effect can overcome decoherence in a typical field sensing scenario. Benchmarking a weak, postselected measurement strategy against a strong, direct strategy we conclude that no advantage is achievable, and that even a small amount of decoherence proves catastrophic to the weak-value amplification technique.Comment: Published version with improvements to presentation, including clarifying our understanding of technical noise and quantum nois

Seeing opportunity in every difficulty: protecting information with weak value techniques

A weak value is an effective description of the influence of a pre and post-selected 'principal' system on another 'meter' system to which it is weakly coupled. Weak values can describe anomalously large deflections of the meter, and deflections in otherwise unperturbed variables: this motivates investigation of the potential benefits of the protocol in precision metrology. We present a visual interpretation of weak value experiments in phase space, enabling an evaluation of the effects of three types of detector noise as 'Fisher information efficiency' functions. These functions depend on the marginal distribution of the Wigner function of the meter, and give a unified view of the weak value protocol as a way of protecting Fisher information from detector imperfections. This approach explains why weak value techniques are more effective for avoiding detector saturation than for mitigating detector jitter or pixelation.Comment: 17 pp, 4 figs, Quantum Stud.: Math. Found. (2018

Creating excitonic entanglement in quantum dots through the optical Stark effect

We show that two initially non-resonant quantum dots may be brought into resonance by the application of a single detuned laser. This allows for control of the inter-dot interactions and the generation of highly entangled excitonic states on the picosecond timescale. Along with arbitrary single qubit manipulations, this system would be sufficient for the demonstration of a prototype excitonic quantum computer.Comment: 4 pages, 3 figures; published version, figure 3 improved, corrections to RWA derive

Electron spin relaxation of N@C60 in CS2

We examine the temperature dependence of the relaxation times of the molecules N@C60 and N@C70 (which comprise atomic nitrogen trapped within a carbon cage) in liquid CS2 solution. The results are inconsistent with the fluctuating zero field splitting (ZFS) mechanism, which is commonly invoked to explain electron spin relaxation for S > 1/2 spins in liquid solution, and is the mechanism postulated in the literature for these systems. Instead, we find a clear Arrhenius temperature dependence for N@C60, indicating the spin relaxation is driven primarily by an Orbach process. For the asymmetric N@C70 molecule, which has a permanent non-zero ZFS, we resolve an additional relaxation mechanism caused by the rapid reorientation of its ZFS. We also report the longest coherence time (T2) ever observed for a molecular electron spin, being 0.25 ms at 170K.Comment: 6 pages, 6 figures V2: Updated to published versio

Switchable ErSc2N rotor within a C80 fullerene cage: An EPR and photoluminescence excitation study

Systems exhibiting both spin and orbital degrees of freedom, of which Er3+ is one, can offer mechanisms for manipulating and measuring spin states via optical excitations. Motivated by the possibility of observing photoluminescence and electron paramagnetic resonance from the same species located within a fullerene molecule, we initiated an EPR study of Er3+ in ErSc2N@C80. Two orientations of the ErSc2N rotor within the C80 fullerene are observed in EPR, consistent with earlier studies using photoluminescence excitation (PLE) spectroscopy. For some crystal field orientations, electron spin relaxation is driven by an Orbach process via the first excited electronic state of the 4I_15/2 multiplet. We observe a change in the relative populations of the two ErSc2N configurations upon the application of 532 nm illuminations, and are thus able to switch the majority cage symmetry. This photoisomerisation, observable by both EPR and PLE, is metastable, lasting many hours at 20 K.Comment: 4 pages, 4 figure