466 research outputs found
Effect of Structural Parameters on Superconductivity in Fluorine-Free LnFeAsO1-y (Ln=La,Nd)
The crystal structure of LnFeAsO (Ln = La, Nd) has been studied by
the powder neutron diffraction technique. The superconducting phase diagram of
NdFeAsO is established as a function of oxygen content which is
determined by Rietveld refinement. The small As-Fe bond length suggests that As
and Fe atoms are connected covalently. FeAs-tetrahedrons transform toward a
regular shape with increasing oxygen deficiency. Superconducting transition
temperatures seem to attain maximum values for regular FeAs-tetrahedrons
Low-Temperature Structure of the Quarter-Filled Ladder Compound alpha'-NaV2O5
The low-temperature (LT) superstructure of -NaVO was
determined by synchrotron radiation x-ray diffraction. Below the phase
transition temperature associated with atomic displacement and charge ordering
at 34K, we observed the Bragg peak splittings, which evidence that the LT
structure is monoclinic. It was determined that the LT structure is
with the space group where and
represent the high temperature orthorhombic unit cell. The valence estimation
of V ions according to the bond valence sum method shows that the V sites are
clearly separated into two groups of V and V with a
charge ordering pattern. This LT structure is consistent with resonant x-ray
and NMR measurements, and strikingly contrasts to the LT structure previously
reported, which includes V sites.Comment: 4 pages, 3 figures, 1 tabl
Coupling to optical phonons in the one-dimensional t-J model: Effects on superconducting fluctuations and phase separation
The one-dimensional (1D) - Holstein model is studied by exact
diagonalization of finite rings using a variational approximation for the
phonon states. Due to renormalization effects induced by the phonons, for
intermediate electron-phonon coupling, the phase separation (PS) boundary, and
with it the region of dominating superconducting fluctuations is shifted
substantially to smaller values of as compared to the pure - model.
Superconducting correlations are weakened through charge density wave
interactions mediated by the phonons. Possible consequences for the high
oxides are discussed.Comment: 4 pages, Latex2
The Structure of Nanoscale Polaron Correlations in La1.2Sr1.8Mn2O7
A system of strongly-interacting electron-lattice polarons can exhibit charge
and orbital order at sufficiently high polaron concentrations. In this study,
the structure of short-range polaron correlations in the layered colossal
magnetoresistive perovskite manganite, La1.2Sr1.8Mn2O7, has been determined by
a crystallographic analysis of broad satellite maxima observed in diffuse X-ray
and neutron scattering data. The resulting q=(0.3,0,1) modulation is a
longitudinal octahedral-stretch mode, consistent with an incommensurate
Jahn-Teller-coupled charge-density-wave fluctuations, that implies an unusual
orbital-stripe pattern parallel to the directions.Comment: Reformatted with RevTe
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Ternary erbium chromium sulfides : structural relationships and magnetic properties
Single crystals of four erbium-chromium sulfides have been grown by chemical vapor transport using iodine as the transporting agent. Single-crystal X-ray diffraction reveals that in Er(3)CrS(6) octahedral sites are occupied exclusively by Cr(3+) cations, leading to one-dimensional CrS(4)(5-) chains of edge-sharing octahedra, while in Er(2)CrS(4), Er(3+), and Cr(2+) cations occupy the available octahedral sites in an ordered manner. By contrast, in Er(6)Cr(2)S(11) and Er(4)CrS(7), Er(3+) and Cr(2+) ions are disordered over the octahedral sites. In Er(2)CrS(4), Er(6)Cr(2)S(11), and Er(4)CrS(7), the network of octahedra generates an anionic framework constructed from M(2)S(5) slabs of varying thickness, linked by one-dimensional octahedral chains. This suggests that these three phases belong to a series in which the anionic framework may be described by the general formula [M(2n+1)S(4n+3)](x-), with charge balancing provided by Er(3+) cations located in sites of high-coordination number within one-dimensional channels defined by the framework. Er(4)CrS(7), Er(6)Cr(2)S(11), and Er(2)CrS(4) may thus be considered as the n = 1, 2, and infinity members of this series. While Er(4)CrS(7) is paramagnetic, successive magnetic transitions associated with ordering of the chromium and erbium sub-lattices are observed on cooling Er(3)CrS(6) (T(C)(Cr) = 30 K; T(C)(Er) = 11 K) and Er(2)CrS(4) (T(N)(Cr) = 42 K, T(N)(Er) = 10 K) whereas Er(6)Cr(2)S(11) exhibits ordering of the chromium sub-lattice only (T(N) = 11.4 K)
An oxalate cathode for lithium ion batteries with combined cationic and polyanionic redox
Authors acknowledge financial support from the National Natural Science Foundation of China (51822210), the Australian Research Council (ARC) for its support through Discover Project (DP 140100193),Shenzhen Peacock Plan (KQJSCX20170331161244761), the Program for Guangdong Innovative and Entrepreneurial Teams (No. 2017ZT07C341), and the Development and Reform Commission of Shenzhen Municipality for the development of the “Low-Dimensional Materials and Devices” discipline.The growing demand for advanced lithium-ion batteries calls for the continued development of high-performance positive electrode materials. Polyoxyanion compounds are receiving considerable interest as alternative cathodes to conventional oxides due to their advantages in cost, safety and environmental friendliness. However, polyanionic cathodes reported so far rely heavily upon transition-metal redox reactions for lithium transfer. Here we show a polyanionic insertion material, Li2Fe(C2O4)2, in which in addition to iron redox activity, the oxalate group itself also shows redox behavior enabling reversible charge/discharge and high capacity without gas evolution. The current study gives oxalate a role as a family of cathode materials and suggests a direction for the identification and design of electrode materials with polyanionic frameworks.Publisher PDFPeer reviewe
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