A calibration line list for 807-1167 cm -1 from high resolution Fourier spectroscopy of the 14NH3 nu sub 2 band

A calibration list of 295 lines observed over the 800 to 1170 cm to the -1 power region is presented. This list is intended for use as a calibration reference for calibrating diode laser spectra. The transition frequencies were calibrated against the well established laser frequencies of CO2. The estimated uncertainty in the corrected frequencies is + or - 1x.0001 cm to the -1 power

Lifetimes, transition probabilities, and level energies in Fe I

We use time-resolved laser-induced fluorescence to measure the lifetime of 186 Fe levels with energies between 25 900 and 60 758 cm . Measured emission branching fractions for these levels yield transition probabilities for 1174 transitions in the range 225-2666 nm. We find another 640 Fe transition probabilities by interpolating level populations in the inductively coupled plasma spectral source. We demonstrate the reliability of the interpolation method by comparing our transition probabilities with absorption oscillator strengths measured by the Oxford group [Blackwell et al., Mon. Not. R. Astron. Soc. 201, 595-602 (1982)]. We derive precise Fe level energies to support the automated method that is used to identify transitions in our spectra

Argon I lines produced in a hollow cathode source, 332 nm to 5865 nm

We report precision measurements by Fourier transform spectroscopy of the vacuum wavenumber, line width, and relative signal strength of 928 lines in the Ar I spectrum. Wavelength in air and classification of the transition are supplied for each line. A comparison of our results with other precision measurements illustrates the sensitivity of Ar I wavelengths to conditions in the light source

A facility for high resolution spectroscopy: Laboratory and ground based observations in support of upper atmospheric research

This research task consists of operating a facility for making spectroscopic observations in support of upper atmospheric research. The facility responds to the needs and interests of the visiting investigators. Therefore, the research objectives are not predetermined except in broad outline. The emphasis is on studies that take advantage of the particular strengths of the Fourier Transform Spectrometer on Kitt Peak: high spectral resolution combined with wide spectral range and low noise

The 12 micron band of ethane: A spectral catalog from 765 cm(-1) to 900 cm(-1)

The high resolution laboratory absorption spectrum of the 12 micro band of ethane gas is studied. The data were obtained using the McMath Solar Telescope 1 meter Fourier Transform interferometer at Kitt Peak National Observatory and tunable diode laser spectrometers at the University of Tennessee and NASA/Goddard Space Flight Center. Over 200 individual vibration rotation transitions were analyzed taking into account many higher order effects including torsional splitting. Line positions were reproduced to better than 0.001/cm. Both ground and upper state molecular constants were determined in the analysis. The experimental details, the analysis procedures and the results are addressed. A list of ethane transitions occurring near (14)CO2 laser lines needed for heterodyne searches for C2H6 in extraterrestrial sources is also included. A spectral catalog of the ethane nu sub g fundamental from 765/cm to 900/cm is provided. A high dispersion (1/cm 12 in.) plot of both the Kitt Peak interferometric data and a simulated spectrum with Doppler limited resolution, a table of over 8500 calculated transitions listed quantum number assignments, frequencies and intensities are provided

Reaction of C_2(a^3Pi_u) with methanol: Temperature dependence and deuterium isotope effect

We present a first temperature dependence and kinetic isotope effect study on the reaction of C_2(a^3Pi_u) with methanol. The bimolecular rate constants for a series of methanol isotopomers have been measured as a function of temperature between 293 and 673 K. The observed positive temperature dependences as well as deuterium kinetic isotope effects permit determination of the reaction mechanism as a site-specific hydrogen abstraction from the methyl site rather than from the hydroxyl site.Comment: 27 pages, 6 figures, 3 tables, 54 references; accepted to JC

Unified set of atomic transition probabilities for neutral argon

The atomic transition probabilities and radiative lifetimes of neutral argon have been the subject of numerous experiments and calculations, but the results exhibit many discrepancies and inconsistencies. We present a unified set of atomic transition probabilities, which is consistent with essentially all recent results, albeit sometimes only after critical reanalysis. The data consistency and scale confirmation has been achieved in two ways. (i) We have carried out some lifetime–branching-ratio measurements for a principal 5p level and the associated 4s-5p transitions. These measurements have very closely confirmed the accuracy of the results of recent independent emission experiments. (ii) We have critically reanalyzed and revised the literature data for the 4s-4p transitions, as well as utilized the results of a similar critical analysis for the 4s-5p transition array, to establish complete sets of absolute data for these arrays. We have found these data to be mutually consistent from cross-correlation checks between the two arrays, using recent literature data. Finally, we have proposed renormalization factors for other argon transitions based on this analysis

Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes

A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.Comment: 90 pages, 19 figures (some with parts "a", "b", etc.); to be published in the Astrophysical Journal Supplement

Argon I lines produced in a hollow cathode source, 332 nm to 5865 nm

We report precision measurements by Fourier transform spectroscopy of the vacuum wavenumber, line width, and relative signal strength of 928 lines in the Ar I spectrum. Wavelength in air and classification of the transition are supplied for each line. A comparison of our results with other precision measurements illustrates the sensitivity of Ar I wavelengths to conditions in the light source