Plasmon Evolution and Charge-Density Wave Suppression in Potassium Intercalated Tantalum Diselenide

We have investigated the influence of potassium intercalation on the formation of the charge-density wave (CDW) instability in 2H-tantalum diselenide by means of Electron Energy-Loss Spectroscopy and density functional theory. Our observations are consistent with a filling of the conduction band as indicated by a substantial decrease of the plasma frequency in experiment and theory. In addition, elastic scattering clearly points to a destruction of the CDW upon intercalation as can be seen by a vanishing of the corresponding superstructures. This is accompanied by a new superstructure, which can be attributed to the intercalated potassium. Based on the behavior of the c-axis upon intercalation we argue in favor of interlayer-sites for the alkali-metal and that the lattice remains in the 2H-modification

Global existence of classical solutions to the Vlasov-Poisson system in a three dimensional, cosmological setting

The initial value problem for the Vlasov-Poisson system is by now well understood in the case of an isolated system where, by definition, the distribution function of the particles as well as the gravitational potential vanish at spatial infinity. Here we start with homogeneous solutions, which have a spatially constant, non-zero mass density and which describe the mass distribution in a Newtonian model of the universe. These homogeneous states can be constructed explicitly, and we consider deviations from such homogeneous states, which then satisfy a modified version of the Vlasov-Poisson system. We prove global existence and uniqueness of classical solutions to the corresponding initial value problem for initial data which represent spatially periodic deviations from homogeneous states.Comment: 23 pages, Latex, report #

Empirical logic of finite automata: microstatements versus macrostatements

We compare the two approaches to the empirical logic of automata. The first, called partition logic (logic of microstatements), refers to experiments on individual automata. The second one, the logic of simulation (logic of macrostatements), deals with ensembles of automata.Comment: late

Thermal Analysis of EPOS components

We present a simulation study of the thermal behaviour of essential parts of the electron-positron converter of the positron source EPOS at the Research Center Dresden-Rossendorf. The positron moderator foil and the upper tube element of the electrostatic extraction einzellens are directly exposed to the primary electron beam (40 MeV, 40 kW). Thus, it was necessary to prove by sophisticated simulations that the construction can stand the evolving temperatures. It was found that thin moderator foils (< 20...40 µm) will not show a too strong heating. Moreover, the temperature can be varied in a wide range by choosing an appropriate thickness. Thus, the radiation-induced lattice defects can at least partly be annealed during operation. The wall of the extraction lens which is made from a stainless steel tube must be distinctly thinned to avoid damage temperatures. The simulations were performed time dependent. We found that the critical parts reach their final temperature after less than a minute

High Temporal Resolution Tropospheric Wind Profile Observations at NASA Kennedy Space Center during Hurricane Irma

The National Aeronautics and Space Administration's (NASA) Kennedy Space Center (KSC) operates a 48-MHz Tropospheric/Stratospheric Doppler Radar Wind Profiler (TDRWP) on a continual basis generating wind profiles between 2-19 km (approximately 6.6-62.3 kft) in the support of space launch vehicle operations. A benefit of the continual operability of the system is the ability to provide unique observations of severe weather events such as hurricanes. On the evening of 10 September 2017, Hurricane Irma passed within 160 km (87 nmi) to the west of KSC through the middle of the Florida peninsula. The hurricane was responsible for power outages to approximately 2/3 of Florida's population (Stein, 2017). This paper will provide an overview of the TDRWP system, describe the characteristics of the wind observations from the TDRWP during Irma passage, provide a comparison to previous TDRWP observations from Hurricane Matthew in 2016, and provide the location where TDRWP data is available to the meteorological community

Matrix-free calcium in isolated chromaffin vesicles

Isolated secretory vesicles from bovine adrenal medulla contain 80 nmol of Ca2+ and 25 nmol of Mg2+ per milligram of protein. As determined with a Ca2+-selective electrode, a further accumulation of about 160 nmol of Ca2+/mg of protein can be attained upon addition of the Ca2+ ionophore A23187. During this process protons are released from the vesicles, in exchange for Ca2+ ions, as indicated by the decrease of the pH in the incubation medium or the release of 9-aminoacridine previously taken up by the vesicles. Intravesicular Mg2+ is not released from the vesicles by A23 187, as determined by atomic emission spectroscopy. In the presence of N H Q , which causes the collapse of the secretory vesicle transmembrane proton gradient (ApH), Ca2+ uptake decreases. Under these conditions A23 187-mediated influx of Ca2+ and efflux of H+ cease at Ca2+ concentrations of about 4 pM. Below this concentration Ca2+ is even released from the vesicles. At the Ca2+ concentration at which no net flux of ions occurs the intravesicular matrix free Ca2+ equals the extravesicular free Ca2+. In the absence of NH4C1 we determined an intravesicular pH of 6.2. Under these conditions the Ca2+ influx ceases around 0.15 pM. From this value and the known pH across the vesicular membrane an intravesicular matrix free Ca2+ concentration of about 24 pM was calculated. This is within the same order of magnitude as the concentration of free Ca2+ in the vesicles determined in the presence of NH4C1. Calculation of the total Ca2+ present in the secretory vesicles gives an apparent intravesicular Ca2+ concentration of 40 mM, which is a factor of lo4 higher than the free intravesicular concentration of Ca2+. It can be concluded, therefore, that the concentration gradient of free Ca2+ across the secretory vesicle membrane in the intact chromaffin cells is probably small, which implies that less energy is required to accumulate and maintain Ca2+ within the vesicles than was previously anticipated

Terahertz Time-Domain Spectroscopy Study of the Conductivity of Hole-Transporting Materials

Some redox-active ionic liquids, organic amorphous solids containing electron-donating moieties, and conductive polymers can efficiently transport positive electrical charges. These hole-conducting media find increasing applications in unconventional solar cells and organic light-emitting diodes. Appropriate methods are required to unravel the detailed conduction and trapping mechanisms in these materials as well as to fully understand the interplay of molecular vibrations and charge transport processes. Here we present terahertz time-domain spectroscopy (THz-TDS) as a powerful technique, that allows the direct determination of the complex conductivity of hole transporting materials in a contactless, purely optical manner. Beyond the measurement of the conductivity of solid and liquid materials, THz (far infrared) spectroscopy also provides direct information of the librational and vibrational modes coupled to charge transport processes and therefore is invaluable in the study of the mechanism of polaronic transport in matter. Application of this technique is illustrated by examples provided by the study of the ionic liquid 3-methyl-1-propylimidazolium bis(trifluoromethane) sulfonimide (PMIT FSI) and that of the molecular liquid hole conductor 10-methylphenoxazine. Both systems are of particular interest, as both types of holetransporting media are successfully used as alternatives to solvent-based electrolytes in dye sensitized solar cell

Effects of Monovalent and Divalent Cations on Ca2+ Fluxes Across Chromaffin Secretory Membrane Vesicles

Abstract: Bovine chromaffin secretory vesicle ghosts loaded with Na+ were found to take up Ca2+ when incubated in K+ media or in sucrose media containing micromolar concentrations of free Ca2+. Li+- or choline+loaded ghosts did not take up Ca2+. The Ca2+ accumulated by Na+-loaded ghosts could be released by the Ca2+ ionophore A23187, but not by EGTA. Ca2+ uptake was inhibited by external Sr2+, Na +, Li +, or choline +. All the 45Ca2+ accumulated by Na+-dependent Ca2+ uptake could be released by external Na +, indicating that both Ca2+ influx and efflux occur in a Na+-dependent manner. Na + -dependent Ca2+ uptake and release were only slightly inhibited by Mg2+. In the presence of the Na+ ionophore Monensin the Ca2+ uptake by Na +-loaded ghosts was reduced. Ca2+ sequestered by the Na+-dependent mechanism could also be released by external Ca2+ or Sr2+ but not by Mg2+, indicating the presence of a Ca2+/Ca2+ exchange activity in secretory membrane vesicles. This Ca2+/Ca2+ exchange system is inhibited by Mg2+, but not by Sr2+. The Na + -dependent Ca2+ uptake system in the presence of Mg2+ is a saturable process with an apparent Km of 0.28 μM and a Vmax= 14.5 nmol min−1 mg protein−1. Ruthenium red inhibited neither the Na+/Ca2+ nor the Ca2+/Ca2+ exchange, even at high concentrations

Validation of Kalman Filter alignment algorithm with cosmic-ray data using a CMS silicon strip tracker endcap

A Kalman Filter alignment algorithm has been applied to cosmic-ray data. We discuss the alignment algorithm and an experiment-independent implementation including outlier rejection and treatment of weakly determined parameters. Using this implementation, the algorithm has been applied to data recorded with one CMS silicon tracker endcap. Results are compared to both photogrammetry measurements and data obtained from a dedicated hardware alignment system, and good agreement is observed.Comment: 11 pages, 8 figures. CMS NOTE-2010/00

“In small places, close to home”: urban environmental impacts on child rights across four global cities

Urban environments influence child behaviours, exposures and experiences and may affect health, development, achievement and realization of fundamental human rights. We examined the status of eleven UN Convention on the Rights of the Child articles, in a multi-case study across four global cities. Within all study cities, children experienced unequal exposure to urban environmental risks and amenities. Many violations of child rights are related to car-based transportation systems and further challenged by pressures on urban systems from rapid population increases in the context of climate change. A child rights framework provides principles for a collective, multi-sectoral re-imagination of urban environments that support the human rights of all citizens