Analyzing the Intensities of K‑Edge Transitions in X2 Molecules (X = F, Cl, Br) for Use in Ligand K‑Edge X‑ray Absorption Spectroscopy

Ligand K-edge X-ray absorption spectroscopy (XAS) is regularly used to determine the ligand contribution to metal-ligand bonds. For quantitative studies, the pre-edge transition intensities must be referenced to an intensity standard, and pre-edge intensities obtained from different ligand atoms cannot be compared without standardization due to different cross sections at each absorption edge. In this work, the intensities of the 1s → σ* transitions in F2, Cl2, and Br2 are analyzed for their use as references for ligand K-edge XAS. We show that the intensities of these transitions are equal to the intensities of the 1s → np transitions in the unbound halogens. This finding is supported by a comparison between the normalized experimental intensities for the molecules and the calculated oscillator strengths for the atoms. These results highlight the potential for these molecules to be used as intensity standards in F, Cl, and Br K-edge XAS experiments

Further functional determinants

Functional determinants for the scalar Laplacian on spherical caps and slices, flat balls, shells and generalised cylinders are evaluated in two, three and four dimensions using conformal techniques. Both Dirichlet and Robin boundary conditions are allowed for. Some effects of non-smooth boundaries are discussed; in particular the 3-hemiball and the 3-hemishell are considered. The edge and vertex contributions to the $C_{3/2}$ coefficient are examined.Comment: 25 p,JyTex,5 figs. on request

Thermodynamics, Euclidean Gravity and Kaluza-Klein Reduction

The aim of this paper is to find out a correspondence between one-loop effective action $W_E$ defined by means of path integral in Euclidean gravity and the free energy $F$ obtained by summation over the modes. The analysis is given for quantum fields on stationary space-times of a general form. For such problems a convenient procedure of a "Wick rotation" from Euclidean to Lorentzian theory becomes quite non-trivial implying transition from one real section of a complexified space-time manifold to another. We formulate conditions under which $F$ and $W_E$ can be connected and establish an explicit relation of these functionals. Our results are based on the Kaluza-Klein method which enables one to reduce the problem on a stationary space-time to equivalent problem on a static space-time in the presence of a gauge connection. As a by-product, we discover relation between the asymptotic heat-kernel coefficients of elliptic operators on a $D$ dimensional stationary space-times and the heat-kernel coefficients of a $D-1$ dimensional elliptic operators with an Abelian gauge connection.Comment: latex file, 22 page

Smeared heat-kernel coefficients on the ball and generalized cone

We consider smeared zeta functions and heat-kernel coefficients on the bounded, generalized cone in arbitrary dimensions. The specific case of a ball is analysed in detail and used to restrict the form of the heat-kernel coefficients $A_n$ on smooth manifolds with boundary. Supplemented by conformal transformation techniques, it is used to provide an effective scheme for the calculation of the $A_n$. As an application, the complete $A_{5/2}$ coefficient is given.Comment: 23 pages, JyTe

Thermodynamics of scalar fields in Kerr's geometry

The one-loop contributions to the entropy for a massive scalar field in a Kerr black hole are investigated using an approximation of the metric, which, after a conformal transformation, permits to work in a Rindler-like spacetime. Of course, as for the Schwarzschild case, the entropy is divergent in the proximity of the event horizon.Comment: 7 pages, LaTex, (revised version-last section modified

The a3/2a_{3/2} heat kernel coefficient for oblique boundary conditions

We present a method for the calculation of the $a_{3/2}$ heat kernel coefficient of the heat operator trace for a partial differential operator of Laplace type on a compact Riemannian manifold with oblique boundary conditions. Using special case evaluations, restrictions are put on the general form of the coefficients, which, supplemented by conformal transformation techniques, allows the entire smeared coefficient to be determined.Comment: 30 pages, LaTe

Multiple reflection expansion and heat kernel coefficients

We propose the multiple reflection expansion as a tool for the calculation of heat kernel coefficients. As an example, we give the coefficients for a sphere as a finite sum over reflections, obtaining as a byproduct a relation between the coefficients for Dirichlet and Neumann boundary conditions. Further, we calculate the heat kernel coefficients for the most general matching conditions on the surface of a sphere, including those cases corresponding to the presence of delta and delta prime background potentials. In the latter case, the multiple reflection expansion is shown to be non-convergent.Comment: 21 pages, corrected for some misprint

The hybrid spectral problem and Robin boundary conditions

The hybrid spectral problem where the field satisfies Dirichlet conditions (D) on part of the boundary of the relevant domain and Neumann (N) on the remainder is discussed in simple terms. A conjecture for the C_1 coefficient is presented and the conformal determinant on a 2-disc, where the D and N regions are semi-circles, is derived. Comments on higher coefficients are made. A hemisphere hybrid problem is introduced that involves Robin boundary conditions and leads to logarithmic terms in the heat--kernel expansion which are evaluated explicitly.Comment: 24 pages. Typos and a few factors corrected. Minor comments added. Substantial Robin additions. Substantial revisio

New times, new politics: history and memory during the final years of the CPGB

This article examines the relationship between collective memory, historical interpretation and political identity. It focuses on the dissolution of the Communist Party of Great Britain (CPGB) as constructed through collective narrative memory, and on Marxist interpretations of history. The divisions within the party and the wider Marxist community, stretching from 1956 until 1991, were often framed around questions of historical interpretation. The events of 1989–1991 created an historical and mnemonic crisis for CPGB members who struggled to reconcile their past identities with their present situation. Unlike the outward-facing revisionism of other political parties, this was an intensely personal affair. The solution for many was to emphasise the need to find new ways to progress socialist aims, without relying on a discredited grand narrative. In contrast, other Communist parties, such as the Communist Party of Britain, which had been established (or ‘re-established’) in 1988, fared rather better. By adhering to the international party line of renewal and continued struggle, the party was able to hold its narrative together, condemning the excesses of totalitarian regimes, while reaffirming the need for international class struggle

The ground state energy of a spinor field in the background of a finite radius flux tube

We develop a formalism for the calculation of the ground state energy of a spinor field in the background of a cylindrically symmetric magnetic field. The energy is expressed in terms of the Jost function of the associated scattering problem. Uniform asymptotic expansions needed are obtained from the Lippmann-Schwinger equation. The general results derived are applied to the background of a finite radius flux tube with a homogeneous magnetic field inside and the ground state energy is calculated numerically as a function of the radius and the flux. It turns out to be negative, remaining smaller by a factor of $\alpha$ than the classical energy of the background except for very small values of the radius which are outside the range of applicability of QED.Comment: 25 pages, 3 figure