56 research outputs found
A Self-Consistent Model for Positronium Formation from Helium Atoms
The differential and total cross sections for electron capture by positrons
from helium atoms are calculated using a first-order distorted wave theory
satisfying the Coulomb boundary conditions. In this formalism a parametric
potential is used to describe the electron screening in a consistent and
realistic manner. The present procedure is self consistent because (i) it
satisfies the correct boundary conditions and post-prior symmetry, and (ii) the
potential and the electron binding energies appearing in the transition
amplitude are consistent with the wave functions describing the collision
system. The results are compared with the other theories and with the available
experimental measurements. At the considered range of collision energies, the
results agree reasonably well with recent experiments and theories.
[Note: This paper will be published on volume 42 of the Brazilian Journal of
Physics
The Schwinger Variational Method
Variational methods have proven invaluable in theoretical physics and chemistry, both for bound state problems and for the study of collision phenomena. For collisional problems they can be grouped into two types: those based on the Schroedinger equation and those based on the Lippmann-Schwinger equation. The application of the Schwinger variational (SV) method to e-molecule collisions and photoionization has been reviewed previously. The present chapter discusses the implementation of the SV method as applied to e-molecule collisions
Low-energy unphysical saddle in polynomial molecular potentials
Vibrational spectra of polyatomic molecules are often obtained from a
polynomial expansion of the adiabatic potential around a minimum. For several
molecules, we show that such an approximation displays an unphysical saddle
point of comparatively small energy, leading to a region where the potential is
negative and unbounded. This poses an upper limit for a reliable evaluation of
vibrational levels. We argue that the presence of such saddle points is
general.Comment: The preprint version of the published Mol. Phys. paper, 19 pages, 3
figure
Attosecond imaging of molecular electronic wavepackets
International audienceA strong laser field may tunnel ionize a molecule from several orbitals simultaneously, forming an attosecond electron–hole wavepacket. Both temporal and spatial information on this wavepacket can be obtained through the coherent soft X-ray emission resulting from the laser-driven recollision of the liberated electron with the core. By characterizing the emission from aligned N 2 molecules, we demonstrate the attosecond contributions of the two highest occupied molecular orbitals. We determine conditions where they are disentangled in the real and imaginary parts of the emission dipole moment. This allows us to carry out a tomographic reconstruction of both orbitals with angstrom spatial resolution. Their coherent superposition provides experimental images of the attosecond wavepacket created in the ionization process. Our results open the prospect of imaging ultrafast intramolecular dynamics combining attosecond and angstrom resolutions
Calculation of intermediate energy electron-atom excitation cross sections by the Schwinger variational method
THE SCATTERING OF POSITRONS AND POSITRONIUM BY ATOMS IN THE CLOSE-COUPLING APPROXIMATION
The interpretation of resonance formation in coupled-channel models of positron scattering by atomic hydrogen using localized optical potentials
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