Beyond 90% capture: Possible, but at what cost?

© 2020 Elsevier Ltd Carbon capture and storage (CCS) will have an essential role in meeting our climate change mitigation targets. CCS technologies are technically mature and will likely be deployed to decarbonise power, industry, heat, and removal of CO2 from the atmosphere. The assumption of a 90% CO2 capture rate has become ubiquitous in the literature, which has led to doubt around whether CO2 capture rates above 90% are even feasible. However, in the context of a 1.5 °C target, going beyond 90% capture will be vital, with residual emissions needing to be indirectly captured via carbon dioxide removal (CDR) technologies. Whilst there will be trade-offs between the cost of increased rates of CO2 capture, and the cost of offsets, understanding where this lies is key to minimising the dependence on CDR. This study quantifies the maximum limit of feasible CO2 capture rate for a range of power and industrial sources of CO2, beyond which abatement becomes uneconomical. In no case, was a capture rate of 90% found to be optimal, with capture rates of up to 98% possible at a relatively low marginal cost. Flue gas composition was found to be a key determinant of the cost of capture, with more dilute streams exhibiting a more pronounced minimum. Indirect capture by deploying complementary CDR is also assessed. The results show that current policy initiatives are unlikely to be sufficient to enable the economically viable deployment of CCS in all but a very few niche sectors of the economy

HST/WFPC2 and VLT/ISAAC observations of PROPLYDS in the giant HII region NGC 3603

We report the discovery of three proplyd-like structures in the giant HII region NGC 3603. The emission nebulae are clearly resolved in narrow-band and broad-band HST/WFPC2 observations in the optical and broad-band VLT/ISAAC observations in the near-infrared. All three nebulae are tadpole shaped, with the bright ionization front at the head facing the central cluster and a fainter ionization front around the tail pointing away from the cluster. Typical sizes are 6,000 A.U. x 20,000 A.U. The nebulae share the overall morphology of the proplyds (``PROto PLanetarY DiskS'') in Orion, but are 20 to 30 times larger in size. Additional faint filaments located between the nebulae and the central ionizing cluster can be interpreted as bow shocks resulting from the interaction of the fast winds from the high-mass stars in the cluster with the evaporation flow from the proplyds. The striking similarity of the tadpole shaped emission nebulae in NGC 3603 to the proplyds in Orion suggests that the physical structure of both types of objects might be the same. We present 2D radiation hydrodynamical simulations of an externally illuminated star-disk-envelope system, which was still in its main accretion phase when first exposed to ionizing radiation from the central cluster. The simulations reproduce the overall morphology of the proplyds in NGC 3603 very well, but also indicate that mass-loss rates of up to 10^-5 Mo/yr are required in order to explain the size of the proplyds. (abbreviated)Comment: 10 pages, 4 Postscript figures, uses emulateapj.sty and psfig.tex. Astronomical Journal, in press (January 2000 issue

Assorted effects of TGFβ and chondroitinsulfate on p38 and ERK1/2 activation levels in human articular chondrocytes stimulated with LPS

SummaryObjectivesInadequate cellular response of chondrocytes to stress frequently terminates in osteoarthritis (OA). Adequate response is fundamentally modulated by concerted cytokine signaling events, directing degradation and synthesis of cartilage on articular surfaces where and whenever necessary. Transforming growth factor (TGF)β is a prominent mediator in cartilage anabolism, although particular catabolic activities are occasionally reported. Clearly, before the TGFβ signal gets through to the gene regulatory machinery, cross talk with modulators occurs.MethodWe tested the hypothesis whether chondroitinsulfate (CS) modulates cell signaling. TGFβ and/or soluble CS was added to human articular chondrocytes (HACs) and activation of p38 and extracellular signal related kinase (ERK)1/2 was determined by immunoblot analysis. Expression levels of mRNA of matrix metalloproteinase (MMP)-2, -3 and -13 were determined by real-time polymerase chain reaction (PCR).ResultsNo significant effects were observed unless cells were stimulated with lipopolysaccharide (LPS), invigorating catabolic metabolism in chondrocytes. LPS effects, however, were profoundly modulated by TGFβ, CS and both applied in combination. Most prominent, the silencing of p38 stress signal by CS was superimposable to that of TGFβ. Phospho-ERK1/2 levels were raised by TGFβ three-fold over LPS induced levels. In contrast, CS treatment, alone or combined with TGFβ, reduced phosphorylation significantly below LPS induced levels. Finally, suppression of LPS induced MMP-13 mRNA levels resulted with CS.ConclusionSoluble CS modulates signaling events in chondrocytes concurrent with MMP-13 down regulation. The effects observed suggest a feedback signaling mechanism cross talking with TGFβ-signal pathways and may serve an explanation, on the cellular level, for the beneficial effects found in clinical studies with pharmacologic application of CS

Powerful H2_2 Emission and Star Formation on the Interacting Galaxy System Arp 143: Observations with Spitzer and GALEX

We present new mid-infrared ($5 - 35\mu$m) and ultraviolet (1539 -- 2316 \AA) observations of the interacting galaxy system Arp 143 (NGC 2444/2445) from the Spitzer Space Telescope and GALEX. In this system, the central nucleus of NGC 2445 is surrounded by knots of massive star-formation in a ring-like structure. We find unusually strong emission from warm H$_2$ associated with an expanding shock wave between the nucleus and the western knots. At this ridge, the flux ratio between H$_2$ and PAH emission is nearly ten times higher than in the nucleus. Arp 143 is one of the most extreme cases known in that regard. From our multi-wavelength data we derive a narrow age range of the star-forming knots between 2 Myr and 7.5 Myr, suggesting that the ring of knots was formed almost simultaneously in response to the shock wave traced by the H$_2$ emission. However, the knots can be further subdivided in two age groups: those with an age of 2--4 Myr (knots A, C, E, and F), which are associated with $8\mu$m emission from PAHs, and those with an age of 7-8 Myr (knots D and G), which show little or no $8\mu$m emission shells surrounding them. We attribute this finding to an ageing effect of the massive clusters which, after about 6 Myr, no longer excite the PAHs surrounding the knots.Comment: 19 pages, 11 figures, including tables at the end; accepted by Ap

USING FUNCTIONAL DATA ANALYSIS TO EVALUATE EFFECT OF SHADE ON BODY TEMPERATURE OF FEEDLOT HEIFERS DURING ENVIRONMENTAL HEAT STRESS

Heat stress can be a serious problem for cattle. Body temperature (Tb) is a good measure of an animal’s thermo-regulatory response to an environmental thermal challenge. Previous studies found that Tb increases in response to increasing ambient temperature in a controlled chamber. However, when animals are in an uncontrolled environment, Tb is subject to many uncontrolled environmental factors, such as sunshade, wind, and humidity, that increase variation in the data. Hence, functional data analysis (FDA) was applied to analyze the data with uncontrolled environmental factors as curves in the whole series of days in this study. Breed (Angus, MARCIII, MARC-I, Charolais) and availability of shade (access versus no access to sunshade) were included as treatment factors in the statistical model. This study illustrates the potential of FDA to retain all information in the curves. The specific objectives are to use FDA to smooth Tb with large noise, to detect treatment effects on Tb, and to assess the interactions between breed and availability of shade with functional regression coefficients. The results show that FDA can be used to detect significant treatment interactions that may otherwise remain undetected using regular linear or nonlinear models. Significant interactions were found, indicating that access to sun-shade influences the way animals respond to a thermal challenge. Overall, it was found that breeds of cattle with dark-hides were more affected by temperature changes and peak temperatures than breeds of cattle with light-hides. Angus cattle (black) had the highest body temperatures in both shade and no shade areas, while Charolais (white) had the lowest body temperatures in the no shade area. However, MARC III (dark red) experienced the largest temperature differential between shade and no shade. Therefore, breed and availability of shade interactions are important considerations when making predictions to aid in management decisions involving feedlot cattle

Spatially Resolved Spitzer-IRS Spectroscopy of the Central Region of M82

We present high spatial resolution (~ 35 parsec) 5-38 um spectra of the central region of M82, taken with the Spitzer Infrared Spectrograph. From these spectra we determined the fluxes and equivalent widths of key diagnostic features, such as the [NeII]12.8um, [NeIII]15.5um, and H_2 S(1)17.03um lines, and the broad mid-IR polycyclic aromatic hydrocarbon (PAH) emission features in six representative regions and analysed the spatial distribution of these lines and their ratios across the central region. We find a good correlation of the dust extinction with the CO 1-0 emission. The PAH emission follows closely the ionization structure along the galactic disk. The observed variations of the diagnostic PAH ratios across M82 can be explained by extinction effects, within systematic uncertainties. The 16-18um PAH complex is very prominent, and its equivalent width is enhanced outwards from the galactic plane. We interpret this as a consequence of the variation of the UV radiation field. The EWs of the 11.3um PAH feature and the H_2 S(1) line correlate closely, and we conclude that shocks in the outflow regions have no measurable influence on the H_2 emission. The [NeIII]/[NeII] ratio is on average low at ~0.18, and shows little variations across the plane, indicating that the dominant stellar population is evolved (5 - 6 Myr) and well distributed. There is a slight increase of the ratio with distance from the galactic plane of M82 which we attribute to a decrease in gas density. Our observations indicate that the star formation rate has decreased significantly in the last 5 Myr. The quantities of dust and molecular gas in the central area of the galaxy argue against starvation and for negative feedback processes, observable through the strong extra-planar outflows.Comment: 15 pages, 12 figures, 3 tables, ApJ, emulateap