Inelastic Diffraction and Spectroscopy of Very Weakly Bound Clusters

We study the coherent inelastic diffraction of very weakly bound two body clusters from a material transmission grating. We show that internal transitions of the clusters can lead to new separate peaks in the diffraction pattern whose angular positions determine the excitation energies. Using a quantum mechanical approach to few body scattering theory we determine the relative peak intensities for the diffraction of the van der Waals dimers (D_2)_2 and H_2-D_2. Based on the results for these realistic examples we discuss the possible applications and experimental challenges of this coherent inelastic diffraction technique.Comment: 15 pages + 5 figures. J. Phys. B (in press

Simulation of polar stratospheric clouds in the chemistry-climate-model EMAC via the submodel PSC

The submodel PSC of the ECHAM5/MESSy Atmospheric Chemistry model (EMAC) has been developed to simulate the main types of polar stratospheric clouds (PSC). The parameterisation of the supercooled ternary solutions (STS, type 1b PSC) in the submodel is based on Carslaw et al. (1995b), the thermodynamic approach to simulate ice particles (type 2 PSC) on Marti and Mauersberger (1993). For the formation of nitric acid trihydrate (NAT) particles (type 1a PSC) two different parameterisations exist. The first is based on an instantaneous thermodynamic approach from Hanson and Mauersberger (1988), the second is new implemented and considers the growth of the NAT particles with the aid of a surface growth factor based on Carslaw et al. (2002). It is possible to choose one of this NAT parameterisation in the submodel. This publication explains the background of the submodel PSC and the use of the submodel with the goal of simulating realistic PSC in EMAC

Effects of Two Energy Scales in Weakly Dimerized Antiferromagnetic Quantum Spin Chains

By means of thermal expansion and specific heat measurements on the high-pressure phase of (VO)$_2$P$_2$O$_7$, the effects of two energy scales of the weakly dimerized antiferromagnetic $S$ = 1/2 Heisenberg chain are explored. The low energy scale, given by the spin gap $\Delta$, is found to manifest itself in a pronounced thermal expansion anomaly. A quantitative analysis, employing T-DMRG calculations, shows that this feature originates from changes in the magnetic entropy with respect to $\Delta$, $\partial S^{m}/ \partial \Delta$. This term, inaccessible by specific heat, is visible only in the weak-dimerization limit where it reflects peculiarities of the excitation spectrum and its sensitivity to variations in $\Delta$.Comment: 4 pages, 4 figures now identical with finally published versio

Amphibians and plant-protection products: what research and action is needed?

Background: The majority of Swiss amphibians are threatened. There is a range of factors which have been discussed as possible causes for their decline, including plant protection products (PPPs). Results: The influence of PPPs on amphibian populations has not yet been studied to any great extent, neither for active ingredients nor for the wetting agents, breakdown products or tank mixtures. A further topic of discussion was how to better protect amphibians by reducing their exposure to PPPs in agricultural fields. Conclusion: Experts at a workshop concluded that further research is needed

Critical Phenomena at the Antiferromagnetic Phase Transition of Azurite

We report on high-resolution acoustic, specific-heat and thermal expansion measurements in the vicinity of the antiferromagnetic phase transition at T_N = 1.88 K on a high-quality single crystal of the natural mineral azurite. A detailed investigation of the critical contribution to the various quantities at T_N is presented. The set of critical exponents and amplitude ratios of the singular contributions above and below the transition indicate that the system can be reasonably well described by a three-dimensional Heisenberg antiferromagnet.Comment: 9 pages, 3 figures, proceedings of ICM 2012, JKP

Magnetoelastic and structural properties of azurite Cu3(CO3)2(OH)2 from neutron scattering and muon spin rotation

Azurite, Cu3(CO3)2(OH)2, has been considered an ideal example of a one-dimensional (1D) diamond chain antiferromagnet. Early studies of this material imply the presence of an ordered antiferromagnetic phase below $T_N \sim 1.9$ K while magnetization measurements have revealed a 1/3 magnetization plateau. Until now, no corroborating neutron scattering results have been published to confirm the ordered magnetic moment structure. We present recent neutron diffraction results which reveal the presence of commensurate magnetic order in azurite which coexists with significant magnetoelastic strain. The latter of these effects may indicate the presence of spin frustration in zero applied magnetic field. Muon spin rotation, $\mu$SR, reveals an onset of short-range order below 3K and confirms long-range order below $T_N$.Comment: 5 pages, 4 figures, PHYSICAL REVIEW B 81, 140406(R) (2010

Contribution of solitons to enhanced rogue wave occurrence in shallow depths: a case study in the southern North Sea

The shallow waters off the coast of Norderney in the southern North Sea are characterised by a higher frequency of rogue wave occurrences than expected. Here, rogue waves refer to waves exceeding twice the significant wave height. The role of nonlinear processes in the generation of rogue waves at this location is currently unclear. Within the framework of the Korteweg–de Vries (KdV) equation, we investigated the discrete soliton spectra of measured time series at Norderney to determine differences between time series with and without rogue waves. For this purpose, we applied a nonlinear Fourier transform (NLFT) based on the Korteweg–de Vries equation with vanishing boundary conditions (vKdV-NLFT). At measurement sites where the propagation of waves can be described by the KdV equation, the solitons in the discrete nonlinear vKdV-NLFT spectrum correspond to physical solitons. We do not know whether this is the case at the considered measurement site. In this paper, we use the nonlinear spectrum to classify rogue wave and non-rogue wave time series. More specifically, we investigate if the discrete nonlinear spectra of measured time series with visible rogue waves differ from those without rogue waves. Whether or not the discrete part of the nonlinear spectrum corresponds to solitons with respect to the conditions at the measurement site is not relevant in this case, as we are not concerned with how these spectra change during propagation. For each time series containing a rogue wave, we were able to identify at least one soliton in the nonlinear spectrum that contributed to the occurrence of the rogue wave in that time series. The amplitudes of these solitons were found to be smaller than the crest height of the corresponding rogue wave, and interaction with the continuous wave spectrum is needed to fully explain the observed rogue wave. Time series with and without rogue waves showed different characteristic soliton spectra. In most of the spectra calculated from rogue wave time series, most of the solitons clustered around similar heights, but the largest soliton was outstanding, with an amplitude significantly larger than all other solitons. The presence of a clearly outstanding soliton in the spectrum was found to be an indicator pointing towards the enhanced probability of the occurrence of a rogue wave in the time series. Similarly, when the discrete spectrum appears as a cluster of solitons without the presence of a clearly outstanding soliton, the presence of a rogue wave in the observed time series is unlikely. These results suggest that soliton-like and nonlinear processes substantially contribute to the enhanced occurrence of rogue waves off Norderney.</p