Electron transport through a metal-molecule-metal junction

Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been recorded at room temperature. Zero bias conductances were measured in the 10-100 nS range and different kinds of non-linear I-V curves with step-like features were reproducibly obtained. Switching between different kinds of I-V curves could be induced by varying the distance between the two metallic electrodes. The experimental results are discussed within the framework of tunneling transport models explicitly taking into account the discrete nature of the electronic spectrum of the molecule.Comment: 12 pages, 12 figures to appear in Phys. Rev. B 59(19) 199

Electron transport through rectifying self-assembled monolayer diodes on silicon: Fermi level pinning at the molecule-metal interface

We report the synthesis and characterization of molecular rectifying diodes on silicon using sequential grafting of self-assembled monolayers of alkyl chains bearing a pi group at their outer end (Si/sigma-pi/metal junctions). We investigate the structure-performance relationships of these molecular devices and we examine to what extent the nature of the pi end-group (change in the energy position of their molecular orbitals) drives the properties of these molecular diodes. For all the pi-groups investigated here, we observe rectification behavior. These results extend our preliminary work using phenyl and thiophene groups (S. Lenfant et al., Nano Letters 3, 741 (2003)).The experimental current-voltage curves are analyzed with a simple analytical model, from which we extract the energy position of the molecular orbital of the pi-group in resonance with the Fermi energy of the electrodes. We report the experimental studies of the band lineup in these silicon/alkyl-pi conjugated molecule/metal junctions. We conclude that Fermi level pinning at the pi-group/metal interface is mainly responsible for the observed absence of dependence of the rectification effect on the nature of the pi-groups, even though they were chosen to have significant variations in their electronic molecular orbitalsComment: To be published in J. Phys. Chem.

Clustering of vector nulls in homogeneous isotropic turbulence

We analyze the vector nulls of velocity, Lagrangian acceleration, and vorticity, coming from direct numerical simulations of forced homogeneous isotropic turbulence at $Re_\lambda \in [40-610]$. We show that the clustering of velocity nulls is much stronger than those of acceleration and vorticity nulls. These acceleration and vorticity nulls, however, are denser than the velocity nulls. We study the scaling of clusters of these null points with $Re_\lambda$ and with characteristic turbulence lengthscales. We also analyze datasets of point inertial particles with Stokes numbers $St = 0.5$, 3, and 6, at $Re_\lambda = 240$. Inertial particles display preferential concentration with a degree of clustering that resembles some properties of the clustering of the Lagrangian acceleration nulls, in agreement with the proposed sweep-stick mechanism of clustering formation

First-principles calculation of intrinsic defect formation volumes in silicon

We present an extensive first-principles study of the pressure dependence of the formation enthalpies of all the know vacancy and self-interstitial configurations in silicon, in each charge state from -2 through +2. The neutral vacancy is found to have a formation volume that varies markedly with pressure, leading to a remarkably large negative value (-0.68 atomic volumes) for the zero-pressure formation volume of a Frenkel pair (V + I). The interaction of volume and charge was examined, leading to pressure--Fermi level stability diagrams of the defects. Finally, we quantify the anisotropic nature of the lattice relaxation around the neutral defects.Comment: 9 pages, 9 figure

Clustering of vector nulls in homogeneous isotropic turbulence

We analyze the vector nulls of velocity, Lagrangian acceleration, and vorticity, coming from direct numerical simulations of forced homogeneous isotropic turbulence at Reλ∈O([40-600]). We show that the clustering of velocity nulls is much stronger than those of acceleration and vorticity nulls. These acceleration and vorticity nulls, however, are denser than the velocity nulls. We study the scaling of clusters of these null points with Reλ and with characteristic turbulence lengthscales. We also analyze datasets of point inertial particles with Stokes numbers St=0.5, 3, and 6, at Reλ=240. Inertial particles display preferential concentration with a degree of clustering that resembles some properties of the clustering of the Lagrangian acceleration nulls, in agreement with the proposed sweep-stick mechanism of clustering formation.Fil: Mora, D. O.. University of Washington; Estados Unidos. Universite Grenoble Alpes; FranciaFil: Bourgoin, M.. Centre National de la Recherche Scientifique; FranciaFil: Mininni, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; ArgentinaFil: Obligado, M.. Universite Grenoble Alpes; Franci

Scaling Law in Carbon Nanotube Electromechanical Devices

We report a method for probing electromechanical properties of multiwalled carbon nanotubes(CNTs). This method is based on AFM measurements on a doubly clamped suspended CNT electrostatically deflected by a gate electrode. We measure the maximum deflection as a function of the applied gate voltage. Data from different CNTs scale into an universal curve within the experimental accuracy, in agreement with a continuum model prediction. This method and the general validity of the scaling law constitute a very useful tool for designing actuators and in general conducting nanowire-based NEMS.Comment: 12 pages, 4 figures. To be published in Phys. Rev. Let

Measurements of the magnetic field induced by a turbulent flow of liquid metal

Initial results from the Madison Dynamo Experiment provide details of the inductive response of a turbulent flow of liquid sodium to an applied magnetic field. The magnetic field structure is reconstructed from both internal and external measurements. A mean toroidal magnetic field is induced by the flow when an axial field is applied, thereby demonstrating the omega effect. Poloidal magnetic flux is expelled from the fluid by the poloidal flow. Small-scale magnetic field structures are generated by turbulence in the flow. The resulting magnetic power spectrum exhibits a power-law scaling consistent with the equipartition of the magnetic field with a turbulent velocity field. The magnetic power spectrum has an apparent knee at the resistive dissipation scale. Large-scale eddies in the flow cause significant changes to the instantaneous flow profile resulting in intermittent bursts of non-axisymmetric magnetic fields, demonstrating that the transition to a dynamo is not smooth for a turbulent flow.Comment: 9 pages, 11 figures, invited talk by C. B. Forest at 2005 APS DPP meeting, resubmitted to Physics of Plasma

Markov property of Lagrangian turbulence

Based on direct numerical simulations with point-like inertial particles transported by homogeneous and isotropic turbulent flows, we present evidence for the existence of Markov property in Lagrangian turbulence. We show that the Markov property is valid for a finite step size larger than a Stokes number-dependent Einstein-Markov memory length. This enables the description of multi-scale statistics of Lagrangian particles by Fokker-Planck equations, which can be embedded in an interdisciplinary approach linking the statistical description of turbulence with fluctuation theorems of non-equilibrium stochastic thermodynamics and fluctuation theorems, and local flow structures.Comment: submitted to PRL, 5 pages, 4 figure