Wavelet transform for the evaluation of peak intensities in flow-injection analysis

The application of the wavelet transform in the determination of peak intensities in flow-injection analysis was studied with regard to its properties of minimizing the effects of noise and baseline drift. The results indicate that for white noise and a favourable peak shape a signal-to-noise ratio of 2 can be tolerated at the 5% error level, which means that a significant reduction in the detection limit can be obtained in comparison with the classical signal-processing methods. With regard to the influence of a changing baseline it was found that its d.c. level has a negligible effect, but a linear or exponentially rising baseline introduces an error that depends on the chosen frequency of the wavelet that is used to determine the peak intensity. The optimum choice of this frequency, in turn, depends on the shape of the peak that is studied. In this respect significant differences were observed for pure Gaussian and exponentially modified Gaussian peaks

A knowledge-based system for the automatic chronopotentiometric elucidation of electrode reaction mechanisms

A knowledge-based system for the elucidation of electrode reaction mechanisms based on chronopotentiometric experiments is described. The system runs the diagnostic experiments and uses the results in the reasoning process. New mechanistic knowledge can be added directly to its knowledge base in the form of production rules. The system is fully modular and its domain- specific modules can easily be changed for application to other electrochemical techniques. Correct operation of the system is demonstrated with the familiar reduction mechanisms of cadmium (II), zinc (II), cystamine and cinnamaldehyde

The Detection of a 3.5-h Period in the Classical Nova Velorum 1999 (V382 Vel) and the Long Term Behavior of the Nova Light Curve

We present CCD photometry, light curve and time series analysis of the classical nova V382 Vel (N Vel 1999). The source was observed for 2 nights in 2000, 21 nights in 2001 and 7 nights in 2002 using clear filters. We report the detection of a distinct period in the light curve of the nova P=0.146126(18) d (3.5 h). The period is evident in all data sets, and we interpret it as the binary period of the system. We also measured an increase in the amplitude modulation of the optical light (in magnitude) by more than 55% from 2000 to 2001 and about 64% from 2001 to 2002. The pulse profiles in 2001 show deviations from a pure sinusoidal shape which progressively become more sinusoidal by 2002. The main cause of the variations in 2001 and 2002 can be explained with the occultation of the accretion disk by the secondary star. We interpret the observed deviations from a pure sinusoidal shape as additional flux resulting from the aspect variations of the irradiated face of the secondary star.Comment: 16 pages and 4 figures, accepted as it stands to be published in the Astronomical Journal (AJ

Wess-Zumino-Witten model off criticality

We study the renormalization group flow properties of the Wess-Zumino-Witten model in the region of couplings between $g^2=0$ and $g^2=4\pi/k$, by evaluating the two-loop Zamolodchikov's $c$-function. We also discuss the region of negative couplings.Comment: 8 page

Impulse-response functions of several detectors used in flow-injection analysis

A procedure for the determination of the impulse-response function of a detector is given. Its application to photometers, ion-sensitive field effect transistors, a potentiometric detector at constant current and a voltammetric detector shows that the impulse-response function can be used to obtain specific information about the performance of the detector in the manifold. This function clearly shows the contribution of the detector to the peak broadening and how the detector generates the final signal from the presented concentration profile. From this information one could derive improvements to the detector, such as changing the construction of the detector cell, minimizing the influence of other parts of the manifold or adapting the attached electronics

Polen: weidegang voor gezonde koeien

Meer welzijn bevordert een langere en gezondere levensduur. In onderstaand artikel doen ze verslag

Decuplet baryon magnetic moments in a QCD-based quark model beyond quenched approximation

We study the decuplet baryon magnetic moments in a QCD-based quark model beyond quenched approximation. Our approach for unquenching the theory is based on the heavy baryon perturbation theory in which the axial couplings for baryon - meson and the meson-meson-photon couplings from the chiral perturbation theory are used together with the QM moment couplings. It also involves the introduction of a form factor characterizing the structure of baryons considered as composite particles. Using the parameters obtained from fitting the octet baryon magnetic moments, we predict the decuplet baryon magnetic moments. The $\Omega^-$ magnetic moment is found to be in good agreement with experiment: $\mu_{\Omega^-}$ is predicted to be $-1.97 \mu_N$ compared to the experimental result of ($-$2.02 $\pm$ 0.05) $\mu_N$.Comment: 19 pages, 2 figure

The Trajectory Model for Track Fitting and Alignment

This note introduces the concept of Trajectories. The LHCb trajectory model and the implementation in the track fitting and tracking sub-detector code as in Brunel v31r2 are described. The possible use of trajectories for alignment is outlined

Spectral imbalance and the normalized dissipation rate of turbulence

The normalized turbulent dissipation rate $C_\epsilon$ is studied in decaying and forced turbulence by direct numerical simulations, large-eddy simulations, and closure calculations. A large difference in the values of $C_\epsilon$ is observed for the two types of turbulence. This difference is found at moderate Reynolds number, and it is shown that it persists at high Reynolds number, where the value of $C_\epsilon$ becomes independent of the Reynolds number, but is still not unique. This difference can be explained by the influence of the nonlinear cascade time that introduces a spectral disequilibrium for statistically nonstationary turbulence. Phenomenological analysis yields simple analytical models that satisfactorily reproduce the numerical results. These simple spectral models also reproduce and explain the increase of $C_\epsilon$ at low Reynolds number that is observed in the simulations