Criticality in failure under compression: acoustic emission study of coal and charcoal with different microstructures

A systematic study of acoustic emission avalanches in coal and charcoal samples under slow uniaxial compression is presented. The samples exhibit a range of organic composition in terms of chemical elements as well as different degrees of heterogeneity in the microstructure. The experimental analysis focuses on the energies E of the individual acoustic emission events as well as on the time correlations between successive events. The studied samples can be classified into three groups. The more homogeneous samples (group I) with pores in the micro and nanoscales, with signatures of hardening effects in the stress-strain curves, exhibit the cleanest critical power-law behavior for the energy distributions g(E)dE∼E-ϵdE with a critical exponent ϵ=1.4. The more heterogeneous samples with voids, macropores, and granular microstructures (group III), show signatures of weakening effects and a larger effective exponent close to the value ϵ=1.66, but in some cases truncated by exponential damping factors. The rest of the samples (group II) exhibit a mixed crossover behavior still compatible with an effective exponent ϵ=1.4 but clearly truncated by exponential factors. These results suggest the existence of two possible universality classes in the failure of porous materials under compression: one for homogeneous samples and another for highly heterogeneous samples. Concerning time correlations between avalanches, all samples exhibit very similar waiting time distributions although some differences for the Omori aftershock distributions cannot be discarded

Biomarkers and inorganic proxies in the paleoenvironmental reconstruction of mires: The importance of landscape in Las Conchas (Asturias, Northern Spain)

We determined the lipid distributions (n-alkanes, n-alkan-2-ones, n-alkanoic acids), total organic carbon (TOC), total nitrogen (TN), Ca/Mg and ash content in Las Conchas mire, a 3.2 m deep bryophyte-dominated mire in Northern Spain covering 8000 cal yr BP. Bog conditions developed in the bottom 20 cm of the profile, and good preservation of organic matter (OM) was inferred from n-alkanoic acid distribution, with the exception of the uppermost 20 cm (last ca. 200 yr). Microbial synthesis of long chain saturated fatty acids from primary OM likely produced a dominance of short chain n-alkanoic acids with a bimodal distribution, as well as the lack of correspondence between the n-alkane and n-alkanoic acid profiles in the upper 20 cm. This was accompanied by an increase in ash content, a decrease in TOC and variation in n-alkane ratios, thereby suggesting significant changes in the mire, namely drainage and transformation to a meadow, in the last ca. 200 yr. The distribution of n-alkan-2-ones indicated an increase in bacterial source from the bottom of the record to 94 cm, whereas their distribution in the upper part could be attributed mainly to plant input and/or the microbial oxidation of n-alkanes. The different n-alkane proxies showed variations, which we interpreted in terms of changes in vegetation (Sphagnum vs. non-Sphagnum dominated phases) during the last 8000 cal yr BP. C23 was the most abundant homolog throughout most of the record, thereby suggesting dominant humid conditions alternating with short drier phases. However, such humid conditions were not linked to paleoclimatic variation but rather to geomorphological characteristics: Las Conchas mire, at the base of the Cuera Range, receives continuous runoff—even during drier periods—which is not necessarily accompanied by additional mineral input to peat, producing the development of Sphagnum moss typical of waterlogged ecotopes and damp habitats. Thus, although geochemical proxies indicated an ombrotrophic regime in the mire, geomorphological characteristics may make a considerable contribution to environmental conditions

Significance of the high abundance of pentacyclic triterpenyl and hopenyl acetates in sphagnum peat bogs from northern spain

© The Author(s).Global warming is expected to increase the rate of CH4 emission from acidic peatlands leading to an increased interest on its mechanisms of formation. The main routes are through the reduction of CO2 by molecular hydrogen and through the cleavage of acetate. A predominance of the former, a reaction which also competes with homoacetogenesis to form acetate, may enrich the media in acetate, which could potentially be incorporated in the peat molecular markers. Acetates of triterpenoid biomarkers have been identified in peats and lake sediments and related to the input of higher plants. Nevertheless, the acetyl derivatives are found in very low amounts in fresh plants and in much lower amount than other derivatives with alcohol or ketone functional groups. The dichloromethane/methanol extracts of Asturian peat bog profiles (North Spain) were analyzed using gas chromatography/mass spectrometry (GC/MS) and compound-specific-isotope-analysis (CSIA). They show abundance of acetates of compounds with oleanane, ursane, and lupane skeletons derived from higher plants and with hopane skeleton, which can be considered a characteristic of these peats. Two families of 3-oxyhopenyl acetates with -17(21)- and -22(29)- configurations were detected in the upper part of the peat profiles, having a δ13C isotopic composition enriched by 4‰ compared with that of higher plant triterpenoids, and similar to that of microorganism-derived regular hopanoids. Both the acetate and ketone derivatives with the oxygenated functionality at C-3 were generally present in a given extract and tended to accumulate at certain depth in the profiles and in specific levels. The widespread occurrence of acetyl-derivatives, their higher concentration in the deeper layers of the peat, the fact that the acetates correspond to different compound families of diverse source and the very low amount of acetates identified in Ericaceae-contributing to the peat compared to the alcohols suggest that they were formed in the peat under particularly favorable environmental conditions. We postulate that these conditions could have been the existence of a medium enriched in acetic acid produced by the dominance of hydrogenotrophic methanogenesis and/or homoacetogenesis over acetoclastic methanogenesis. This phenomenon that has been preferentially described in Sphagnum bogs at high latitudes, and in the deeper layers of peat, appears to be also present in the temperate peats of the Asturian coast.Financial support from the Spanish Ministry for Science and Innovation (MICINN) and the German Academic Exchange Service (DAAD) through a bilateral research project (DE2009-0055) is gratefully acknowledged. Further economic support was received from projects CGL2009-13990-C02-01 (MICINN) and CGL2013-46458-C2-1-R (MINECO) and the LOEWE program (Landes Offensive zur Entwicklung Wissenschaftlich-ökonomischer Exzellenz) of Hesse’s Ministry of Higher Education, Research, and the Arts by funding the Biodiversity and Climate Research Centre (BiK-F).Peer reviewe

Thermochronometry unveils ancient thermal regimes in the NW Pampean Ranges, Argentina: From Mesozoic rifting to Miocene flat-slab subduction

Reconstructing thermal histories in thrust belts is commonly used to infer the age and rates of thrusting and hence the driving mechanisms of orogenesis. In areas where ancient basins have been incorporated into the orogenic wedge, a quantitative reconstruction of the thermal history helps distinguish among potential mechanisms responsible for heating events. We present such a reconstruction for the Ischigualasto-Villa Unión basin in the western Pampean Ranges of Argentina, where Triassic rifting and late Cretaceous-Cenozoic retroarc foreland basin development has been widely documented, including Miocene flat-slab subduction. We report results of organic and inorganic thermal indicators acquired along three stratigraphic sections, including vitrinite reflectance and X-ray diffractometry in claystones and new thermochronological [(apatite fission-track and apatite and zircon [U-Th]/He)] analyses. Despite up to 5 km-thick Cenozoic overburden and unlike previously thought, the thermal peak in the basin is not due to Cenozoic burial but occurred in the Triassic, associated with a high heat flow of up to 90 mWm−2 and <2 km of burial, which heated the base of the Triassic strata to ~160°C. Following exhumation, attested by the development of an unconformity between the Triassic and Late-Cretaceous–Cenozoic sequences, Cenozoic re-burial increased the temperature to ~110°C at the base of the Triassic section and only ~50°C 7 km upsection, suggesting a dramatic decrease in the thermal gradient. The onset of Cenozoic cooling occurred at ~10−8 Ma, concomitant with sediment accumulation and thus preceding the latest Miocene onset of thrusting that has been independently documented by stratigraphic–cross-cutting relationships. We argue that the onset of cooling is associated with lithospheric refrigeration following establishment of flat-slab subduction, leading to the eastward displacement of the asthenospheric wedge beneath the South American plate. Our study places time and temperature constraints on flat-slab cooling that calls for a careful interpretation of exhumation signals in thrustbelts inferred from thermochronology only.Fil: Ezpeleta, Miguel. Universidad Nacional de La Rioja; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Parra, Mauricio. Universidade de Sao Paulo; BrasilFil: Collo, Gilda. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Wunderlin, Cecilia Ayelén. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Borrego, Angeles G.. Instituto Nacional del Carbón; EspañaFil: Sobel, Edward Robert. Universitat Potsdam. Mathematisch Nautrwissenschaften Fakultat. Institut Fur Geowissenschaften. Allgemeine Geologie; AlemaniaFil: Glodny, Johannes. German Research Centre for Geosciences; Alemani

Debates CSIC: Compromiso de la ciencia con los Objetivos de Desarrollo Sostenible

Datos técnicos: 106 minutos, color, español. Ficha técnica: Gabinete de Presidencia CSIC y Departamento de ComunicaciónOrden de intervención de los ponentes: 0:03 : Ángeles Heras - Secretaria de Estado, Universidades, Investigación, Desarrollo e Innovación; 9:53 : Gustavo Suárez-Pertierra - Presidente de UNICEF Comité Español; 26:55 : Mª Ángeles Durán - Centro de Ciencias Humanas y Sociales (CSIC); 45:31 : Iñigo Losada - Hidráulica Ambiental (Universidad de Cantabria); 57:12 : Joaquín Tintoré - CSIC, SOCIB-IMEDEA; 1:14:28 : Ángeles G.Borrego - Instituto Nacional del Carbón; 1:24:58 : Turno de Preguntas.-- Nota aclaratoria: por problemas técnicos en la grabación se han omitido algunas partes que estaban dañadas, disculpen las molestias.N