Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form

Water-redispersible, nanofibrillated cellulose (NFC) in powder form was prepared from refined, bleached beech pulp (RBP) by carboxymethylation (c) and mechanical disintegration (m). Two routes were examined by altering the sequence of the chemical and mechanical treatment, leading to four different products: RBP-m and RBP-mc (route 1), and RBP-c and RBP-cm (route 2). The occurrence of the carboxymethylation reaction was confirmed by FT-IR spectrometry and 13C solid state NMR (13C CP-MAS) spectroscopy with the appearance of characteristic signals for the carboxylate group at 1,595cm−1 and 180ppm, respectively. The chemical modification reduced the crystallinity of the products, especially for those of route 2, as shown by XRD experiments. Also, TGA showed a decrease in the thermal stability of the carboxymethylated products. However, sedimentation tests revealed that carboxymethylation was critical to obtain water-redispersible powders: the products of route 2 were easier to redisperse in water and their aqueous suspensions were more stable and transparent than those from route 1. SEM images of freeze-dried suspensions from redispersed RBP powders confirmed that carboxymethylation prevented irreversible agglomeration of cellulose fibrils during drying. These results suggest that carboxymethylated and mechanically disintegrated RBP in dry form is a very attractive alternative to conventional NFC aqueous suspensions as starting material for derivatization and compounding with (bio)polymer

Experimental Validation of the Largest Calculated Isospin-Symmetry-Breaking Effect in a Superallowed Fermi Decay

A precision measurement of the gamma yields following the beta decay of 32Cl has determined its isobaric analogue branch to be (22.47^{+0.21}_{-0.19})%. Since it is an almost pure Fermi decay, we can also determine the amount of isospin-symmetry breaking in this superallowed transition. We find a very large value, delta_C=5.3(9)%, in agreement with a shell-model calculation. This result sets a benchmark for isospin-symmetry-breaking calculations and lends support for similarly-calculated, yet smaller, corrections that are currently applied to 0+ -> 0+ transitions for tests of the Standard Model

Determining the 7Li(n,gamma) cross section via Coulomb dissociation of 8Li

The applicability of Coulomb dissociation reactions to determine the cross section for the inverse neutron capture reaction was explored using the reaction 8Li(gamma,n)7Li. A 69.5 MeV/nucleon 8Li beam was incident on a Pb target, and the outgoing neutron and 7Li nucleus were measured in coincidence. The deduced (n,gamma) excitation function is consistent with data for the direct capture reaction 7Li(n,gamma)8Li and with low-energy effective field theory calculations.Comment: Accepted for publication in Phys. Rev.

A New Precision Measurement of the 7Be(p,gamma)8B Cross section with an Implanted 7Be Target

The 7Be(p,gamma)8B reaction plays a central role in the evaluation of solar neutrino fluxes. We report on a new precision measurement of the cross section of this reaction, following our previous experiment with an implanted 7Be target, a raster scanned beam and the elimination of the backscattering loss. The new measurement incorporates a more abundant 7Be target and a number of improvements in design and procedure. The point at Elab=991 keV was measured several times under varying conditions, yielding a value of S17(Ec.m. =850 keV) = 24.0(5) eV b. Measurements were carried out at lower energies as well. Due to the precise knowledge of the implanted 7Be density profile it was possible to reconstitute both the off- and on resonance parts of the cross section and to obtain from the entire set of measurements an extrapolated value of S17(0)=21.2(7) eV b.Comment: 4 Pages, 3 Figure

LUNA: a Laboratory for Underground Nuclear Astrophysics

It is in the nature of astrophysics that many of the processes and objects one tries to understand are physically inaccessible. Thus, it is important that those aspects that can be studied in the laboratory be rather well understood. One such aspect are the nuclear fusion reactions, which are at the heart of nuclear astrophysics. They influence sensitively the nucleosynthesis of the elements in the earliest stages of the universe and in all the objects formed thereafter, and control the associated energy generation, neutrino luminosity, and evolution of stars. We review an experimental approach for the study of nuclear fusion reactions based on an underground accelerator laboratory, named LUNA.Comment: Invited Review; accepted for publication in Reports on Progress in Physics; 26 pages; 27 figure

Can the neutron-capture cross sections be measured with Coulomb dissociation?

In this paper we present first results from a 8Li electromagnetic neutron-breakup experiment. Specific reactions studied were Pb( 8Li, 7Li+n) Pb and C( 8Li, 7Li+n) C at 41MeV/nucleon beam energy. This is an effort to compare the results of a Coulomb dissociation experiment with the well determined (n,γ) reaction cross sections at astrophysical energies. The angular dependence of the cross section above 7 degree, which is the grazing angle of 8Li- Pb system, is similar in shape for lead and carbon and approximately proportional to A 2/3 in magnitude indicating that the nuclear dissociation is the main component in this region. At very forward angles the angular distributions differ significantly and the electromagnetic dissociation dominates for the lead, although the nuclear contribution is not negligible