Magnetic core nanoparticles coated by titania and alumina for water and wastewater remediation from metal contaminants

Nanomaterials have been widely used for remediation of contaminated streams. However, using nanomaterials within water and wastewater might be dangerous since fate and health impact of nanoparticles is still unknown. Therefore, it is mandatory to avoid contamination by removing all the nanoparticles from the treated stream. This can be performed by immobilizing the nanoparticles on supports, although this approach leads to lower efficiency values. Another possibility is to use suspended nanoparticles: in this case, efficiency of the treatment process is enhanced. If nanomaterials have a magnetic core-shell, then suspended nanoparticles can be removed in a safe and easy was by using magnetic traps. In the present study, new nanomaterials based on magnetic core-shell structure were developed: the magnetic core guarantees a complete removal from the treated water and wastewater streams, whereas the shell (coating) is functionalized to eliminate specific classes of pollutants. A first experimental step allowed to produce the magnetic nanoparticles and perform a coating with SiO2 in order to electrically isolate the core from the ambient and to avoid degradation. This procedure is well established and the production of SiO2 coated magnetic nanoparticles are nowadays a validated procedure by using a spinning disk reactor.In a successive step, the silica shell magnetic cores were coated by titania and/or activated alumina particles with the aim of removing metals by adsorption. In the present study, the arsenic adsorption capacity of silica shell magnetic cores nanoparticles coated by titania and/or activated was investigated through kinetic experiments. All the tested adsorbents performed very well showing very rapid rates of the adsorption process. Among them, the best performing media were found to be those with titania coating. The best fitting kinetic model was found to be the pseudo-second order one for all of the adsorbents

Defining a Trade-Off Between Spatial and Temporal Resolution of a Geosynchronous SAR mission for Soil Moisture Monitoring

The next generation of synthetic aperture radar (SAR) systems could foresee satellite missions based on a geosynchronous orbit (GEO SAR). These systems are able to provide radar images with an unprecedented combination of spatial ( 641 km) and temporal ( 6412 h) resolutions. This paper investigates the GEO SAR potentialities for soil moisture (SM) mapping finalized to hydrological applications, and defines the best compromise, in terms of image spatio-temporal resolution, for SM monitoring. A synthetic soil moisture\u2013data assimilation (SM-DA) experiment was thus set up to evaluate the impact of the hydrological assimilation of different GEO SAR-like SM products, characterized by diverse spatio-temporal resolutions. The experiment was also designed to understand if GEO SAR-like SM maps could provide an added value with respect to SM products retrieved from SAR images acquired from satellites flying on a quasi-polar orbit, like Sentinel-1 (POLAR SAR). Findings showed that GEO SAR systems provide a valuable contribution for hydrological applications, especially if the possibility to generate many sub-daily observations is sacrificed in favor of higher spatial resolution. In the experiment, it was found that the assimilation of two GEO SAR-like observations a day, with a spatial resolution of 100 m, maximized the performances of the hydrological predictions, for both streamflow and SM state forecasts. Such improvements of the model performances were found to be 45% higher than the ones obtained by assimilating POLAR SAR-like SM maps

A Low-Power Sigma-Delta Modulator for Healthcare and Medical Diagnostic Applications

This paper presents a switched-capacitor Sigma-Delta modulator designed in 90-nm CMOS technology, operating at 1.2-V supply voltage. The modulator targets healthcare and medical diagnostic applications where the readout of small-bandwidth signals is required. The design of the proposed A/D converter was optimized to achieve the minimum power consumption and area. A remarkable performance improvement is obtained through the integration of a low-noise amplifier with modified Miller compensation and rail-to-rail output stage. The manuscript also presents a set of design equations, from the small-signal analysis of the amplifier, for an easy design of the modulator in different technology nodes. The Sigma-Delta converter achieves a measured 96-dB dynamic range, over a 250-Hz signal bandwidth, with an oversampling ratio of 500. The power consumption is 30 μW, with a silicon area of 0.39 mm²

A Multilevel Architecture for Autonomous UAVs

In this paper, a multilevel architecture able to interface an on-board computer with a generic UAV flight controller and its radio receiver is proposed. The computer board exploits the same standard communication protocol of UAV flight controllers and can easily access additional data, such as: (i) inertial sensor measurements coming from a multi-sensor board; (ii) global navigation satellite system (GNSS) coordinates; (iii) streaming video from one or more cameras; and (iv) operator commands from the remote control. In specific operating scenarios, the proposed platform is able to act as a “cyber pilot” which replaces the role of a human UAV operator, thus simplifying the development of complex tasks such as those based on computer vision and artificial intelligence (AI) algorithms which are typically employed in autonomous flight operations

An evaluation of the potential of Sentinel 1 for improving flash flood predictions via soil moisture–data assimilation

open8siThe assimilation of satellite-derived soil moisture estimates (soil moisture–data assimilation, SM–DA) into hydrological models has the potential to reduce the uncertainty of streamflow simulations. The improved capacity to moni- tor the closeness to saturation of small catchments, such as those characterizing the Mediterranean region, can be exploited to enhance flash flood predictions. When compared to other microwave sensors that have been exploited for SM– DA in recent years (e.g. the Advanced SCATterometer – AS- CAT), characterized by low spatial/high temporal resolution, the Sentinel 1 (S1) mission provides an excellent opportu- nity to monitor systematically soil moisture (SM) at high spatial resolution and moderate temporal resolution. The aim of this research was thus to evaluate the impact of S1-based SM–DA for enhancing flash flood predictions of a hydro- logical model (Continuum) that is currently exploited for civil protection applications in Italy. The analysis was car- ried out in a representative Mediterranean catchment prone to flash floods, located in north-western Italy, during the time period October 2014–February 2015. It provided some important findings: (i) revealing the potential provided by S1- based SM–DA for improving discharge predictions, espe- cially for higher flows; (ii) suggesting a more appropriate pre-processing technique to be applied to S1 data before the assimilation; and (iii) highlighting that even though high spa- tial resolution does provide an important contribution in a SM–DA system, the temporal resolution has the most crucial role. S1-derived SM maps are still a relatively new product and, to our knowledge, this is the first work published in an international journal dealing with their assimilation within a hydrological model to improve continuous streamflow simulations and flash flood predictions. Even though the reported results were obtained by analysing a relatively short time pe- riod, and thus should be supported by further research activ- ities, we believe this research is timely in order to enhance our understanding of the potential contribution of the S1 data within the SM–DA framework for flash flood risk mitigation.openCenci, Luca; Pulvirenti, Luca; Boni, Giorgio; Chini, Marco; Matgen, Patrick; Gabellani, Simone; Squicciarino, Giuseppe; Pierdicca, NazzarenoCenci, Luca; Pulvirenti, Luca; Boni, Giorgio; Chini, Marco; Matgen, Patrick; Gabellani, Simone; Squicciarino, Giuseppe; Pierdicca, Nazzaren

Fast Obstacle Detection System for UAS Based on Complementary Use of Radar and Stereoscopic Camera

Autonomous unmanned aerial systems (UAS) are having an increasing impact in the scientific community. One of the most challenging problems in this research area is the design of robust real-time obstacle detection and avoidance systems. In the automotive field, applications of obstacle detection systems combining radar and vision sensors are common and widely documented. However, these technologies are not currently employed in the UAS field due to the major complexity of the flight scenario, especially in urban environments. In this paper, a real-time obstacle-detection system based on the use of a 77 GHz radar and a stereoscopic camera is proposed for use in small UASs. The resulting system is capable of detecting obstacles in a broad spectrum of environmental conditions. In particular, the vision system guarantees a high resolution for short distances, while the radar has a lower resolution but can cover greater distances, being insensitive to poor lighting conditions. The developed hardware and software architecture and the related obstacle-detection algorithm are illustrated within the European project AURORA. Experimental results carried out employing a small UAS show the effectiveness of the obstacle detection system and of a simple avoidance strategy during several autonomous missions on a test site

Raccontare la valutazione sommativa. Strategie per rendere formativo il voto

The summative assessment is known, mainly in the upper secondaryschool, as the grade that the teachers give after an oral, written or practicalexamination. Sometimes, the teachers talk and debate with the pupils,sometimes the pupils are only informed without underlining any formativeaspects. If the teachers tell and discuss the summative assessment with thepupils, they can activate several formative values which can remain latentand hidden. This situation can rise misunderstandings and the assessmentcannot trigger metacognitive and self-reflective processes. This experimentalstudy was aimed at verifying that the organization of modalities ofgrade’s communication among teachers, pupils and parents can foster andenhance a better comprehension of the assessment and start meaningfulformative processes.La valutazione sommativa è meglio conosciuta, soprattutto nella scuola secondariadi II grado, come il voto che viene assegnato dopo una verificaorale, scritta o pratica. Talvolta gli insegnanti accompagnano la comunicazionedel voto con dialoghi o discussioni con gli studenti talora, invece, ilvoto viene comunicato in maniera asciutta senza la valorizzazione degli aspettiformativi. A seconda di come viene raccontata e dialogata la valutazionesommativa, possono essere attivate quelle valenze formative che ilvoto porta con sé ma che possono rimanere latenti e nascoste. Ciò può farnascere incomprensioni e la valutazione rischia di non innescare processiautoriflessivi e metacognitivi. Questo studio sperimentale ha avuto l’obiettivodi verificare che la strutturazione di modalità di esplicazione del votofra insegnanti, studenti e famiglie favorisce una migliore comprensione dellavalutazione e origina processi formativi significativi