Validation of a Method to Prepare Artificial Chylomicron Remnant-like Particles

1 página. Proceedings and Abstracts of the 2nd International Symposium on Chylomicrons in Disease-2 (ISCD2)Resumen póster.Peer reviewe

Combining high strength and moderate ductility in wear resistant coatings: a MO2BC study

Wear resistant coatings employed in cutting and forming applications usually require the combination of high stiffness and high hardness, as these properties often enable low wear rates. Moreover, moderate ductility is often desirable as crack formation can lead to early service failure. Traditionally, the combination of high stiffness and high ductility has been considered as self-excluding. However, recent investigations based on correlative experimental and theoretical research suggest that this empirical relationship can be overcome by a new generation of hard coating materials. For example, ab initio calculations have predicted Mo2BC to exhibit a high stiffness in combination with moderate ductility [1]. The material crystallizes in an orthorhombic structure (space group Cmcm), in which B atoms are positioned in Mo6B trigonal prisms and C atoms are at Mo6C octahedral sites in alternating sequence (unit cell is shown in Fig. 1a). The calculated bulk modulus of 324 GPa for Mo2BC surpasses the one of Ti0.75Al0.25N (178 GPa) [2], often referred as benchmark coating, by more than 50%. In addition, Mo2BC has been also predicted to be moderately ductile based on its ratio of bulk to shear moduli (B/G) and the calculated positive Cauchy pressure [3]. Please click Additional Files below to see the full abstract

Influence of alloying elements on the mechanical properties, especially fracture toughness, of the WB2-z base system

Transition metal diborides are an emerging class of thin film materials with promising properties ranging from ultra-low compressibility, high thermal stability, super hardness to superconductivity. These properties allow an application as protective coating in harsh environments. Our recent ab initio calculations suggest an attractive combination of both, high hardness and relatively high fracture toughness, for WB2. This is enabled by a stabilization of the α-structure (space group 191, AlB2-prototype, P6/mmm) over the intrinsic more stable ω-structure due to omnipresent point defects in physical vapor deposited coatings (i.e. boron and metal vacancies) [1]. However, those point defects in turn lower the thermal stability as the are affected by recovery events, leading to phase transformation into the ω-type. Further calculations point towards a stabilization of the α-type with the addition of Ta (which diboride is stabilized in the α-structure without the need of vacancies) at—compared to other transition metals investigated—low cost on ductility. Within this study we deposited various W1-xMxB2-z solid solution coatings with different alloying element contents and examined them for mechanical properties and thermal stability. It was found for M=Ta that the hardness increases ~4 GPa (from 40.8±1.5 to 45.0±2.0 GPa) together with an improvement of the thermal stability (a change of the phase transformation temperature from ~800-1000 °C to over 1400 °C was observed) [2,3]. Besides these characteristics, in various applications a certain amount of damage tolerance (crack initiation and propagation) is required to prevent premature failure. To assess this behavior, we determined the fracture toughness of these coatings by performing micromechanical experiments by means of single cantilever bending tests within the framework of specifications given by Matoy et al. and Brinckmann et al. [4–6]. At the same time of the increase in hardness and thermal stability, we observe a decrease (in agreement with our DFT calculations) in fracture toughness (from 3.7±0.3 MPaÖm for to 3.0±0.2 MPaÖm) with the addition of tantalum up to a maximum content of 26 at% on the metal sublattice. [1] V. Moraes, H. Riedl, C. Fuger, P. Polcik, H. Bolvardi, D. Holec, P.H. Mayrhofer, Sci. Rep. (2018). [2] V. Moraes, C. Fuger, V. Paneta, D. Primetzhofer, P. Polcik, H. Bolvardi, M. Arndt, H. Riedl, P.H. Mayrhofer, Scr. Mater. 155 (2018) 5–10. [3] C. Fuger, V. Moraes, R. Hahn, H. Bolvardi, P. Polcik, H. Riedl, P.H. Mayrhofer, MRS Commun. (2019) 1–6. [4] K. Matoy, H. Schönherr, T. Detzel, T. Schöberl, R. Pippan, C. Motz, G. Dehm, Thin Solid Films 518 (2009) 247–256. [5] S. Brinckmann, C. Kirchlechner, G. Dehm, Scr. Mater. 127 (2017) 76–78. [6] S. Brinckmann, K. Matoy, C. Kirchlechner, G. Dehm, Acta Mater. 136 (2017) 281–287

Modeling of metastable phase formation diagrams for sputtered thin films

A method to model the metastable phase formation in the Cu–W system based on the critical surface diffusion distance has been developed. The driver for the formation of a second phase is the critical diffusion distance which is dependent on the solubility of W in Cu and on the solubility of Cu in W. Based on comparative theoretical and experimental data, we can describe the relationship between the solubilities and the critical diffusion distances in order to model the metastable phase formation. Metastable phase formation diagrams for Cu–W and Cu–V thin films are predicted and validated by combinatorial magnetron sputtering experiments. The correlative experimental and theoretical research strategy adopted here enables us to efficiently describe the relationship between the solubilities and the critical diffusion distances in order to model the metastable phase formation during magnetron sputtering