Die Wirkung von Yoga auf Reiterinnen

Viele Reiter fühlen sich nicht fit fürs Pferd. Fehlende Beweglichkeit und Kraft können eine Ursache für einen Trainingsstillstand sein.Wie sieben jungen Reiterinnen die regelmäßige Praxis von Yoga zu einem besseren Gefühl im Sattel verhelfen konnte und welche weiteren positiven Effekte das Training auf Körper und Geist hat, zeigt diese Studie im Rahmen einer Bachelorarbeit an der HfWU Nürtingen

Two-Step Delamination of Highly Charged, Vermiculite-like Layered Silicates via Ordered Heterostructures

Because of strong Coulomb interactions, the delamination of charged layered materials becomes progressively more difficult with increasing charge density. For instance, highly charged sodium fluorohectorite (Na_0.6Mg_2.4Li_0.6Si₄O₁₀F₂, Na-Hec) cannot be delaminated directly by osmotic swelling in water because its layer charge exceeds the established limit for osmotic swelling of 0.55 per formula unit Si₄O₁₀F₂. Quite surprisingly, we found that this hectorite at the border of the smectite and vermiculite group can, however, be utterly delaminated into 1-nm-thick platelets with a high aspect ratio (24 000) in a two-step process. The hectorite is first converted by partial ion exchange into a one-dimensionally ordered, interstratified heterostructure with strictly alternating Na⁺ and <i>n</i>-butylammonium (C4) interlayers. This heterostructure then spontaneously delaminates into uniform single layers upon immersion in water whereas neither of the homoionic phases (Na-Hec and C4-Hec) swells osmotically. The delamination of more highly charged synthetic layered silicates is a key step to push the aspect ratio beyond the current limits

Strategies for the selective loading of patchy worm-like micelles with functional nanoparticles

Block copolymer self-assembly in solution paves the way for the construction of well-defined compartmentalized nanostructures. These are excellent templates for the incorporation and stabilisation of nanoparticles (NPs), giving rise to highly relevant applications in the field of catalysis or sensing. However, the regio-selective incorporation of NPs in specific compartments is still an issue, especially concerning the loading with different NP types. Using crystallisation-driven self-assembly (CDSA), functional worm-like crystalline-core micelles (wCCMs) with a tailor-made, nanometre-sized patchy corona were prepared as versatile templates for the incorporation and stabilisation of metal and metal oxide NPs. Different strategies, like ligand exchange or co-precipitation of polymer stabilised NPs with one surface patch, were developed that allow the incorporation of NPs in specific regions of the patchy wCCM corona. Independent of the NP type and the incorporation method, the NPs showed no tendency for agglomeration and were fixed within the corona patches of the wCCMs. The binary loading of patchy micelles with metal and metal oxide NPs was realised by combining different loading strategies, yielding hybrids with homogeneously dispersed NPs guided by the patchy structure of the template