380 research outputs found
Calorimetric and magnetic study for NiMnIn and relative cooling power in paramagnetic inverse magnetocaloric systems
The non-stoichiometric Heusler alloy NiMnIn undergoes a
martensitic phase transformation in the vicinity of 345 K, with the high
temperature austenite phase exhibiting paramagnetic rather than ferromagnetic
behavior, as shown in similar alloys with lower-temperature transformations.
Suitably prepared samples are shown to exhibit a sharp transformation, a
relatively small thermal hysteresis, and a large field-induced entropy change.
We analyzed the magnetocaloric behavior both through magnetization and direct
field-dependent calorimetry measurements. For measurements passing through the
first-order transformation, an improved method for heat-pulse relaxation
calorimetry was designed. The results provide a firm basis for the analytic
evaluation of field-induced entropy changes in related materials. An analysis
of the relative cooling power (RCP), based on the integrated field-induced
entropy change and magnetizing behavior of the Mn spin system with
ferromagnetic correlations, shows that a significant RCP may be obtained in
these materials by tuning the magnetic and structural transformation
temperatures through minor compositional changes or local order changes
Purification, crystallization and preliminary X-ray analysis of adenylosuccinate synthetase from the fungal pathogen Cryptococcus neoformans
Periodic orbit resonances in layered metals in tilted magnetic fields
The frequency dependence of the interlayer conductivity of a layered Fermi
liquid in a magnetic field which is tilted away from the normal to the layers
is considered. For both quasi-one- and quasi-two-dimensional systems resonances
occur when the frequency is a harmonic of the frequency at which the magnetic
field causes the electrons to oscillate on the Fermi surface within the layers.
The intensity of the different harmonic resonances varies significantly with
the direction of the field. The resonances occur for both coherent and weakly
incoherent interlayer transport and so their observation does not imply the
existence of a three-dimensional Fermi surface.Comment: 4 pages, RevTeX + epsf, 2 figures. Discussion of other work revised.
To appear in Phys. Rev. B, Rapid Commun., October 1
Determination of the Fermi Velocity by Angle-dependent Periodic Orbit Resonance Measurements in the Organic Conductor alpha-(BEDT-TTF)2KHg(SCN)4
We report detailed angle-dependent studies of the microwave (f=50 to 90 GHz)
interlayer magneto-electrodynamics of a single crystal sample of the organic
charge-density-wave (CDW) conductor alpha-(BEDT-TTF)2KHg(SCN)4. Recently
developed instrumentation enables both magnetic field (B) sweeps for a fixed
sample orientation and, for the first time, angle sweeps at fixed f/B. We
observe series' of resonant absorptions which we attribute to periodic orbit
resonances (POR) - a phenomenon closely related to cyclotron resonance. The
angle dependence of the POR indicate that they are associated with the low
temperature quasi-one-dimensional (Q1D) Fermi surface (FS) of the title
compound; indeed, all of the resonance peaks collapse beautifully onto a single
set of f/B versus angle curves, generated using a semiclassical
magneto-transport theory for a single Q1D FS. We show that Q1D POR measurements
provide one of the most direct methods for determining the Fermi velocity,
without any detailed assumptions concerning the bandstructure; our analysis
yields an average value of v_F=6.5x10^4 m/s. Quantitative analysis of the POR
harmonic content indicates that the Q1D FS is strongly corrugated. This is
consistent with the assumption that the low-temperature FS derives from a
reconstruction of the high temperature quasi-two-dimensional FS, caused by the
CDW instability. Detailed analysis of the angle dependence of the POR yields
parameters associated with the CDW superstructure which are consistent with
published results. Finally, we address the issue as to whether or not the
interlayer electrodynamics are coherent in the title compound.Comment: 28 pages, including 6 figures. Submitted to PR
Does Spin-Orbit Coupling Effect Favor Planar Structures for Small Platinum Clusters?
We have performed full-relativistic density functional theory calculations to
study the geometry and binding energy of different isomers of free platinum
clusters Pt () within the spin multiplicities from singlet to
nonet. The spin-orbit coupling effect has been discussed for the minimum-energy
structures, relative stabilities, vibrational frequencies, magnetic moments,
and the highest occupied and lowest unoccupied molecular-orbital gaps. It is
found in contrast to some of the previous calculations that 3-dimentional
configurations are still lowest energy structures of these clusters, although
spin-orbit effect makes some planar or quasi-planar geometries more stable than
some other 3-dimentional isomers
Modeling of light scattering and haze in semicrystalline polymers
This article reports a new model approach for the description of light scattering in semicrystalline polymers, to describe more precisely the influence of supermolecular structure on the optical properties. This is the first study in which light scattering of polymer films has been modeled using exact Mie scattering theory of radially anisotropic spheres. As a model material a wellâknown polymer, isotactic polypropylene (iPP) was used. Samples were prepared with different sample thicknesses and crystalline structures in order to identify the key parameters of light scattering in polycrystalline polymeric systems. Validation haze measurements were carried out with a spectrophotometer equipped with a 150âmm snapâin integrating sphere. It was found that the optical properties of the polycrystalline sample can be described using multiple light scattering on these scattering centers. Good agreement was found between the simulated and experimentally measured haze values which proves the reliability and applicability of our new approach
The host galaxies of luminous quasars
We present results of a deep HST/WFPC2 imaging study of 17 quasars at z~0.4,
designed to determine the properties of their host galaxies. The sample
consists of quasars with absolute magnitudes in the range -24>M_V>-28, allowing
us to investigate host galaxy properties across a decade in quasar luminosity,
but at a single redshift. We find that the hosts of all the RLQs, and all the
RQQs with nuclear luminosities M_V<-24, are massive bulge-dominated galaxies,
confirming and extending the trends deduced from our previous studies. From the
best-fitting model host galaxies we have estimated spheroid and black-hole
masses, and the efficiency (with respect to Eddington luminosity) with which
each quasar is radiating. The largest inferred black-hole mass in our sample is
\~3.10^9 M_sun, comparable to those at the centres of M87 and Cygnus A. We find
no evidence for super-Eddington accretion in even the most luminous objects. We
investigate the role of scatter in the black-hole:spheroid mass relation in
determining the ratio of quasar to host-galaxy luminosity, by generating
simulated populations of quasars lying in hosts with a Schechter mass function.
Within the subsample of the highest luminosity quasars, the observed variation
in nuclear-host luminosity ratio is consistent with being the result of the
scatter in the black-hole:spheroid relation. Quasars with high nuclear-host
ratios can be explained by sub-Eddington accretion onto black holes in the
high-mass tail of the black-hole:spheroid relation. Our results imply that,
owing to the Schechter cutoff, host mass should not continue to increase
linearly with quasar luminosity, at the very highest luminosities. Any quasars
more luminous than M_V=-27 should be found in massive elliptical hosts which at
the present day would have M_V ~ -24.5.Comment: Accepted for publication in MNRAS. 18 pages; 7 figures and 17
greyscale images are reproduced here at low quality due to space limitations.
High-resolution figures are available from
ftp://ftp.roe.ac.uk/pub/djef/preprints/floyd2004
High-precision calculations of van der Waals coefficients for heteronuclear alkali-metal dimers
Van der Waals coefficients for the heteronuclear alkali-metal dimers of Li,
Na, K, Rb, Cs, and Fr are calculated using relativistic ab initio methods
augmented by high-precision experimental data. We argue that the uncertainties
in the coefficients are unlikely to exceed about 1%.Comment: 11 pages, 2 figs, graphicx.st
Controlling magnetic order and quantum disorder in molecule-based magnets
We investigate the structural and magnetic properties of two molecule-based magnets synthesized from the same starting components. Their different structural motifs promote contrasting exchange pathways and consequently lead to markedly different magnetic ground states. Through examination of their structural and magnetic properties we show that [Cu(pyz)(H2O)(gly)2](ClO4)2 may be considered a quasi-one-dimensional quantum Heisenberg antiferromagnet whereas the related compound [Cu(pyz)(gly)](ClO4), which is formed from dimers of antiferromagnetically interacting Cu2+ spins, remains disordered down to at least 0.03 K in zero field but shows a field-temperature phase diagram reminiscent of that seen in materials showing a Bose-Einstein condensation of magnons
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