Tightly Correlated HI and FUV Emission in the Outskirts of M83

We compare sensitive HI data from The HI Nearby Galaxy Survey (THINGS) and deep far UV (FUV) data from GALEX in the outer disk of M83. The FUV and HI maps show a stunning spatial correlation out to almost 4 optical radii (r25), roughly the extent of our maps. This underscores that HI traces the gas reservoir for outer disk star formation and it implies that massive (at least low level) star formation proceeds almost everywhere HI is observed. Whereas the average FUV intensity decreases steadily with increasing radius before leveling off at ~1.7 r25, the decline in HI surface density is more subtle. Low HI columns (<2 M_solar/pc^2) contribute most of the mass in the outer disk, which is not the case within r25. The time for star formation to consume the available HI, inferred from the ratio of HI to FUV intensity, rises with increasing radius before leveling off at ~100 Gyr, i.e., many Hubble times, near ~1.7 r25. Assuming the relatively short H2 depletion times observed in the inner parts of galaxies hold in outer disks, the conversion of HI into bound, molecular clouds seems to limit star formation in outer galaxy disks. The long consumption times suggest that most of the extended HI observed in M83 will not be consumed by in situ star formation. However, even these low star formation rates are enough to expect moderate chemical enrichment in a closed outer disk.Comment: Accepted for Publication in ApJ

The Distances of SNR W41 and overlapping HII regions

New HI images from the VLA Galactic Plane Survey show prominent absorption features associated with the supernovae remnant G23.3-0.3 (SNR W41). We highlight the HI absorption spectra and the $^{13}$CO emission spectra of eight small regions on the face of W41, including four HII regions, three non-thermal emission regions and one unclassified region. The maximum velocity of absorption for W41 is 78$\pm$2 km/s and the CO cloud at radial velocity 95$\pm$5 km/s is behind W41. Because an extended TeV source, a diffuse X-ray enhancement and a large molecular cloud at radial velocity 77$\pm$5 km/s are also projected at the center of W41, these yield the kinematic distance of 3.9 to 4.5 kpc for W41. For HII regions, our analyses reveal that both G23.42-0.21 and G23.07+0.25 are at the far kinematic distances ($\sim$9.9 kpc and $\sim$ 10.6 kpc respectively) of their recombination-line velocities (103$\pm$0.5 km/s and 89.6$\pm$2.1 km/s respectively), G23.07-0.37 is at the near kinematic distance (4.4$\pm$0.3 kpc) of its recombination-line velocity (82.7$\pm$2.0 km/s), and G23.27-0.27 is probably at the near kinematic distance (4.1$\pm$0.3 kpc) of its recombination-line velocity (76.1$\pm$0.6 km/s).Comment: 11 pages, 3 figs., 2 tables, accepted by A

A Magellanic Origin for the Warp of the Galaxy

We show that a Magellanic Cloud origin for the warp of the Milky Way can explain most quantitative features of the outer HI layer recently identified by Levine, Blitz & Heiles (2005). We construct a model similar to that of Weinberg (1998) that produces distortions in the dark matter halo, and we calculate the combined effect of these dark-halo distortions and the direct tidal forcing by the Magellanic Clouds on the disk warp in the linear regime. The interaction of the dark matter halo with the disk and resonances between the orbit of the Clouds and the disk account for the large amplitudes observed for the vertical m=0,1,2 harmonics. The observations lead to six constraints on warp forcing mechanisms and our model reasonably approximates all six. The disk is shown to be very dynamic, constantly changing its shape as the Clouds proceed along their orbit. We discuss the challenges to MOND placed by the observations.Comment: 4 pages, 3 figures, submitted to ApJ Letters. Additional graphics, 3d visualizations and movies available at http://www.astro.umass.edu/~weinberg/lm

Kinetics of CH₂OO reactions with SO₂, NO₂, NO, H₂O and CH₃CHO as a function of pressure

Kinetics of CH₂OO Criegee intermediate reactions with SO₂, NO₂, NO, H₂O and CH₃CHO and CH₂I radical reactions with NO₂ are reported as a function of pressure at 295 K. Measurements were made under pseudo-first-order conditions using flash photolysis of CH₂I₂–O₂–N₂ gas mixtures in the presence of excess co-reagent combined with monitoring of HCHO reaction products by laser-induced fluorescence (LIF) spectroscopy and, for the reaction with SO₂, direct detection of CH₂OO by photoionisation mass spectrometry (PIMS). Rate coefficients for CH₂OO + SO₂ and CH₂OO + NO₂ are independent of pressure in the ranges studied and are (3.42 ± 0.42) × 10‾¹¹ cm³ s‾¹ (measured between 1.5 and 450 Torr) and (1.5 ± 0.5) × 10‾¹² cm³ s‾¹ (measured between 25 and 300 Torr), respectively. The rate coefficient for CH₂OO + CH₃CHO is pressure dependent, with the yield of HCHO decreasing with increasing pressure. Upper limits of 2 × 10−13 cm³ s‾¹ and 9 × 10−17 cm³ s‾¹ are placed on the rate coefficients for CH₂OO + NO and CH₂OO + H₂O, respectively. The upper limit for the rate coefficient for CH₂OO + H₂O is significantly lower than has been reported previously, with consequences for modelling of atmospheric impacts of CH₂OO chemistry

Unusually Luminous Giant Molecular Clouds in the Outer Disk of M33

We use high spatial resolution (~7pc) CARMA observations to derive detailed properties for 8 giant molecular clouds (GMCs) at a galactocentric radius corresponding to approximately two CO scale lengths, or ~0.5 optical radii (r25), in the Local Group spiral galaxy M33. At this radius, molecular gas fraction, dust-to-gas ratio and metallicity are much lower than in the inner part of M33 or in a typical spiral galaxy. This allows us to probe the impact of environment on GMC properties by comparing our measurements to previous data from the inner disk of M33, the Milky Way and other nearby galaxies. The outer disk clouds roughly fall on the size-linewidth relation defined by extragalactic GMCs, but are slightly displaced from the luminosity-virial mass relation in the sense of having high CO luminosity compared to the inferred virial mass. This implies a different CO-to-H2 conversion factor, which is on average a factor of two lower than the inner disk and the extragalactic average. We attribute this to significantly higher measured brightness temperatures of the outer disk clouds compared to the ancillary sample of GMCs, which is likely an effect of enhanced radiation levels due to massive star formation in the vicinity of our target field. Apart from brightness temperature, the properties we determine for the outer disk GMCs in M33 do not differ significantly from those of our comparison sample. In particular, the combined sample of inner and outer disk M33 clouds covers roughly the same range in size, linewidth, virial mass and CO luminosity than the sample of Milky Way GMCs. When compared to the inner disk clouds in M33, however, we find even the brightest outer disk clouds to be smaller than most of their inner disk counterparts. This may be due to incomplete sampling or a potentially steeper cloud mass function at larger radii.Comment: Accepted for Publication in ApJ; 7 pages, 4 figure

An instrument to measure fast gas phase radical kinetics at hight temperatures and pressures

Fast radical reactions are central to the chemistry of planetary atmospheres and combustion systems. Laser-induced fluorescence is a highly sensitive and selective technique that can be used to monitor a number of radical species in kinetics experiments, but is typically limited to low pressure systems owing to quenching of fluorescent states at higher pressures. The design and characterisation of an instrument is reported using laser-induced fluorescence detection to monitor fast radical kinetics (up to 25,000 s-1) at high temperatures and pressures by sampling from a high pressure reaction region to a low pressure detection region. Kinetics have been characterised at temperatures reaching 740 K and pressures up to 2 atm, with expected maximum operational conditions of up to ~ 900 K and ~ 5 atm. The distance between the point of sampling from the high pressure region and the point of probing within the low pressure region is critical to the measurement of fast kinetics. The instrumentation described in this work can be applied to the measurement of kinetics relevant to atmospheric and combustion chemistry

Fundamental Aspects of the ISM Fractality

The ubiquitous clumpy state of the ISM raises a fundamental and open problem of physics, which is the correct statistical treatment of systems dominated by long range interactions. A simple solvable hierarchical model is presented which explains why systems dominated by gravity prefer to adopt a fractal dimension around 2 or less, like the cold ISM and large scale structures. This has direct relation with the general transparency, or blackness, of the Universe.Comment: 6 pages, LaTeX2e, crckapb macro, no figure, uuencoded compressed tar file. To be published in the proceeedings of the "Dust-Morphology" conference, Johannesburg, 22-26 January, 1996, D. Block (ed.), (Kluwer Dordrecht

Temperature and Pressure Dependent Kinetics of QOOH Decomposition and Reaction with O2: Experimental and Theoretical Investigations of QOOH Radicals Derived from Cl + (CH3)3COOH

QOOH radicals are key species in autoignition, produced by internal isomerisations of RO2 radicals, and are central to chain branching reactions in low temperature combustion. The kinetics of QOOH radical decomposition and reaction with O2 have been determined as a function of temperature and pressure, using observations of OH radical production and decay following H-atom abstraction from tertiary-butyl hydroperoxide ((CH3)3COOH) by Cl atoms to produce QOOH (.CH2(CH3)2COOH) radicals. The kinetics of QOOH decomposition have been investigated as a function of temperature (251 to 298 K), and pressure (10 to 350 Torr), in helium and nitrogen bath gases, and those of the reaction between QOOH and O2 have been investigated as a function of temperature (251 to 304 K), and pressure (10 to 100 Torr) in He and N2. Decomposition of the QOOH radicals was observed to display temperature and pressure dependence, with a barrier height for decomposition of (44.7 ± 4.0) kJ mol-1 determined by master equation fitting to the experimental data. The rate coefficient for the reaction between QOOH and O2 was determined to be (5.6 ± 1.7) × 10-13 cm3 s-1 at 298 K, with no significant dependence on pressure, and can be described by the Arrhenius parameters A = (7.3 ± 6.8) × 10-14 cm3 s-1 and Ea = -(5.4 ± 2.1) kJ mol-1 in the temperature range 251 to 304 K. This work represents the first measurements of any QOOH radical kinetics as a function of temperature and pressure