Configurable LDPC Decoder Architecture for Regular and Irregular Codes

Low Density Parity Check (LDPC) codes are one of the best error correcting codes that enable the future generations of wireless devices to achieve higher data rates with excellent quality of service. This paper presents two novel flexible decoder architectures. The first one supports (3, 6) regular codes of rate 1/2 that can be used for different block lengths. The second decoder is more general and supports both regular and irregular LDPC codes with twelve combinations of code lengths −648, 1296, 1944-bits and code rates-1/2, 2/3, 3/4, 5/6- based on the IEEE 802.11n standard. All codes correspond to a block-structured parity check matrix, in which the sub-blocks are either a shifted identity matrix or a zero matrix. Prototype architectures for both LDPC decoders have been implemented and tested on a Xilinx field programmable gate array.NokiaNational Science Foundatio

Ozone-enabled fatty acid discovery reveals unexpected diversity in the human lipidome.

Fatty acid isomers are responsible for an under-reported lipidome diversity across all kingdoms of life. Isomers of unsaturated fatty acids are often masked in contemporary analysis by incomplete separation and the absence of sufficiently diagnostic methods for structure elucidation. Here, we introduce a comprehensive workflow, to discover unsaturated fatty acids through coupling liquid chromatography and mass spectrometry with gas-phase ozonolysis of double bonds. The workflow encompasses semi-automated data analysis and enables de novo identification in complex media including human plasma, cancer cell lines and vernix caseosa. The targeted analysis including ozonolysis enables structural assignment over a dynamic range of five orders of magnitude, even in instances of incomplete chromatographic separation. Thereby we expand the number of identified plasma fatty acids two-fold, including non-methylene-interrupted fatty acids. Detection, without prior knowledge, allows discovery of non-canonical double bond positions. Changes in relative isomer abundances reflect underlying perturbations in lipid metabolism

Valorisation of Biowastes for the Production of Green Materials Using Chemical Methods

With crude oil reserves dwindling, the hunt for a sustainable alternative feedstock for fuels and materials for our society continues to expand. The biorefinery concept has enjoyed both a surge in popularity and also vocal opposition to the idea of diverting food-grade land and crops for this purpose. The idea of using the inevitable wastes arising from biomass processing, particularly farming and food production, is, therefore, gaining more attention as the feedstock for the biorefinery. For the three main components of biomass—carbohydrates, lipids, and proteins—there are long-established processes for using some of these by-products. However, the recent advances in chemical technologies are expanding both the feedstocks available for processing and the products that be obtained. Herein, this review presents some of the more recent developments in processing these molecules for green materials, as well as case studies that bring these technologies and materials together into final products for applied usage