Photochemistry of Some Metal Carbonyls in Frozen Solvent Glasses

Photolysis reactions of Fe(CO)5, group VI hexacarbonyls, some substituted group VI hexacarbonyl derivatives, and cyclopentadienyl manganese tricarbonyl and some related compounds in hydrocarbon glass have been examined. Reactions in the more reactive glass. 2-methyltetrahydrofuran, and reactions of the above species in hydrocarbon glass in the presence of some potential ligands have also been examined. The glass temperature throughout this work was 77K. Reaction monitoring throughout was by i. r. spectroscopy, mostly observing the carbonyl stretching region only, and the object of the work was to observe the results of photolysis in glasses and to correlate these with results obtained in very low temperature gas matrices and in solution by other workers rather than to determine the actual photolysis mechanisms. In many experiments glasses containing photolysis fragments were deliberately allowed to warm up beyond the glass softening temperature and the changes occurring on glass softening were monitored in an attempt to link the results obtained in the glasses with results of photolysis in solution where molecules are free to associate. The predominant reaction in all the systems studied in glasses was stepwise CO loss, and many CO deficient fragments have been observed and identified as far as is possible from their i. r. spectra. In cases where the results of matrix isolation studies were available the results obtained in this work are consistent with these. The results obtained in hydrocarbon glass also support the view that saturated hydrocarbon interacts with CO deficient metal carbonyl fragments to an extent not realised until very recently. Another point of general interest which has arisen from the photolysis reactions in hydrocarbon in the presence of added donors is the importance of pre-photolytic association of carbonyl and potential ligand. The possible effect of this type of association on solution photochemical reactions does not seem to have been previously recognised and should certainly be investigated

η\eta Carinae's Dusty Homunculus Nebula from Near-Infrared to Submillimeter Wavelengths: Mass, Composition, and Evidence for Fading Opacity

Infrared observations of the dusty, massive Homunculus Nebula around the luminous blue variable $\eta$ Carinae are crucial to characterize the mass-loss history and help constrain the mechanisms leading to the Great Eruption. We present the 2.4 - 670 $\mu$m spectral energy distribution, constructed from legacy ISO observations and new spectroscopy obtained with the {\em{Herschel Space Observatory}}. Using radiative transfer modeling, we find that the two best-fit dust models yield compositions which are consistent with CNO-processed material, with iron, pyroxene and other metal-rich silicates, corundum, and magnesium-iron sulfide in common. Spherical corundum grains are supported by the good match to a narrow 20.2 $\mu$m feature. Our preferred model contains nitrides AlN and Si$_3$N$_4$ in low abundances. Dust masses range from 0.25 to 0.44 $M_\odot$ but $M_{\rm{tot}} \ge$ 45 $M_\odot$ in both cases due to an expected high Fe gas-to-dust ratio. The bulk of dust is within a 5$"$ $\times$ 7$"$ central region. An additional compact feature is detected at 390 $\mu$m. We obtain $L_{\rm{IR}}$ = 2.96 $\times$ 10$^6$ $L_\odot$, a 25\% decline from an average of mid-IR photometric levels observed in 1971-1977. This indicates a reduction in circumstellar extinction in conjunction with an increase in visual brightness, allowing 25-40\% of optical and UV radiation to escape from the central source. We also present an analysis of $^{12}$CO and $^{13}$CO $J = 5-4$ through $9-8$ lines, showing that the abundances are consistent with expectations for CNO-processed material. The [$^{12}$C~{\sc{ii}}] line is detected in absorption, which we suspect originates in foreground material at very low excitation temperatures.Comment: Accepted in Ap

Economic aspects of creamery organization

This archival publication may not reflect current scientific knowledge or recommendations

Directing diarrhoeal disease research towards disease-burden reduction

Despite gains in controlling mortality relating to diarrhoeal disease, the burden of disease remains unacceptably high. To refocus health research to target disease-burden reduction as the goal of research in child health, the Child Health and Nutrition Research Initiative developed a systematic strategy to rank health research options. This priority-setting exercise included listing of 46 competitive research options in diarrhoeal disease and their critical and quantitative appraisal by 10 experts based on five criteria for research that reflect the ability of the research to be translated into interventions and achieved disease-burden reduction. These criteria included the answerability of the research questions, the efficacy and effectiveness of the intervention resulting from the research, the maximal potential for disease-burden reduction of the interventions derived from the research, the affordability, deliverability, and sustainability of the intervention supported by the research, and the overall effect of the research-derived intervention on equity. Experts scored each research option independently to delineate the best investments for diarrhoeal disease control in the developing world to reduce the burden of disease by 2015. Priority scores obtained for health policy and systems research obtained eight of the top 10 rankings in overall scores, indicating that current investments in health research are significantly different from those estimated to be the most effective in reducing the global burden of diarrhoeal disease by 2015

Economies of space and the school geography curriculum

This paper is about the images of economic space that are found in school curricula. It suggests the importance for educators of evaluating these representations in terms of the messages they contain about how social processes operate. The paper uses school geography texts in Britain since the 1970s to illustrate the different ways in which economic space has been represented to students, before exploring some alternative resources that could be used to provide a wider range of representations of economic space. The paper highlights the continued importance of understanding the politics of school knowledge

Primordial Star Formation under Far-ultraviolet radiation

Thermal and chemical evolution of primordial gas clouds irradiated with far-ultraviolet (FUV; < 13.6 eV) radiation is investigated. In clouds irradiated by intense FUV radiation, sufficient hydrogen molecules to be important for cooling are never formed. However, even without molecular hydrogen, if the clouds are massive enough, they start collapsing via atomic hydrogen line cooling. Such clouds continue to collapse almost isothermally owing to successive cooling by H^{-} free-bound emission up to the number density of 10^{16} cm^{-3}. Inside the clouds, the Jeans mass eventually falls well below a solar mass. This indicates that hydrogen molecules are dispensable for low-mass primordial star formation, provided fragmentation of the clouds occurs at sufficiently high density.Comment: 32 pages and 9 figures. ApJ, in pres

Sports mega-events – three sites of contemporary political contestation

This article discusses the contemporary politics of sports mega-events, involving the Olympic Games and Fédération Internationale de Football Association (FIFA) Men’s Football World Cup Finals as well as other lower ‘order’ sports megas, taking two main forms: the promotional and the protest. There is a politics in, and a politics of, sports mega-events. The former focuses on the internal politics of the organizing bodies, such as the International Olympic Committee and FIFA. This form of politics has been written about elsewhere, and hence, there is no detailed discussion in this article about it. Instead this article offers a brief discussion of the range and number of sports mega-events since 2000, an assessment of the contemporary politics of sports mega-events, a focus on three main sites of political contestation – rights, legacy and labour, and finally, it offers conclusions about research into the politics of sports mega-events

Carinae's Dusty Homunculus Nebula from Near-Infrared to Submillimeter Wavelengths: Mass, Composition, and Evidence for Fading Opacity

Infrared observations of the dusty, massive Homunculus Nebula around the luminous blue variable Carinae are crucial to characterize the mass-loss history and help constrain the mechanisms leading to the great eruption. We present the 2.4-670 m spectral energy distribution, constructed from legacy Infrared Space Observatory observations and new spectroscopy obtained with the Herschel Space Observatory. Using radiative transfer modeling, we find that the two best-fit dust models yield compositions that are consistent with CNO-processed material, with iron, pyroxene and other metal-rich silicates, corundum, and magnesium-iron sulfide in common. Spherical corundum grains are supported by the good match to a narrow 20.2 m feature. Our preferred model contains nitrides AlN and Si3N4 in low abundances. Dust masses range from 0.25 to 0.44 M, but M(sub tot) 45 M in both cases, due to an expected high Fe gas-to-dust ratio. The bulk of dust is within a 5" x 7" central region. An additional compact feature is detected at 390 m. We obtain L = 2.96 x 10(exp 6) Lunar mass, a 25% decline from an average of mid-IR photometric levels observed in 1971-1977. This indicates a reduction in circumstellar extinction in conjunction with an increase in visual brightness, allowing 25%-40% of optical and UV radiation to escape from the central source. We also present an analysis of 12CO and 13CO J = 5-4 through 9-8 lines, showing that the abundances are consistent with expectations for CNO-processed material. The [12CII] line is detected in absorption, which we suspect originates in foreground material at very low excitation temperatures