Identifying electron transfer coordinates in Donor-Bridge-Acceptor systems using mode projection analysis

We report upon an analysis of the vibrational modes that couple and drive the state-to-state electronic transfer branching ratios in a model donor-bridge-acceptor system consisting of a phenothiazine-based donor linked to a naphthalene-monoimide acceptor via a platinum-acetylide bridging unit. Our analysis is based upon an iterative Lanczos search algorithm that finds superpositions of vibronic modes that optimize the electron/nuclear coupling using input from excited-state quantum chemical methods. Our results indicate that the electron transfer reaction coordinates between a triplet charge transfer state and lower lying chargeseparated and localised excitonic states are dominated by asymmetric and symmetric modes of the acetylene groups on either side of the central atom in this system. In particular, we find that while a nearly symmetric mode couples both the charge-separation and charge-recombination transitions more or less equally, the coupling along an asymmetric mode is far greater suggesting that IR excitation of the acetylene modes preferentially enhances charge recombination transition relative to charge-separation

Finding Common Ground: A Survey of Capacitive Sensing in Human-Computer Interaction

For more than two decades, capacitive sensing has played a prominent role in human-computer interaction research. Capacitive sensing has become ubiquitous on mobile, wearable, and stationary devices---enabling fundamentally new interaction techniques on, above, and around them. The research community has also enabled human position estimation and whole-body gestural interaction in instrumented environments. However, the broad field of capacitive sensing research has become fragmented by different approaches and terminology used across the various domains. This paper strives to unify the field by advocating consistent terminology and proposing a new taxonomy to classify capacitive sensing approaches. Our extensive survey provides an analysis and review of past research and identifies challenges for future work. We aim to create a common understanding within the field of human-computer interaction, for researchers and practitioners alike, and to stimulate and facilitate future research in capacitive sensing

Forming and smoothing D{sub 2} and HD layers for ICF by infra-red heating

We describe a technique to form and smooth uniform solid D{sub 2}, HD or DT layers for inertial confinement fusion targets. Pumping the infrared (IR) collision induced vibration-rotation band generates a bulk heating of the solid. Shadowgraphs reveal that this bulk heat quickly redistributes the solid into a relatively uniform layer depending on the IR intensity profile. Measured redistribution time constants are used to determine the conversion efficiency of IR light into bulk heat. Phase shifting interferometry reveals that the surface roughness decreases with increasing IR heating

Traveling planetary wave activity from mesopause region airglow temperatures determined by the Network for the Detection of Mesospheric Change (NDMC)

The global distribution of traveling planetary wave (PW) activity in the mesopause region is estimated for the first time from ground-based airglow measurements. Monthly and total mean climatologies of PW power are determined from rotational temperatures measured at 19 sites from 78° N to 76° S which contribute to the Network for the Detection of Mesospheric Change (NDMC). Wave power is expressed as the standard deviation of nocturnal mean temperature around the seasonal temperature variation. The results from 20° N confirm the SABER traveling PW proxy by Offermann et al. (2009, J. Geophys. Res. 114, D06110) at two altitudes. Most sites between 69° S and 69° N show total mean traveling PW activity of about 6 K, and only some high latitude sites have considerably higher activity levels. At the two tropical sites, there is practically no seasonal variation of PW activity. At 70% of the midlatitude sites, the seasonal variation is moderate for most of the year, but it is quite appreciable at all high latitude sites. Results about traveling PW activity at 87 km and 95 km available from several sites signal similar behavior at both altitudes. The total mean climatological results here obtained have further been used to separate the traveling PW contribution from the superposition of wave types contained in OH rotational temperature fluctuations measured by the SCIAMACHY instrument on Envisat. A narrow equatorial wave activity maximum is probably caused by gravity waves, while a tendency towards greater activity at higher northern latitudes may be due to stationary planetary waves