Non-monotonous crossover between capillary condensation and interface localisation/delocalisation transition in binary polymer blends

Within self-consistent field theory we study the phase behaviour of a symmetric binary AB polymer blend confined into a thin film. The film surfaces interact with the monomers via short range potentials. One surface attracts the A component and the corresponding semi-infinite system exhibits a first order wetting transition. The surface interaction of the opposite surface is varied as to study the crossover from capillary condensation for symmetric surface fields to the interface localisation/delocalisation transition for antisymmetric surface fields. In the former case the phase diagram has a single critical point close to the bulk critical point. In the latter case the phase diagram exhibits two critical points which correspond to the prewetting critical points of the semi-infinite system. The crossover between these qualitatively different limiting behaviours occurs gradually, however, the critical temperature and the critical composition exhibit a non-monotonic dependence on the surface field.Comment: to appear in Europhys.Let

Spontaneous creation of discrete breathers in Josephson arrays

We report on the experimental generation of discrete breather states (intrinsic localized modes) in frustrated Josephson arrays. Our experiments indicate the formation of discrete breathers during the transition from the static to the dynamic (whirling) system state, induced by a uniform external current. Moreover, spatially extended resonant states, driven by a uniform current, are observed to evolve into localized breather states. Experiments were performed on single Josephson plaquettes as well as open-ended Josephson ladders with 10 and 20 cells. We interpret the breather formation as the result of the penetration of vortices into the system.Comment: 5 pages, 5 figure

Effective temperature of active matter

We follow the dynamics of an ensemble of interacting self-propelled motorized particles in contact with an equilibrated thermal bath. We find that the fluctuation-dissipation relation allows for the definition of an effective temperature that is compatible with the results obtained using a tracer particle as a thermometer. The effective temperature takes a value which is higher than the temperature of the bath and it is continuously controlled by the motor intensity

Monte Carlo Simulations of an Extended Feynman-Kikuchi Model

We present Quantum Monte Carlo simulations of a generalization of the Feynman-Kikuchi model which includes the possibility of vacancies and interactions between the particles undergoing exchange. By measuring the winding number (superfluid density) and density structure factor, we determine the phase diagram, and show that it exhibits regions which possess both superfluid and charge ordering.Comment: 10 pages, 15 figure

Confinement Effects in Antiferromagnets

Phase equilibrium in confined Ising antiferromagnets was studied as a function of the coupling (v) and a magnetic field (h) at the surfaces, in the presence of an external field H. The ground state properties were calculated exactly for symmetric boundary conditions and nearest-neighbor interactions, and a full zero-temperature phase diagram in the plane v-h was obtained for films with symmetry-preserving surface orientations. The ground-state analysis was extended to the H-T plane using a cluster-variation free energy. The study of the finite-T properties (as a function of v and h) reveals the close interdependence between the surface and finite-size effects and, together with the ground-state phase diagram, provides an integral picture of the confinement in anisotropic antiferromagnets with surfaces that preserve the symmetry of the order parameter.Comment: 10 pages, 8 figures, Accepted in Phys. Rev.

Majority-Vote Model on a Random Lattice

The stationary critical properties of the isotropic majority vote model on random lattices with quenched connectivity disorder are calculated by using Monte Carlo simulations and finite size analysis. The critical exponents $\gamma$ and $\beta$ are found to be different from those of the Ising and majority vote on the square lattice model and the critical noise parameter is found to be $q_{c}=0.117\pm0.005$.Comment: 4 pages, 6 figure

Effect of long range forces on the interfacial profiles in thin binary polymer films

We study the effect of surface fields on the interfacial properties of a binary polymer melt confined between two parallel walls. Each wall attracts a different component of the blend by a non-retarded van der Waals potential. An interface which runs parallel to the surfaces is stabilized in the center of the film. Using extensive Monte Carlo simulations we study the interfacial properties as a function of the film thickness, the strength of the surface forces and the lateral size over which the profiles across the film are averaged. We find evidence for capillary wave broadening of the apparent interfacial profiles. However, the apparent interfacial width cannot be described quantitatively by a simple logarithmic dependence on the film thickness. The Monte Carlo simulations reveal that the surface fields give rise to an additional reduction of the intrinsic interfacial width and an increase of the effective interfacial tension upon decreasing the film thickness. These modifications of the intrinsic interfacial properties are confirmed by self-consistent field calculations. Taking account of the thickness dependence of the intrinsic interfacial properties and the capillary wave broadening, we can describe our simulation results quantitatively.Comment: to appear in J.Chem.Phy

Ising analogue to compact-star matter

By constructing an Ising analogue of compact-star matter at sub-saturation density we explored the effect of Coulomb frustration on the nuclear liquid-gas phase transition. Our conclusions is twofold. First, the range of temperatures where inhomogeneous phases form expands with increasing Coulomb-field strength. Second, within the approximation of uniform electron distribution, the limiting point upon which the phase-coexistence region ends does not exhibit any critical behaviour. Possible astrophysics consequences and thermodynamical connections are discussed.Comment: 4 pages, 3 figure

Yang-Lee zeroes for an urn model for the separation of sand

We apply the Yang-Lee theory of phase transitions to an urn model of separation of sand. The effective partition function of this nonequilibrium system can be expressed as a polynomial of the size-dependent effective fugacity $z$. Numerical calculations show that in the thermodynamic limit, the zeros of the effective partition function are located on the unit circle in the complex $z$-plane. In the complex plane of the actual control parameter certain roots converge to the transition point of the model. Thus the Yang-Lee theory can be applied to a wider class of nonequilibrium systems than those considered previously.Comment: 4 pages, 3 eps figures include

Work-distribution quantumness and irreversibility when crossing a quantum phase transition in finite time

The thermodynamic behavior of out-of-equilibrium quantum systems in finite-time dynamics encompasses the description of energy fluctuations, which dictates a series of the system's physical properties. In addition, strong interactions in many-body systems strikingly affect the energy-fluctuation statistics along a nonequilibrium dynamics. By driving transient currents to oppose the precursor to the metal-Mott-insulator transition in a diversity of dynamical regimes, we show how increasing many-body interactions dramatically affect the statistics of energy fluctuations and, consequently, the extractable work distribution of finite Hubbard chains. Statistical properties of such distributions as its skewness with its impressive change across the transition can be related to irreversibility and entropy production. Even for slow driving rates, the quasi quantum phase transition hinders equilibration, increasing the process irreversibility, and inducing strong features in the work distribution. In the Mott-insulating phase, the work fluctuation-dissipation balance gets modified with the irreversible entropy production dominating over work fluctuations. Because of this, effects of an interaction-driven quantum phase transition on thermodynamic quantities and irreversibility must be considered in the design of protocols in small-scale devices for application in quantum technology. Eventually, such many-body effects can also be employed in work extraction and refrigeration protocols on a quantum scale