334 research outputs found
A room-temperature alternating current susceptometer - Data analysis, calibration, and test
An AC susceptometer operating in the range of 10 Hz to 100 kHz and at room
temperature is designed, built, calibrated and used to characterize the
magnetic behaviour of coated magnetic nanoparticles. Other weakly magnetic
materials (in amounts of some millilitres) can be analyzed as well. The setup
makes use of a DAQ-based acquisition system in order to determine the amplitude
and the phase of the sample magnetization as a function of the frequency of the
driving magnetic field, which is powered by a digital waveform generator. A
specific acquisition strategy makes the response directly proportional to the
sample susceptibility, taking advantage of the differential nature of the coil
assembly. A calibration method based on conductive samples is developed.Comment: 8 pages, 7 figures, 19 ref
Recent advances in the chemistry of metal carbamates
Following a related review dating back to 2003, the present review discusses in detail the various synthetic, structural and reactivity aspects of metal species containing one or more carbamato ligands, representing a large family of compounds across all the periodic table. A preliminary overview is provided on the reactivity of carbon dioxide with amines, and emphasis is given to recent findings concerning applications in various fields
Larmor frequency dressing by an anharmonic transverse magnetic field
We present a theoretical and experimental study of spin precession in the
presence of both a static and an orthogonal oscillating magnetic field, which
is nonresonant, not harmonically related to the Larmor precession, and of
arbitrary strength. Due to the intrinsic nonlinearity of the system, previous
models that account only for the simple sinusoidal case cannot be applied. We
suggest an alternative approach and develop a model that closely agrees with
experimental data produced by an optical-pumping atomic magnetometer. We
demonstrate that an appropriately designed nonharmonic field makes it possible
to extract a linear response to a weak dc transverse field, despite the scalar
nature of the magnetometer, which normally causes a much weaker, second-order
response.Comment: Published version has some minor changes; 22 pages and 8 picture
A new class of sum rules for products of Bessel functions
In this paper we derive a new class of sum rules for products of the Bessel
functions of first kind. Using standard algebraic manipulations we extend some
of the well known properties of . Some physical applications of the
results are also discussed. A comparison with the Newberger[J. Math. Phys.
\textbf{23} (1982) 1278] sum rules is performed on a typical example.Comment: Published in Journal of Mathematical Physics, 9 pages, no picture
Nonlinear wavelength conversion in photonic crystal fibers with three zero dispersion points
In this theoretical study, we show that a simple endlessly single-mode
photonic crystal fiber can be designed to yield, not just two, but three
zero-dispersion wavelengths. The presence of a third dispersion zero creates a
rich phase-matching topology, enabling enhanced control over the spectral
locations of the four-wave-mixing and resonant-radiation bands emitted by
solitons and short pulses. The greatly enhanced flexibility in the positioning
of these bands has applications in wavelength conversion, supercontinuum
generation and pair-photon sources for quantum optics
Multiple hydrodynamical shocks induced by Raman effect in photonic crystal fibres
We theoretically predict the occurrence of multiple hydrodynamical-like shock
phenomena in the propagation of ultrashort intense pulses in a suitably
engineered photonic crystal fiber. The shocks are due to the Raman effect,
which acts as a nonlocal term favoring their generation in the focusing regime.
It is shown that the problem is mapped to shock formation in the presence of a
slope and a gravity-like potential. The signature of multiple shocks in XFROG
signals is unveiled
The cytotoxic activity of diiron bis-cyclopentadienyl complexes with bridging c3-ligands
Diiron bis-cyclopentadienyl bis-carbonyl cationic complexes with a bridging vinylim-inium ligand, [Fe2Cp2 (CO)(µ-CO){µ-η1:η3-C3 (R′)C2HC1NMe(R′′)}]CF3SO3 (R = Xyl = 2,6-C6H3Me2, R′ = Ph, R′′ = H, 2a; R = Xyl, R′ = R′′ = Me, 2b; R = R′ = Me, R′′ = H, 2c; R = Me, R′ = 2-naphthyl, R′′ = H, 2d; R = Me, R′ = R′′ = Ph, 2e), are easily available from commercial chemicals, robust in aqueous media and exert a variable in vitro cytotoxicity against cancer cell lines depending on the nature of the substituents on the vinyliminium ligand. The anticancer activity is, at least in part, associated to fragmentation reactions, leading to iron oxidation and active neutral and well-defined monoiron species. We report an innovative synthetic procedure for the preparation of 2a,c,d, and a facile method to access the monoiron derivative of 2a, i.e., [FeCp(CO){C1 (NMeXyl)C2HC3 (Ph)C(O)}] (3a). According to IC50 analyses at different times of incubation of the complexes, 3a is significantly faster in inhibiting cell viability compared to its diiron precursor 2a. The neutral complexes [Fe2Cp2 (CO)(µ-CO){µ-k1N:k1C:k1C-C3 (R′)C2 (Se)C1 (NMe2)C4 (CO2Y)C5 (CO2Y)}] (R′ = Y = Me, 4a; R′ = Pr, Y =tBu, 4b; R′ = Y = Et, 4c) are obtained via the two-step modification of the vinyliminium moiety and comprise a bridging selenophene-decorated alkylidene ligand. The antiproliferative activity exhibited by 4a-c is moderate but comparable on the ovarian cancer cell line A2780 and the corresponding cisplatin resistant cell line, A2780cisR. Complexes 4a-c in aqueous solutions undergo progressive release of the alkylidene ligand as a functionalized selenophene, this process being slower in cell culture medium. Since the released selenophenes SeC1 {C(O)R′ }C2 (NMe2)C3 (CO2Y)C4 (CO2Y) (R′ = Y = Me, 5a; R′ = Pr, Y =tBu, 5b) are substantially not cytotoxic, it is presumable that the activity of 4a-c is largely ascribable to the {Fe2Cp2 (CO)2 } scaffold
Anticancer and antibacterial potential of robust Ruthenium(II) arene complexes regulated by choice of α-diimine and halide ligands
Several complexes of general formula [Ru(halide)(η6-p-cymene)(α-diimine)]+, in the form of nitrate, triflate and hexafluorophosphate salts, including a newly synthesized iodide compound, were investigated as potential anticancer drugs and bactericides. NMR and UV–Vis studies evidenced remarkable stability of the complexes in water and cell culture medium. In general, the complexes displayed strong cytotoxicity against A2780 and A549 cancer cell lines with IC50 values in the low micromolar range, and one complex (RUCYN) emerged as the most promising one, with a significant selectivity compared to the non-cancerous HEK293 cell line. A variable affinity of the complexes for BSA and DNA binding was ascertained by spectrophotometry/fluorimetry, circular dichroism, electrophoresis and viscometry. The performance of RUCYN appears associated to enhanced cell internalization, favored by two cyclohexyl substituents, rather than to specific interaction with the evaluated biomolecules. The chloride/iodide replacement, in one case, led to increased cellular uptake and cytotoxicity at the expense of selectivity, and tuned DNA binding towards intercalation. Complexes with iodide or a valproate bioactive fragment exhibited the best antimicrobial profiles
Understanding the dynamics of photoionization-induced solitons in gas-filled hollow-core photonic crystal fibers
We present in detail our developed model [Saleh et al., Phys. Rev. Lett. 107]
that governs pulse propagation in hollow-core photonic crystal fibers filled by
an ionizing gas. By using perturbative methods, we find that the
photoionization process induces the opposite phenomenon of the well-known Raman
self-frequency red-shift of solitons in solid-core glass fibers, as was
recently experimentally demonstrated [Hoelzer et al., Phys. Rev. Lett. 107].
This process is only limited by ionization losses, and leads to a constant
acceleration of solitons in the time domain with a continuous blue-shift in the
frequency domain. By applying the Gagnon-B\'{e}langer gauge transformation,
multi-peak `inverted gravity-like' solitary waves are predicted. We also
demonstrate that the pulse dynamics shows the ejection of solitons during
propagation in such fibers, analogous to what happens in conventional
solid-core fibers. Moreover, unconventional long-range non-local interactions
between temporally distant solitons, unique of gas plasma systems, are
predicted and studied. Finally, the effects of higher-order dispersion
coefficients and the shock operator on the pulse dynamics are investigated,
showing that the resonant radiation in the UV [Joly et al., Phys. Rev. Lett.
106] can be improved via plasma formation.Comment: 9 pages, 10 figure
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