High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb 2 @C 79 N with a Single-Electron Terbium–Terbium Bond

The azafullerene Tb 2 @C 79 N is found to be a single-molecule magnet with a high 100-s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy-axis single-ion magnetic anisotropy are strongly coupled by the unpaired spin of the single-electron Tb−Tb bond. Relaxation of magnetization in Tb 2 @C 79 N below 15 K proceeds via quantum tunneling of magnetization with the characteristic time τ QTM =16 462±1230 s. At higher temperature, relaxation follows the Orbach mechanism with a barrier of 757±4 K, corresponding to the excited states, in which one of the Tb spins is flipped. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA

Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al

Mn2O3 has been selected to realize nanothermite membrane for the first time in the literature. Mn2O3/Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn2O3 skeleton. The energy release is significantly enhanced owing to the unusual 3DOM structure, which ensures Al and Mn2O3 to integrate compactly in nanoscale and greatly increase effective contact area. The morphology and DSC curve of the nanothermite membrane have been investigated at various aluminizing times. At the optimized aluminizing time of 30 min, energy release reaches a maximum of 2.09 kJ∙g−1, where the Al layer thickness plays a decisive role in the total energy release. This method possesses advantages of high compatibility with MEMS and can be applied to other nanothermite systems easily, which will make great contribution to little-known nanothermite research

ENTERPRISE OPERATION PLANNING IN THE CONDITIONS OF RISK AND UNCERTAINTY IN THE EXTERNAL AND INTERNAL ENVIRONMENT

Optimization of the enterprise activity planning taking into account the risk and uncertainty of the external and internal environment is a complex scientific and methodological problem. Its solution is important for the planning practice. Therefore, the relevance of this research topic is beyond doubt. Planning is based on the use of a multilevel system of models. At the top level, the achievement of key strategic indicators is ensured by the development and implementation of innovations, mainly related to the planning of the release of new high-tech products. However, it is at this level that the risks and uncertainties have the greatest impact on the planning processes for the development, production and marketing of new products. In the scientific literature it is proposed to use the stochastic graphs with returns for this purpose. This idea is also supported in this work. However, the implementation of such an idea requires additional methodological developments and quantitative calculations. The coordination of strategic decisions with tactical plans is based on the idea of eliminating the economic and other risks associated with the economic activity of the enterprise in tactical planning, by creating the stochastic reserves based on the implementation of additional innovations that ensure the receipt of above-target sales volumes, profits and other indicators of the strategic plan. The organization of operational management of production is represented by an iterative, sliding process (reducing risks in production), which is realized taking into account the limitations of tactical control

Optical spectroscopyof matrix-isolated halogenated fullerenes

info:eu-repo/semantics/publishe