Hopping of the Photohole during Photoemission from Physisorbed N₂: The Influence of Band Formation on Vibrational Excitation

N2 physisorbed on top of a Xe spacer layer on Ag(111) and Pd(111) has been studied by angle-resolved and polarization-dependent UV photoemission. The N2 1πu valence level exhibits a vibrational fine structure due to two multiplets corresponding to the ionic (N+2) and neutral (N2) states. The neutral-state multiplet is explained through hopping of the photohole during photoemission. We show that its intensity is stronger for emission from the in-plane component of 1πu, than for the perpendicular one. This is due to a larger lateral overlap in the former case, as concluded by the observed band formation

A mixed quantitative approach to evaluate rockfall risk and the maximum allowable traffic on road infrastructure

Rockfall events constitute one of the most dangerous phenomena in mountainous areas, which can affect transportation routes. In a risk mitigation perspective, the quantification of the risk for pedestrians and vehicles represents a crucial aspect for authorities. A method tailored to these elements at risk is herein presented. The proposed method is based on a mixed formulation of the Quantitative Risk Assessment and the Event Tree Analysis approaches. According to these procedures, an accurate evaluation of the annual probability of adverse outcomes can be computed considering all the scenarios which can lead to a fatality or to an injury. Vice versa, the method lets to evaluate the allowable traffic condition, given an acceptable threshold for the risk. Furthermore, it serves to quantify the risk reduction in case of installed passive mitigation measures and, thus, to plan the priority of intervention works. An application on a study case in the Italian Alps illustrates the potentialities of the methodology

Wrist Ultrasound Analysis Of Patients With Early Rheumatoid Arthritis.

In the present study, we evaluated 42 wrists using the semi-quantitative scales power Doppler ultrasound (PDUS) and gray scale ultrasound (GSUS) with scores ranging from 0 to 3 and correlated the results with clinical, laboratory and radiographic data. Twenty-one patients (17 women and 4 men) with rheumatoid arthritis according to criteria of the American College of Rheumatology were enrolled in the study from September 2008 to July 2009 at Universidade Estadual de Campinas (UNICAMP). The average disease duration was 14 months. The patients were 66.6% Caucasians and 33.3% non-Caucasians, with a mean age of 42 and 41 years, respectively. A dorsal longitudinal scan was performed by ultrasound on the radiocarpal and midcarpal joints using GE LOGIQ XP-linear ultrasound and a high frequency (8-10 MHz) transducer. All patients were X-rayed, and the Larsen score was determined for the joints, with grades ranging from 0 to V. This study showed significant correlations between clinical, sonographic and laboratory data: GSUS and swollen right wrist (r = 0.546), GSUS of right wrist and swelling of left wrist (r = 0.511), PDUS of right wrist and pain in left wrist (r = 0.436), PDUS of right wrist and C-reactive protein (r = 0.466). Ultrasound can be considered a useful tool in the diagnosis of synovitis in early rheumatoid arthritis mainly when the anti-cyclic citrullinated peptide and rheumatoid factor are negative, and can lead to an early change in the therapeutic decision.4411-

Myocardial infarction and arterial thrombosis in severe (homozygous) FXII deficiency: no apparent causative relation.

Twenty-one patients (12 female and 9 male) with severe (homozygous) factor XII (FXII) deficiency and 58 (32 female and 26 male) with heterozygous FXII deficiency were observed for an average 16.2 years. No patient with homozygous FXII deficiency experienced myocardial infarction or any other arterial thrombosis. The same was true for heterozygotes. The cases of FXII deficiency and arterial thrombosis reported in the literature were evaluated. In every instance, associated risk factors were present that could justify the arterial thrombosis. Dyslipidemia, hypertension, smoking, and diabetes mellitus were the most frequent findings. The examination of the few papers that dealt with the prevalence of arterial thrombosis in patients with severe FXII deficiency showed that only 1 patient of 61 experienced myocardial infarction. In conclusion, it seems that the role of FXII deficiency in the pathogenesis of arterial thrombosis is minor

Dissociation of CH Species on Ni(111):A HREELS Study

The isothermal dissociation rate of CCH and CH on Ni(111) was measured by following, with HREEL spectroscopy, the intensity of the CH stretching peak as a function of time. By repeating the experiment at several different temperatures we obtained an activation energy of 8±3 kcal/mol for the CCH dissociation reaction and of 12±3 kcal/mol for the CH dissociation reaction. Pre-exponential factors were found to be 10^3±1 s-1 in both cases. Independent thermal desorption spectra show a feature at 470 K and a tail extending up to 600 K which can be assigned to the CCH dissociation and the CH dissociation respectively. The two experiments are quantitatively consistent

Diffusion weighted imaging in cystic fibrosis disease: beyond morphological imaging

To explore the feasibility of diffusion-weighted imaging (DWI) to assess inflammatory lung changes in patients with Cystic Fibrosis (CF) METHODS: CF patients referred for their annual check-up had spirometry, chest-CT and MRI on the same day. MRI was performed in a 1.5 T scanner with BLADE and EPI-DWI sequences (b = 0-600 s/mm(2)). End-inspiratory and end-expiratory scans were acquired in multi-row scanners. DWI was scored with an established semi-quantitative scoring system. DWI score was correlated to CT sub-scores for bronchiectasis (CF-CTBE), mucus (CF-CTmucus), total score (CF-CTtotal-score), FEV1, and BMI. T-test was used to assess differences between patients with and without DWI-hotspots

Emerging contaminants in drinking water treatment plants: how ozonation affects activated carbon adsorption

Contaminants of Emerging Concern (CECs) in drinking water are a growing concern for potential negative effects on human health. This study combines full-scale monitoring campaigns in a drinking water treatment plant (DWTP) and lab-scale experiments using real water matrices without CECs spike. Monitoring campaigns were performed over one year and over 116 monitored CECs, a maximum of 22 compounds have been detected at the DWTP inlet. The analyses show that ozonation and adsorption on activated carbon (AC) have the main impact in reducing a wide variety of CECs, with performances influenced by their characteristics. At lab-scale adsorption isotherms were performed on 4 different water matrices, before and after ozonation, the evaluate the effect of ozonation on the adsorption process. Ozonation is less effective than AC adsorption in CECs removal, but the combination of the two processes allows to reduce the variability of the removal efficiencies, providing a highest performance for the removal of all the investigated CECs

Limb reconstruction with knee mega-prosthesis in patients with distal femur primary tumours: gait analysis and alignment evaluation

Introduction: The aim of this study was the functional evaluation and lower limb alignment assessment of patients with a modular knee prosthesis after distal femur resection for primary bone tumour. Materials and methods: 15 patients affected by distal femur tumor and treated with a megaprosthesis implant (6 females and 9 males, mean age: 41 years, range: 15-74 years) and 15 controls were recruited for the study. For each subject the function evaluation included an instrumented gait analysis, while only patients underwent a teleradiography and a latero-lateral X-ray projection of the knee. Results: The duration of the stance phase of gait was shortened in the prosthetic limb with respect to the contralateral limb (57.5±3.6 % gait cycle vs. 60.9±4.8 % gait cycle, P = 0.01), with a correspondent increase of the swing phase. The prosthetic limb also showed an altered knee joint kinematic curve during gait, with a flexion deficit at load response with respect to the contralateral limb (4.5±3.6° vs. 13.4±5.0°, P = 0.000003). Abnormal timing in the muscle activation intervals were observed for tibialis anterior, gastrocnemius lateralis and rectus femoris of the prosthetic limb. The prosthetic limb was found to be misaligned with respect to the contralateral limb, both for the femorotibial (P<0.05) and the ankle joints (P<0.05). Conclusions: Gait analysis performed widely in reference centres could lead to a change in the design of megaprostheses to improve the function and prevent degenerative changes in not involved joint. A multicentric expertise is mandator