20 research outputs found
Basic Amino Acid Mutations in the Nuclear Localization Signal of Hibiscus Chlorotic Ringspot Virus p23 Inhibit Virus Long Distance Movement
10.1371/journal.pone.0074000PLoS ONE89-POLN
FIRST RESULTS OF AN EXPERIMENT ON ADVANCED COLLIMATOR MATERIALS AT CERN HIRADMAT FACILITY
A comprehensive, first-of-its-kind experiment (HRMT-14) has been recently carried out at CERN HiRadMat facility on six different materials of interest for Beam Intercepting Devices (collimators, targets, dumps). Both traditional materials (Mo, W and Cu alloys) as well as advanced metal/diamond and metal/graphite composites were tested under extreme conditions as to pressure, density and temperature, leading to the development of highly dynamic phenomena as shock-waves, spallation, explosions. Experimental data were acquired, mostly in real time, relying on extensive integrated instrumentation (strain gauges, temperature and vacuum sensors) and on remote acquisition devices (laser Doppler vibrometer and high-speed camera). The experiment was a success under all points of view in spite of the technological challenges and harsh environment. First measurements are in good agreement with results of complex simulations, confirming the effectiveness of the acquisition system and the reliability of advanced numerical methods when material constitutive models are completely available. Valuable information has been collected as to thermalshock robustness of tested materials
Long-term household waste management: Insights from the policymaking process
International audienc
Scaling of Trigate Junctionless Nanowire MOSFET With Gate Length Down to 13 nm
In this letter, we report the performance of high-kappa/metal gate nanowire (NW) transistors without junctions fabricated with a channel thickness of 9 nm and sub-15-nm gate length and NW width. Near-ideal subthreshold slope (SS) and extremely low leakage currents are demonstrated for ultrascaled gate lengths with a high on-off ratio (I-on/I-off) > 10(6). For the first time, an SS lower than 70 mV/dec is achieved at L-G = 13 nm for n-type and p-type transistors, highlighting excellent electrostatic integrity of trigate junctionless NW MOSFETs
Investigation on AlN epitaxial growth and related etching phenomenon at high temperature using high temperature chemical vapor deposition process.
International audienceThick MN layers were grown by high temperature chemical vapor deposition (HTCVD) on 8 degrees off-axis (0 0 0 1) 4H-SiC, on-axis (0 0 0 1) 6H-SiC and on-axis (0 0 0 1) AlN templates between 900 degrees C and 1600 degrees C. The experimental set-up consists of a vertical cold-wall reactor working at low pressure in which the reactions take place on a graphite susceptor heated by induction. The reactants used are ammonia (NH(3)) and aluminum chlorides (AlCl(x)) species in situ formed via Cl(2) reaction with high purity aluminum wire. As-grown AlN layers have been characterized by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), Transmission Electron Microscopy (TEM), Optical Profilometry, Atomic Force Microscopy (AFM) and Raman spectroscopy. In this study, the influence of the deposition temperature and the N/Al ratio in the gas phase is studied in order to stabilize epitaxial growth. The epitaxy on AlN template is favored using a low N/Al ratio in the gas phase and a high temperature above 1400 degrees C. The crystalline quality of epitaxial AlN layers is found to increase with increasing deposition temperature from 1400 to 1500 degrees C. Growth rates up to 14 mu m h(-1) have been reached for epitaxial AlN layers. An important etching phenomenon is also observed at high temperature: apparition of pin holes certainly around threading dislocations at 1400-1500 degrees C and substrate etching at 1600 degrees C. (C) 2011 Elsevier B.V. All rights reserved
Undoped TiO2 and nitrogen-doped TiO2 thin films deposited by atomic layer deposition on planar and architectured surfaces for photovoltaic applications
International audienceUndoped and nitrogen doped TiO2 thin films were deposited by atomic layer deposition on planar substrates. Deposition on 3D-architecture substrates made of metallic foams was also investigated to propose architectured photovoltaic stack fabrication. All the films were deposited at 265 degrees C and nitrogen incorporation was achieved by using titanium isopropoxide, NH3 and/or N2O as precursors. The maximum nitrogen incorporation level obtained in this study was 2.9 at. %, resulting in films exhibiting a resistivity of 115 Omega cm (+/-10 Omega cm) combined with an average total transmittance of 60% in the 400-1000 nm wavelength range. Eventually, TiO2 thin films were deposited on the 3D metallic foam template
Nanostructured TiO2 anatase-rutile-carbon solid coating with visible light antimicrobial activity
TiO2 photocatalyst is of interest for antimicrobial coatings on hospital touch-surfaces. Recent research
has focused on visible spectrum enhancement of photocatalytic activity. Here, we report TiO2 with a
high degree of nanostructure, deposited on stainless steel as a solid layer more than 10 μm thick by
pulsed-pressure-MOCVD. The TiO2 coating exhibits a rarely-reported microstructure comprising anatase
and rutile in a composite with amorphous carbon. Columnar anatase single crystals are segmented into
15–20 nm thick plates, resulting in a mille-feuilles nanostructure. Polycrystalline rutile columns exhibit
dendrite generation resembling pine tree strobili. We propose that high growth rate and co-deposition
of carbon contribute to formation of the unique nanostructures. High vapor flux produces step-edge
instabilities in the TiO2, and solid carbon preferentially co-deposits on certain high energy facets. The
equivalent effective surface area of the nanostructured coating is estimated to be 100 times higher
than standard TiO2 coatings and powders. The coatings prepared on stainless steel showed greater
than 3-log reduction in viable E coli after 4 hours visible light exposure. The pp-MOCVD approach could
represent an up-scalable manufacturing route for supported catalysts of functional nanostructured
materials without having to make nanoparticles
Developments of TaN ALD Process for 3D Conformal Coatings
International audienceThere is a growing interest in producing tantalum nitride (TaN) thin films for various industrial applications. For example, in microelectronics, the development of IC technology is driven by the need to increase both performance and functionality while reducing power and cost. This goal can be achieved by several solutions among which the introduction of architecture enhancements such as 3D integration. The most challenging step is the deposition of a conformal, continuous, and adherent diffusion barrier. In this work, atomic layer deposition (ALD) of TaN thin films is explored using the combination between the thermodynamical behavior of the precursor, mass transfer in the reactor, and the operating conditions. TaN thin film deposition on very complex shape substrates, such as nanodots, TSV, silicon nanowires, and carbon nanotubes, has been evaluated