6 research outputs found
Ammonia Mono Hydrate IV: An Attempted Structure Solution
The mixed homonuclear and heteronuclear hydrogen bonds in ammonia hydrates have been of interest for several decades. In this manuscript, a neutron powder diffraction study is presented to investigate the structure of ammonia monohydrate IV at 170 K at an elevated pressure of 3–5 GPa. The most plausible structure that accounts for all features in the experimental pattern was found in the P21/c space group and has the lattice parameters a=5.487(3) Å, b=19.068(4) Å, c=5.989(3) Å, and β=99.537(16) deg. While the data quality limits discussion to a proton-ordered structure, the structure presented here sheds light on an important part of the ammonia–water phase diagram
Neutron-diffraction of hydrogen-rich molecules under high pressure
A proton and an electron form the lightest element of the periodic table:
Hydrogen. Despite the simplicity of this element and an ongoing research interest,
surprisingly little is known about its solid phases and structures of hydrogen-rich
compounds such as water, ammonia or methane. In the particular, high pressure
phases of these compounds are poorly understood.
The reason for this is of a two-fold nature; first and foremost, small, hydrogen-rich molecules have very complex phase diagrams - partially due to the quantum
nature of hydrogen - and form a vast variety of crystal structures. And secondly,
the only direct way of measuring the hydrogen positions in these crystal structures
is neutron-diffraction. While very powerful in structure determination, this
technique requires large sample volumes and, hence, the pressure range has been
limited to below 40 GPa; until recently, neutron diffraction had to rely on large-volume pressure cell such as the Paris-Edinburgh-Press.
The overall aim of this body of work was to overcome current pressure-limitations
and the concomitant limitations in data quality using single-crystals in diamond
anvil cells for neutron diffraction. This attempt has been successful and the data-reduction and correction procedure reported in this work are now being used at
the Snap beamline at Sns (Oak Ridge National Laboratory).
The original aim for the second half of this thesis was to use single-crystal neutron-diffraction to measure single-crystals of hydrogen (deuterium) and water. Due to
the ongoing pandemic caused by Covid-19 and the restrictions to travel to Sns,
this was not possible. Hence, the second half of this works tries to fill gaps in the
knowledge of the high-pressure behaviour of water-gas compounds using existing
techniques. In particular, studies on the water-nitrogen, water-ammonia and the
water-ammonia-methane systems will be presented here
Supplemental Material
This file contains additional information on X-ray detector calibration and intensity corrections made to the Varex detector