The impedance of thin dense oxide cathodes

The impedance is derived for a dense layer electrode of a mixed conducting oxide, assuming that the electronic resistance may be ignored. The influence of layer thickness, oxygen diffusion and surface exchange rate on the ‘General Finite Length Diffusion’ expression is evaluated. The thickness dependence is tested for a series of thin, dense layer electrodes of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) deposited on a Ce0.9Gd0.1O1.95 electrolyte by pulsed laser deposition (PLD). A minimum thickness is required to avoid the influence of contact points of the contacting Pt-gauze and sheet resistance, which is about 1 μm for the studied LSCF electrodes. LEISS surface analysis indicates that PLD deposition process easily leads to a significant Cr contamination of the LSCF surface. Electrochemical impedance spectroscopy analysis indicates that the influence on the exchange rate of this Cr-contamination is still negligible

La(Ni,Fe)O3 Stability in the Presence of Chromia—A Solid-State Reactivity Study

The perovskite $La(Ni_{0.6}Fe_{0.4})O_3$ (LNF) is a candidate material for the electrochemically active cathode layer, the cathode current collecting layer, and/or the interconnect protective coating in intermediate temperature solid oxide fuel cells (IT-SOFCs) operated at . Since these operating temperatures enable the use of relatively cheap interconnect materials such as chromia-forming ferritic stainless steel, investigation of the chemical stability of LNF in the presence of chromium species is of importance. This study demonstrates that LNF is chemically unstable at when it is in direct contact with $Cr_2O_3$. It has been observed that Cr enters the perovskite phase, replacing first Ni and then Fe, already after 200h. At 600°C, however, only minor reaction products were detected after 1000h exposure to $Cr_2O_3$. Although this is a promising result, long-term testing under fuel cell operating conditions at 600°C is needed to prove that LNF is a viable IT-SOFC material

Impact of Cr-poisoning on the conductivity of different LaNi0.6Fe0.4O3 cathode microstructures

The microstructure of porous LaNi0.6Fe0.4O3 (LNF) layers has a significant influence on the degree of the Cr-poisoning impact. The increase in the in-plane resistance and Cr accumulation in poisoned LNF-layers has been correlated with microstructural features. The Cr-poisoning impact is more severe in the case of a microstructure characterized by finer particles, higher porosity and larger particle surface area

Impact of Cr-poisoning on the conductivity of LaNi0.6Fe0.4O3

This study demonstrates the significant impact of Cr on the electronic conductivity of a LaNi0.6Fe0.4O3 (LNF) porous cathode layer at 800 °C. Vapor transport of Cr-species, originating from a porous metallic foam, and subsequent reaction with LNF, results in a decrease of the electronic conductivity of the LNF-layer. Cr has been detected throughout the entire cross-section of a 16 μm thick LNF layer, while Ni, besides its compositional distribution in the LNF layer, has also been found in enriched spots forming Ni-rich metal oxide crystals. Transmission electron microscopy revealed that Cr is gradually incorporated into the LNF-grains, while Ni is proportionally expelled. Electron diffraction performed in the center of a sliced grain showed the initial rhombohedral crystal structure of LNF, whereas diffraction performed close to the edge of the grain revealed the orthorhombic perovskite crystal structure, indicating a Cr-enriched perovskite phase. Progressive Cr deposition and penetration into the LNF grains and necks explains the electronic conductivity deterioration. The impact of Cr-poisoning on the electronic conductivity of the LNF porous layer is considerably smaller at 600 °C than at 800 °C

Bethe-Salpeter Approach for the P33P_{33} Elastic Pion-Nucleon Scattering in Heavy Baryon Chiral Perturbation Theory

Heavy Baryon Chiral Perturbation Theory (HBChPT) to leading order provides a kernel to solve the Bethe-Salpeter equation for the $P_{33}$ ($\Delta(1232)$-channel) $\pi-N$ system, in the infinite nucleon mass limit. Crossed Born terms include, when iterated within the Bethe-Salpeter equation, both {\it all} one- and {\it some} two-pion intermediate states, hence preserving elastic unitarity below the two-pion production threshold. This suggests searching for a solution with the help of dispersion relations and suitable subtraction constants, when all in-elasticities are explicitly neglected. The solution allows for a successful description of the experimental phase shift from threshold up to $\sqrt{s}=1500$ MeV in terms of four subtraction constants. Next-to-leading order HBChPT calculations are also used to estimate the unknown subtraction constants which appear in the solution. Large discrepancies are encountered which can be traced to the slow convergence rate of HBChPT.Comment: 11 pages, 3 figure

Time transfer and frequency shift to the order 1/c^4 in the field of an axisymmetric rotating body

Within the weak-field, post-Newtonian approximation of the metric theories of gravity, we determine the one-way time transfer up to the order 1/c^4, the unperturbed term being of order 1/c, and the frequency shift up to the order 1/c^4. We adapt the method of the world-function developed by Synge to the Nordtvedt-Will PPN formalism. We get an integral expression for the world-function up to the order 1/c^3 and we apply this result to the field of an isolated, axisymmetric rotating body. We give a new procedure enabling to calculate the influence of the mass and spin multipole moments of the body on the time transfer and the frequency shift up to the order 1/c^4. We obtain explicit formulas for the contributions of the mass, of the quadrupole moment and of the intrinsic angular momentum. In the case where the only PPN parameters different from zero are beta and gamma, we deduce from these results the complete expression of the frequency shift up to the order 1/c^4. We briefly discuss the influence of the quadrupole moment and of the rotation of the Earth on the frequency shifts in the ACES mission.Comment: 17 pages, no figure. Version 2. Abstract and Section II revised. To appear in Physical Review

Muon Capture on the Proton and Deuteron

By measuring the lifetime of the negative muon in pure protium (hydrogen-1), the MuCap experiment determines the rate of muon capture on the proton, from which the proton's pseudoscalar coupling g_p may be inferred. A precision of 15% for g_p has been published; this is a step along the way to a goal of 7%. This coupling can be calculated precisely from heavy baryon chiral perturbation theory and therefore permits a test of QCD's chiral symmetry. Meanwhile, the MuSun experiment is in its final design stage; it will measure the rate of muon capture on the deuteron using a similar technique. This process can be related through pionless effective field theory and chiral perturbation theory to other two-nucleon reactions of astrophysical interest, including proton-proton fusion and deuteron breakup.Comment: Submitted to the proceedings of the 2007 Advanced Studies Institute on Symmetries and Spin (SPIN-Praha-2007

The continuum limit of quark number susceptibilities

We report the continuum limit of quark number susceptibilities in quenched QCD. Deviations from ideal gas behaviour at temperature T increase as the lattice spacing is decreased from T/4 to T/6, but a further decrease seems to have very little effect. The measured susceptibilities are 20% lower than the ideal gas values, and also 10% below the hard thermal loop (HTL) results. The off-diagonal susceptibility is several orders of magnitude smaller than the HTL results. We verify a strong correlation between the lowest screening mass and the susceptibility. We also show that the quark number susceptibilities give a reasonable account of the Wroblewski parameter, which measures the strangeness yield in a heavy-ion collision.Comment: 8 pages, 5 figure