Synthesis of benzimidazole-cyclohexanone derivatives

This work reports the synthesis and characterization of new benzimidazole-cyclohexanone derivatives 3a-d, 4a-d and 5a-d under different reaction conditions. The intermediates and final compounds were purified and their  chemical structures were elucidated using 1H-NMR, 13C-NMR and mass spectral data.Keywords: Benzimidazole, Cyclohexanone, NMR, Reaction intermediate

Different linearization control techniques for a quadrotor system

International audienc

Characterization of Moroccan coal waste: valorization in the elaboration of the Portland clinker

Coal exploited in the mine of Jerada (northeast of Morocco) was accompanied by large quantities of waste. The purpose of this work is to characterize this waste with the aim of its use as a material for civil engineering. Mineral and chemical investigations on this waste in the raw state, and at different temperature of heat treatments, were carried out by various methods: X-ray fluorescence, X-ray diffraction, infrared spectroscopy. These analyzes showed that the studied waste, contain essentially a mineral part formed by silica and various clays, as well as coal’s residues. The thermal investigation of waste, by differential scanning calorimetry (DSC), revealed an exothermic phenomenon attributed to the combustion of coal residues. Other phenomena were noted on the thermograms due to the mineral part transformations. In this analysis a comparison was also made with pure coal. These characteristics of coal waste encourage studying its development in reducing energy consumption in the Portland cement manufacture. Mixtures of waste with limestone or with raw cement materials were studied, and the resulting products were analyzed by different methods

Synthesis of benzimidazole-cyclohexanone derivatives

International audienc

Impact of Deficit Irrigation on Yield and Fruit Quality of Orange Trees (Citrus Sinensis, L. Osbeck, CV. Meski Maltaise) in Southern Tunisia

An experiment on deficit irrigation of orange trees (Citrus sinensis, L. Osbeck, cv. Meski Maltaise) with saline water (1.5 g l‐1) was conducted in the arid region of Medenine, Tunisia. Four irrigation treatments were applied: full irrigation (FI), irrigated at 100% of the crop evapotranspiration; deficit irrigation (DI75) and (DI50), which received respectively 25 and 50% less water than FI; and the farmer's method (FM). Soil water content and salinity were monitored during the orange active period. Yield and fruit quality were measured at harvest and used to analyse water productivity (WP) and net income. Results show a decrease in soil salinity between the spring and winter seasons with maximum values observed for the DI50 treatment. Maximum yield levels were obtained under the FI treatment (26.6 t ha−1). Applying continuous deficit irrigation resulted in 24 and 45% yield reduction respectively for DI75 and DI50, compared to FI. Fruit‐quality parameters showed significant differences, with higher levels of total soluble solids for DI50 and better fruit weight for FI and FM. For total water supplies between 415 and 786 mm, WP was in the range 2.9–3.6 kg m‐3, with the highest values observed for the DI50 treatment and the lowest for FM. The soil water balance‐based irrigation method (FI) generated the greatest net income and the lowest soil salinization. Reduction in water supply produced an equivalent reduction in yield but a much stronger decrease in the economic return: using the DI75 strategy resulted in 25% water saving, 24% reduction in yield and 40% reduction in net income

(E)-1,1-Diphenyl-2-(thiophen-2-ylmethylidene)hydrazine

The asymmetric unit of the title compound, C17H14N2S, consists of two crystallographically independent molecules with similar conformations. The dihedral angles between the phenyl rings are 89.32 (5) and 82.80 (5)° in the two molecules. In the crystal, molecules are linked by C—H...π interactions, forming a three-dimensional network