Towards the Design of Power Switches Utilizing HTS Material

Conventional superconducting switches for power applications, which operate at liquid helium temperature, generally utilize Nb-Ti superconductor in a cupro-nickel matrix. For superconducting circuits based on High Temperature Superconductors (HTS) that work at higher temperatures, the associated superconducting switches must also be based on HTS. This paper addresses the issues concerning the requirements and the appropriate design of HTS switches, including approaches to fast triggering

“Mainstreaming” Interprofessional Education within Hospital Settings: Findings from a Multiple Case Study

AbstractBackground: Interest in interprofessional education (IPE) to promote effective interprofessional collaboration (IPC) has gained momentum across healthcare, professional education, and government sectors. In general, the IPE literature tends to report single-site studies. This article presents a rare study that reports a largescale multi-site IPE initiative. It draws upon a newly developed notion of mainstreaming—introduced to the literature by Barr and Ross—that helps illuminate the implementation issues related to an IPE initiative.Methods and Findings: A realistic evaluation framework was employed to explore the overarching impact of this large initiative (involving 6 IPE programs within 13 hospitals) on the teaching hospital network in which it was implemented. Qualitative methods were used to gather a total of 142 interviews with program leaders, facilitators, and learners. Findings provide insight into the mainstreaming of IPE in relation to educational, professional, and organizational outcomes. Educational outcomes detail how inter-organizational partnerships developed among hospitals with the sharing of ideas and resources for implementing IPE and IPC. Professional outcomes describe learners’ experiences of increased awareness of the policy agenda and the meanings and value they attach to IPE and IPC. Organizational outcomes demonstrate that interprofessional champions with senior management support and protected time were core mainstreaming elements, and yet participants outlined a range of concerns and desires for the sustainability of this IPE initiative.Conclusions: This article provided empirical insight into the perceptions, ideas, and experiences of IPE from a wide range of program developers, facilitators, and attendees. Barr and Ross’ concept of mainstreaming and the use of a realistic evaluation framework provide a useful way to illuminate the processes and outcomes of implementing a large multi-institutional IPE initiative

Symmetry-breaking in the endofullerene H2O@C60 revealed in the quantum dynamics of ortho and para-water: a neutron scattering investigation

Inelastic neutron scattering (INS) has been employed to investigate the quantum dynamics of water molecules permanently entrapped inside the cages of C60 fullerene molecules. This study of the supramolecular complex, H2O@C60, provides the unique opportunity to study isolated water molecules in a highly symmetric environment. Free from strong interactions, the water molecule has a high degree of rotational freedom enabling its nuclear spin isomers, ortho-H2O and para-H2O to be separately identified and studied. The INS technique mediates transitions between the ortho and para spin isomers and using three INS spectrometers, the rotational levels of H2O have been investigated, correlating well with the known levels in gaseous water. The slow process of nuclear spin conversion between ortho-H2O and para-H2O is revealed in the time dependence of the INS peak intensities over periods of many hours. Of particular interest to this study is the observed splitting of the ground state of ortho-H2O, raising the three-fold degeneracy into two states with degeneracy 2 and 1 respectively. This is attributed to a symmetry-breaking interaction of the water environment

Synthesis and properties of open fullerenes encapsulating ammonia and methane

We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH₄ and NH₃ are encapsulated, respectively. The ¹H NMR resonance of endohedral NH₃ is broadened by scalar coupling to the quadrupolar ¹⁴N nucleus, which relaxes rapidly. This broadening is absent for small satellite peaks, which are attributed to natural abundance ¹⁵N. The influence of the scalar relaxation mechanism on the linewidth of the ¹H ammonia resonance is probed by variable temperature NMR. A rotational correlation time of τc= 1.5 ps. is determined for endohedral NH₃, and of τc=57±5 ps. for the open fullerene, indicating free rotation of the encapsulated molecule. IR spectroscopy of NH3@2 at 5 K identifies three vibrations of NH₃ (ν₁, ν₃ and ν₄) redshifted in comparison with free NH₃, and temperature dependence of the IR peak intensity indicates the presence of a large number of excited translational/ rotational states. Variable temperature ¹H NMR spectra indicate that endohedral CH4 is also able to rotate freely at 223 K, on the NMR timescale. Inelastic neutron scattering (INS) spectra of CH₄@1 show both rotational and translational modes of CH₄. Energy of the first excited rotational state (J=1) of CH₄@1 is significantly lower than that of free CH₄

The dipolar endofullerene HF@C60

The cavity inside fullerenes provides a unique environment for the study of isolated atoms and molecules. We report encapsulation of hydrogen fluoride inside C60 using molecular surgery to give the endohedral fullerene HF@C60. The key synthetic step is the closure of the open fullerene cage while minimizing escape of HF. The encapsulated HF molecule moves freely inside the cage and exhibits quantization of its translational and rotational degrees of freedom, as revealed by inelastic neutron scattering and infrared spectroscopy. The rotational and vibrational constants of the encapsulated HF molecules were found to be redshifted relative to free HF. The NMR spectra display a large 1H-19F J coupling typical of an isolated species. The dipole moment of HF@C60 was estimated from the temperature-dependence of the dielectric constant at cryogenic temperatures and showed that the cage shields around 75% of the HF dipole

Quantum rotation of ortho and para-water encapsulated in a fullerene cage

Inelastic neutron scattering, far-infrared spectroscopy, and cryogenic nuclear magnetic resonance are used to investigate the quantized rotation and ortho–para conversion of single water molecules trapped inside closed fullerene cages. The existence of metastable ortho-water molecules is demonstrated, and the interconversion of ortho-and para-water spin isomers is tracked in real time. Our investigation reveals that the ground state of encapsulated ortho water has a lifted degeneracy, associated with symmetry-breaking of the water environmen

Transport IV characterisation of MgB2 conductor at a bend radius of 50mm

Performance of state of the art MgB2 multifilamentary conductor at a required bend radius is essential for many applications including but not limited to magnets and motors. The characterisation is generally done with benchmark transport Ic but further detail can be seen in IV characteristics which are undertaken in this paper. Two conductors with the same architecture but different diameters, 0.89 and 0.45 mm were measured from 32 K to 20 K in self-field in conditions of as received and deformed to a 50 mm bend diameter, corresponding to strains of 1.4 % and 0.7 % respectively. The qualifying 0.45mm conductor was further measured in background fields up to 3 T. The smaller diameter wire was found to have no signs of degradation of critical behaviour in Ic or IV characteristic

Some aspects of thermometry and heat transfer below 0.3 K

Applied Science