Shear-Force Sensors on Flexible Substrates Using Inkjet Printing

Printing techniques are a promising way of fabricating low-cost electronics without the need for masking and etching. In recent years, additive printing techniques, such as inkjet and screen printing, have been adopted to fabricate low-cost and large-area electronics on flexible substrates. In this work, a three-axial normal and shear force sensor was designed and printed that consists of four miniaturized, printed capacitors. The partially overlapping electrodes are arranged in a manner, so that force sensitivity in orthogonal directions is achieved. A silicone rubber is used as an elastic dielectric and spacer between the two electrodes. The base unit of this sensor has been fabricated using inkjet printing and characterized for normal and shear forces. The force response was investigated in a force range from 0.1 N to 8 N, the normal-force sensitivity was determined to be Sz=5.2 fF/N, and the shear-force sensitivity was Sy=13.1 fF/N. Due to its sensing range, this sensor could be applicable in tactile sensing systems like wearables and artificial electronic skins

A Facile and Efficient Protocol for Preparing Residual-Free Single-Walled Carbon Nanotube Films for Stable Sensing Applications

In this article, we report on an efficient post-treatment protocol for the manufacturing of pristine single-walled carbon nanotube (SWCNT) films. To produce an ink for the deposition, the SWCNTs are dispersed in an aqueous solution with the aid of a carboxymethyl cellulose (CMC) derivative as the dispersing agent. On the basis of this SWCNT-ink, ultra-thin and uniform films are then fabricated by spray-deposition using a commercial and fully automated robot. By means of X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), we show that the CMC matrix covering the CNTs can be fully removed by an immersion treatment in HNO3 followed by thermal annealing at a moderate temperature of 100 ºC, in the ambient air. We propose that the presented protocols for the ink preparation and the post-deposition treatments can in future serve as a facile and efficient platform for the fabrication of high-quality and residual-free SWCNT films. The purity of SWCNT films is of particular importance for sensing applications, where residual-induced doping and dedoping processes distort the contributions from the sensing specimen. To study the usability of the presented films for practical applications, gas sensors are fabricated and characterized with the CNT-films as the sensing material, screen printed silver-based films for the interdigitated electrode (IDE) structure, and polyimide as a flexible and robust substrate. The sensors show a high and stable response of 11% to an ammonia (NH3) test gas, at a concentration of 10 ppm.The authors thank the Deutsche Forschungsgemeinschaft (DFG) and the Natural Sciences and Engineering Research Council (NSERC) for financial support of the Alberta/Technische Universität München Graduate School for Functional Hybrid Materials ATUMS (IRTG2022, NSERC CREATE), as well as the TUM Graduate School, the Nanosystems Initiative Munich (NIM), and the TUM International Graduate School of Science and Engineering (IGSSE)

Screen-Printed Chipless Wireless Temperature Sensor

A chipless wireless sensor for temperature monitoring is described in this work. The sensor is fabricated by screen printing of an RLC circuit on a flexible substrate. The sensing element is a resistive carbon paste with positive temperature coefficient placed in a small area in the interconnection between the inductor and the capacitor. This sensing layer modifies the resonance frequency of the circuit when the temperature varies. We also show the influence of the sensor sensitivity with respect to the reading distance

UHF Printed Sensor for Force Detection

In this contribution, we show the advances in the direction of designing Radiofrequency Identification (RFID) antennas with sensing capabilities. In this particular case, we have integrated a force/pressure sensor made of a silicon-based organic polymer in one of the arms of a dipole antenna made of silver paste. The sensor response to external forces modifies the resonance frequency of the dipole antenna that can be detected by an external RFID reader, building up a wireless force sensor system.Pervasive Electronics Advanced Research Laboratory(PEARL), Department of Electronics and Computer Technology, University of Granada Institute for Nanoelectronics, Technical University of Munic

Optimization of a Handwriting Method by an Automated Ink Pen for Cost-Effective and Sustainable Sensors

In this work, we present a do-it-yourself (DIY) approach for the environmental-friendly fabrication of printed electronic devices and sensors. The setup consists only of an automated handwriting robot and pens filled with silver conductive inks. Here, we thoroughly studied the fabrication technique and different optimized parameters. The best-achieved results were 300 mΩ/sq as sheet resistance with a printing resolution of 200 µm. The optimized parameters were used to manufacture fully functional electronics devices: a capacitive sensor and a RFID tag, essential for the remote reading of the measurements. This technique for printed electronics represents an alternative for fast-prototyping and ultra-low-cost fabrication because of both the cheap equipment required and the minimal waste of materials, which is especially interesting for the development of cost-effective sensors.TUM Graduate School and by the European Commission through the fellowship H2020-MSCA-IF-2017-794885-SELFSEN

Screen Printable Electrochemical Capacitors on Flexible Substrates

This work presents a novel approach for the fabrication of Electrochemical Capacitors (ECs) based on the screen-printing of a commercial carbon-based conductive ink on flexible substrates. This technique enables the fast and cost-effective production of ECs with high flexibility and outstanding performance over bending states and voltage cycling, as demonstrated by means of cyclic voltammetry and galvanometric charge-discharge measurements. Despite the fact that the specific areal capacitances achieved are lower than the ones obtained using other carbon-based materials (~22 μF/cm2), the results show that, as soon as new screen-printable carbon-based pastes become available, this fabrication method will enable the mass production of ECs that can be attached to any surface as a conformal patch, as it is being required by a large number of the emerging technological applications.This work has been partially supported by the Spanish Ministry of Education, Culture and Sport (MECD) and the European Union through the pre-doctoral grant FPU16/01451, and its mobility program, the project TEC2017-89955-P and fellowship H2020-MSCA-IF-2017794885-SELFSENS

How Metal/Insulator Interfaces Enable the Enhancement of the Hydrogen Evolution Reaction Kinetics in Two Ways

Laterally nanostructured surfaces give rise to a new dimension of understanding and improving electrochemical reactions. In this study, we present a peculiar mechanism appearing at a metal/insulator interface, which can significantly enhance the Hydrogen Evolution Reaction (HER) from water reduction by altering the local reaction conditions in two ways: facilitated adsorption of hydrogen on the metal catalyst surface and improved transfer of ions through the double layer. The mechanism is uncovered using electrodes consisting of well-defined nanometer-sized metal arrays (Au, Cu, Pt) embedded in an insulator layer (silicon nitride), varying various parameters of both the electrode (size of the metal patches, catalyst material) and the electrolyte (cationic species, cation concentration, pH). In addition, simulations of the electrochemical double layer are carried out, which support the elaborated mechanism. Knowledge of this mechanism will enable new design principles for novel composite electrocatalytic systems

Over-Stretching Tolerant Conductors on Rubber Films by Inkjet-Printing Silver Nanoparticles for Wearables

The necessity to place sensors far away from the processing unit in smart clothes or artificial skins for robots may require conductive wirings on stretchable materials at very low-cost. In this work, we present an easy method to produce wires using only commercially available materials. A consumer grade inkjet printer was used to print a wire of silver nanoparticles with a sheet resistance below 1 W/sq. on a non-pre-strained sheet of elastic silicone. This wire was stretched more than 10,000 times and was still conductive afterwards. The viscoelastic behavior of the substrate results in a temporarily increased resistance that decreases to almost the original value. After over-stretching, the wire is conductive within less than a second. We analyze the swelling of the silicone due to the ink’s solvent and the nanoparticle film on top by microscope and SEM images. Finally, a 60 mm long stretchable conductor was integrated onto wearables, and showed that it can bear strains of up to 300% and recover to a conductivity that allows the operation of an assembled LED assembled at only 1.8 V. These self-healing wires can serve as wiring and binary strain or pressure sensors in sportswear, compression underwear, and in robotic applications.This work has been partially supported the TUM Graduate School (TUM GS), and the European Union through the fellowship H2020-MSCA-IF-2017 794885-SELFSENS. Additionally, this work was supported by the German Research Foundation (DFG) and the Technical University of Munich within the Open Access Publishing Funding Programme

Screen Printed Security-Button for Radio Frequency Identification Tags

Radio frequency identi cation (RFID) security is a relevant matter. The wide spread of RFID applications in the general society and the persistent attempts to safeguard it con rm it, especially since its use involves payments and the store or transmission of sensitive information. In this contribution, we present an innovative solution for improving the security of RFID passive tags through the use of a screen printed button, that allows the reception and transmission only when a certain level of physical pressure normal to its plane is applied. The materials and fabrication technology used demonstrate an easy to implement and cost-effective system, valuable in several scenarios where the user has straight contact with the tags and where its usage is direct and intentional.This work was supported by the fellowship under Grant 2020-MSCA-IF-2017-794885-SELFSENS

Enabling Logic Computation Between Ta/CoFeB/MgO Nanomagnets

Dipolar coupled magnets proved to have the potential to be capable of successfully performing digital computation in a highly parallel way. For that, nanomagnet-based computation requires precise control of the domain wall nucleation from a well-localized region of the magnet. Co/Pt and Co/Ni multilayer stacks were successfully used to demonstrate a variety of computing devices. However, Ta/CoFeB/MgO appears more promising, thanks to the lower switching field required to achieve a full magnetization reversal, reduced thickness (less than 10 nm), and its compatibility with magnetic tunnel junctions. In this work, the switch of the information is achieved through the application of a magnetic field, which allows to scale more the nanomagnets with respect to current-driven magnetization reversal-based devices and to go toward 3-D structures. We experimentally demonstrate that Ga ions can be used to tune the energy landscape of the structured magnets to provide signal directionality and achieve a distinct logic computation. We prove that it is possible to define the artificial nucleation center (ANC) in different structures with two irradiation steps and that this approach can enable logic computation in ultrathin films by dipolar interaction. Moreover, different from previous studies, the results coming from the irradiation analysis are then used for real logic devices. We present the experimental demonstration of a set of fully working planar inverters, showing that it is possible to reach a coupling field between the input and the output, which is strong enough to reliably implement logic operations. Micromagnetic simulations are used to study the nucleation center's effectiveness with respect to its position in the magnet and to support the experiments. Our results open the path to the development of more efficient nanomagnet-based logic circuits