DoE Method for Operating Parameter Optimization of a Dual-Fuel BioEthanol/Diesel Light Duty Engine

In recent years, alcoholic fuels have been considered as an alternative transportation biofuel even in compression ignition engines either as blended in diesel or as premixed fuel in the case of dual-fuel configuration. Within this framework, the authors investigated the possibility to improve the combustion efficiency when ethanol is used in a dual-fuel light duty diesel engine. In particular, the study was focused on reducing the HC and CO emissions at low load conditions, acting on the most influential engine calibration parameters. Since this kind of investigation would require a significant number of runs, the statistical design of experiment methodology was adopted to reduce significantly its number. As required by the DoE approach, a set of factors (injection parameters, etc.) were selected. For each of them, two levels "high" and "low" were defined in a range of reasonable values. Combining the levels of all the factors, it was possible to evaluate the effects and the weight of each factor and of their combination on the outputs. The results identified the rail pressure, the pilot, and post-injection as the most influential emission parameters. Significant reductions of unburnt were found acting on those parameters without substantial penalties on the global engine performances

Experimental assessment on exploiting low carbon ethanol fuel in a light-duty dual-fuel compression ignition engine

Compression ignition (CI) engines are widely used in modern society, but they are also recognized as a significative source of harmful and human hazard emissions such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, the combustion of fossil fuels is related to the growing amount of greenhouse gas (GHG) emissions, such as carbon dioxide (CO2). Stringent emission regulatory programs, the transition to cleaner and more advanced powertrains and the use of lower carbon fuels are driving forces for the improvement of diesel engines in terms of overall efficiency and engine-out emissions. Ethanol, a light alcohol and lower carbon fuel, is a promising alternative fuel applicable in the dual-fuel (DF) combustion mode to mitigate CO2 and also engine-out PM emissions. In this context, this work aims to assess the maximum fuel substitution ratio (FSR) and the impact on CO2 and PM emissions of different nozzle holes number injectors, 7 and 9, in the DF operating mode. The analysis was conducted within engine working constraints and considered the influence on maximum FSR of calibration parameters, such as combustion phasing, rail pressure, injection pattern and exhaust gas recirculation (EGR). The experimental tests were carried out on a single-cylinder light-duty CI engine with ethanol introduced via port fuel injection (PFI) and direct injection of diesel in two operating points, 1500 and 2000 rpm and at 5 and 8 bar of brake mean effective pressure (BMEP), respectively. Noise and the coefficient of variation in indicated mean effective pressure (COVIMEP) limits have been chosen as practical constraints. In particular, the experimental analysis assesses for each parameter or their combination the highest ethanol fraction that can be injected. To discriminate the effect on ethanol fraction and the combustion process of each parameter, a one-at-a-time-factor approach was used. The results show that, in both operating points, the EGR reduces the maximum ethanol fraction injectable; nevertheless, the ethanol addition leads to outstanding improvement in terms of engine-out PM. The adoption of a 9 hole diesel injector, for lower load, allows reaching a higher fraction of ethanol in all test conditions with an improvement in combustion noise, on average 3 dBA, while near-zero PM emissions and a reduction can be noticed, on the average of 1 g/kWh, and CO2 compared with the fewer nozzle holes case. Increasing the load insensitivity to different holes number was observed

Experimental Assessment on Exploiting Low Carbon Ethanol Fuel in a Light-Duty Dual-Fuel Compression Ignition Engine

Compression ignition (CI) engines are widely used in modern society, but they are also recognized as a significative source of harmful and human hazard emissions such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, the combustion of fossil fuels is related to the growing amount of greenhouse gas (GHG) emissions, such as carbon dioxide (CO2). Stringent emission regulatory programs, the transition to cleaner and more advanced powertrains and the use of lower carbon fuels are driving forces for the improvement of diesel engines in terms of overall efficiency and engine-out emissions. Ethanol, a light alcohol and lower carbon fuel, is a promising alternative fuel applicable in the dual-fuel (DF) combustion mode to mitigate CO2 and also engine-out PM emissions. In this context, this work aims to assess the maximum fuel substitution ratio (FSR) and the impact on CO2 and PM emissions of different nozzle holes number injectors, 7 and 9, in the DF operating mode. The analysis was conducted within engine working constraints and considered the influence on maximum FSR of calibration parameters, such as combustion phasing, rail pressure, injection pattern and exhaust gas recirculation (EGR). The experimental tests were carried out on a single-cylinder light-duty CI engine with ethanol introduced via port fuel injection (PFI) and direct injection of diesel in two operating points, 1500 and 2000 rpm and at 5 and 8 bar of brake mean effective pressure (BMEP), respectively. Noise and the coefficient of variation in indicated mean effective pressure (COVIMEP) limits have been chosen as practical constraints. In particular, the experimental analysis assesses for each parameter or their combination the highest ethanol fraction that can be injected. To discriminate the effect on ethanol fraction and the combustion process of each parameter, a one-at-a-time-factor approach was used. The results show that, in both operating points, the EGR reduces the maximum ethanol fraction injectable; nevertheless, the ethanol addition leads to outstanding improvement in terms of engine-out PM. The adoption of a 9 hole diesel injector, for lower load, allows reaching a higher fraction of ethanol in all test conditions with an improvement in combustion noise, on average 3 dBA, while near-zero PM emissions and a reduction can be noticed, on the average of 1 g/kWh, and CO2 compared with the fewer nozzle holes case. Increasing the load insensitivity to different holes number was observed

Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy Fuels, copyright © American Chemical Society after peer review and technical editing by the publisher.[EN] The present work includes findings from proof-of-principle feasibility studies on iron nanopowder combustion under idealized, enginelike, and real engine conditions. The study was conducted under the scope of recent interest in metallic nanoparticles as alternative fuels for internal combustion engines. More specifically, Fe nanoparticles with different morphologies and average primary particle sizes ranging from 25 to 85 nm were studied with respect to their oxidation characteristics via thermogravimetric analysis as well as in customized shock tube, constant-volume vessel, and compression-ignition (CI) engine configurations. Combusted powder samples were in all cases examined via in situ and ex situ techniques for the identification of combustion products and their morphologies. The findings facilitated the determination of the main phenomena involved during oxidation. The results verified that combustion of Fe nanoparticles in a slightly modified CI engine is feasible, albeit with various technological challenges related to ignition and scavenging that inhibit combustion quality.The authors thank the European Commission for partial funding of this work through the Project “COMETNANO” (FP7-NMP4-SL-2009-229063).Mandilas, C.; Karagiannakis, G.; Konstandopoulos, AG.; Beatrice, C.; Lazzaro, M.; Di Blasio, G.; Molina, S.... (2016). Study of Oxidation and Combustion Characteristics of Iron Nanoparticles under Idealized and Enginelike Conditions. Energy and Fuels. 30(5):4318-4330. https://doi.org/10.1021/acs.energyfuels.6b00121S4318433030

Development of a Diesel Surrogate Fuel Library

[EN] Diesel fuel is composed of a complex mixture of hundreds of hydrocarbons that vary globally depending on crude oil sources, refining processes, legislative requirements and other factors. In order to simplify the study of this fuel, researchers create surrogate fuels to mimic the physical and chemical properties of Diesel fuels. This work employed the commercial software Reaction Workbench - Surrogate Blend Optimizer (SBO) to develop a Surrogate Fuel Library containing 18 fuels. Within the fuel library, the cetane number ranges from 35 to 60 (in increments of 5) at threshold soot index (TSI) levels representative of low, baseline and high sooting tendency fuels (TSI = 17, 31 and 48, respectively). The Surrogate Fuel Library provides the component blend ratios and predicted properties for cetane number, threshold soot index, lower heating value, density, kinematic viscosity, molar hydrogen-to-carbon ratio and distillation curve temperatures from T-10 to T-90. A market petroleum Diesel fuel with a cetane number of 50 and a threshold soot index of 31 was selected as the Baseline Diesel Fuel. The combustion, physical and chemical properties of the Baseline Diesel Fuel were precisely matched by the Baseline Surrogate Fuel. To validate the SBO predicted fuel properties, a set of five surrogate fuels, deviating in cetane number and threshold soot index, were blended and examined with ASTM tests. Good agreement was obtained between the SBO predicted and ASTM measured fuel properties. To further validate the Surrogate Fuel Library, key properties that were effected by altering the component blend ratios to control cetane number and TSI were compared to a set of five market Diesel fuels with good results. These properties included density, viscosity, energy density and the T-10 and T-90 distillation temperatures. The Surrogate Fuel Library provided by this work supplies Diesel engine researchers and designers the ability to analytically and experimentally vary fuel cetane number and threshold soot index with fully-representative surrogate fuels. This new capability to independently vary cetane number and threshold soot index provides a means to further enhance the understanding of Diesel combustion and design future combustion systems that improve efficiency and emissions.Szymkowicz, P.; Benajes, J. (2018). Development of a Diesel Surrogate Fuel Library. Fuel. 222:21-34. https://doi.org/10.1016/j.fuel.2018.01.112S213422

Low cetane number renewable oxy-fuels for premixed combustion concept application : experimental investigation on a light duty diesel engine

This paper illustrates the results of an experimental study on the impact of a low cetane number (CN) oxygenated fuel on the combustion process and emissions of a light-duty (LD) single-cylinder research engine. In an earlier study, it was concluded that cyclic oxygenates consistently outperformed their straight and branched counterparts at equal oxygen content and with respect to lowering soot emissions. A clear correlation was reported linking soot and CN, with lower CN fuels leading to more favorable soot levels. It was concluded that a lower CN fuel, when realized by adding low reactive cyclic oxygenates to commercial diesel fuel, manifests in longer ignition delays and thus more premixing. Ultimately, a higher degree of premixing, in turn, was thought to suppress soot formation rates. Such compounds have the advantage to be stable in blends with fossil diesel fuel, to have a boiling point close to the diesel fuel range, and have the potential to be produced in a renewable way from lignin , which has a similar hexagonal hydrocarbon basis, albeit in polymer form. Lignin is currently a widely available second generation biomass waste stream, found in for example the paper pulp industry and cellulosic ethanol plants. In the present work, blends of diesel and cyclohexanone were tested in a LD single cylinder research diesel engine in order to evaluate its effects on the combustion process and pollutant emissions, employing both conventional (i.e. mixing-controlled) combustion (at medium/high engine loads) and premixed combustion (at medium/low loads). The results suggest that the combination of low CN and fuel oxygen appears to have a favorable impact on both fuel efficiency and overall emissions in premixed-mode. For mixing-controlled combustion, at medium/high engine loads, the negative effects of low CN (e.g. retarded combustion phasing) can be overcome with an appropriate calibration of the injection parameters. The high unburnt hydrocarbon emissions at low load, conversely, require a further development of the combustion system design, as well as the after-treatment device. Finally, to realize a more and more precise control of the in-cylinder air-fuel charge, before and during the combustion, the future PCCI fuels have to be tailored to the specific combustion process characteristics. In this framework, renewable low CN oxygenated fuels might function as an enabler for PCCI combustion engines

Assessment of Direct Injected Liquefied Petroleum Gas-Diesel Blends for Ultra-Low Soot Combustion Engine Application

Technological and economic concerns correlated to fulfilling future emissions and CO2 standards require great research efforts to define an alternative solution for low emissions and highly efficient propulsion systems. Alternative fuel formulation could contribute to this aim. Liquefied petroleum gas (LPG) with lower carbon content than other fossil fuels and which is easily vaporized at ambient conditions has the advantage of lowering CO2 emissions and optimizing the combustion process. Liquefied petroleum gas characteristics and availability makes the fuel a promising alternative for internal combustion engines. The possible combination of using it in high-efficiency compression ignition engines makes it worth analyzing the innovative method of using LPG as a blend component in diesel. Few relevant studies are detectable in literature in this regard. In this study, two blends containing diesel and LPG, in volume ratios 20/80 and 35/65, respectively, were formulated and utilized. Their effects on combustion and emissions performance were assessed by performing proper experimental tests on a modern light-duty single-cylinder engine test rig. Reference operating points at conventional engine calibration settings were examined. A specific exhaust gas recirculation (EGR) parametrization was performed evaluating the LPG blends’ potential in reducing the smoke emissions at standard engine-out NOx levels. The results confirm excellent NOx-smoke trade-off improvements with smoke reductions up to 95% at similar NOx and efficiency. Unburnt emissions slightly increase, and to acceptable levels. Improvements, in terms of indicated specific fuel consumption (ISFC), are detected in the range of 1–3%, as well as the CO2 decrease proportionally to the mixing ratio

Parametric Analysis of the Effect of Pilot Quantity, Combustion Phasing and EGR on Efficiencies of a Gasoline PPC Light-Duty Engine

In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions. The experiments are conducted on a 2l Volvo Euro 6 diesel engine. The fuels tested are Gasoline RON75 and MK1 diesel. Gasoline RON75 permits operation from low to high engine load conditions. A pilot/main injection strategy is adopted, necessary to control the peak pressure rise rate (PRRmax) to acceptable values and to extend the maximum engine load operating area in PPC. The experimental results show that increasing the EGR rate from 0 to 30%, the net efficiency improves approximately of 1.5% units, due to the shorter combustion duration. For all the conditions examined in PPC, the soot levels are about two times lower than diesel combustion. With a high level of EGR, combined with optimized pilot quantity and combustion phasing, high-efficiency PPC combustion can be achieved without penalties in terms of NOx emissions compared to diesel combustion

Performance and emissions of diesel-gasoline-ethanol blends in a light duty compression ignition engine

An approach to reduce CO2 emissions while simultaneously keeping the soot emissions down from compression ignition (CI) engines is to blend in short chained oxygenates into the fuel. In this work, two oxygenated fuel blends consisting of diesel, gasoline and ethanol (EtOH) in the ratio of 68:17:15 and 58:14:30 have been utilized and studied in a single cylinder light duty (LD) CI engine in terms of efficiency and emissions. The reasons of utilizing gasoline in the fuel blend is due to the emulsifying properties it has while increasing the total octane rating of the fuel to be able to run the engine with a higher fraction of premixed flame. When performing the experiments, the control parameters were set as close as possible to the original equipment manufacturer (OEM) EU5 calibration of the multi-cylinder engine to study the possibility of using such blends in close to stock LD CI engines. With the oxygenates, in particular the fuel with the higher concentration of EtOH achieved an indicated net efficiency of ∼51% inf comparison to ∼47% for diesel at 8 bar BMEP. The NOX emissions increased slightly for the double injection strategy at 13 bar BMEP from ∼13.5 g/kW h to ∼14.5 g/kW h when going from diesel fuel to the higher ethanol blend. However utilizing single injection strategy at lower loads reduces the NOX. Highest soot mass measured for diesel was ∼0.46 g/kW h in contrast to ∼0.1 g/kW h for the oxygenates. Also, soot production when running the engine on the ethanol containing fuels was not significantly affected by EGR utilization as in the case of diesel. Considering particle size distribution, the particles are reduced both in terms of mean diameter and quantity. At 1500 rpm and 2 bar BMEP an increase of over ∼300% in THC and CO was measured, however, increasing the speed and load to above 2000 rpm and 8 bar BMEP respectively, made the difference negligible due to high in-cylinder temperatures contributing to better fuel oxidation. Despite having lower cetane numbers, higher combustion stability was observed for the oxygenates fuels