Suppression of superconductivity in high-TcT_c cuprates due to nonmagnetic impurities: Implications for the order parameter symmetry

We studied the effects of nonmagnetic impurities on high-temperature superconductors by solving the Bogoliubov-de Gennes equations on a two-dimensional lattice via exact diagonalization technique in a fully self-consistent way. We found that s-wave order parameter is almost unaffected by impurities at low concentrations while $d_{x^2-y^2}$-wave order parameter exhibits a strong linear decrease with impurity concentration. We evaluated the critical impurity concentration $n_i^c$ at which superconductivity ceases to be 0.1 which is in good agreement with experimental values. We also investigated how the orthorhombic nature of the crystal structure affects the suppression of superconductivity and found that anisotropy induces an additional s-wave component. Our results support $d_{x^2-y^2}$-wave symmetry for tetragonal and $s+d_{x^2-y^2}$-wave symmetry for orthorhombic structure.Comment: LaTeX, 5 pages, 4 figures, uses grafik.sty (included

Energy spectrum for two-dimensional potentials in very high magnetic fields

A method, analogous to supersymmetry transformation in quantum mechanics, is developed for a particle in the lowest Landau level moving in an arbitrary potential. The method is applied to two-dimensional potentials formed by Dirac delta scattering centers. In the periodic case, the problem is solved exactly for rational values of the magnetic flux (in units of flux quantum) per unit cell. The spectrum is found to be self-similar, resembling the Hofstadter butterfly.Comment: 9 pages, 3 figures, REVTEX, to appear in Phys. Rev. B, Sep. 1

Dropping of electromagnetic waves through localized modes in three-dimensional photonic band gap structure

Cataloged from PDF version of article.We experimentally demonstrate trapping and dropping of photons through localized cavity modes in three-dimensional layer-by-layer photonic crystal structures. By creating acceptor- and donor-like cavities which are coupled to a highly confined waveguide (HCW), we drop selected frequencies from the waveguide mode. Tunability of the demultiplexing structures can be achieved by changing the properties of cavities and the coupling between the cavity and the HCW. (C) 2002 American Institute of Physics

Turn-on Fluorescent Dopamine Sensing Based on in Situ Formation of Visible Light Emitting Polydopamine Nanoparticles

Cataloged from PDF version of article.Dopamine is the principle biomarker for diseases such as schizophrenia, Huntington's, and Parkinson's, and the need is urgent for rapid and sensitive detection methods for diagnosis and monitoring of such diseases. In this Article, we report a turn-on fluorescent method for rapid dopamine sensing which is based on monitoring the intrinsic fluorescence of in situ synthesized polydopamine nanoparticles. The assay uses only a common base and an acid, NaOH and HCl to initiate and stop the polymerization reaction, respectively, which makes the assay extremely simple and low cost. First, we studied the in situ optical properties of polydopamine nanoparticles, for the first time, which formed under different alkaline conditions in order to determine optimum experimental parameters. Then, under optimized conditions we demonstrated high sensitivity (40 nM) and excellent selectivity of the assay. With its good analytical figures of merit, the described method is very promising for detection of dopamine related diseases

Superenhancers: Novel opportunities for nanowire optoelectronics

Cataloged from PDF version of article.Nanowires play a crucial role in the development of new generation optoelectronic devices ranging from photovoltaics to photodetectors, as these designs capitalize on the low material usage, utilize leaky-mode optical resonances and possess high conversion efficiencies associated with nanowire geometry. However, their current schemes lack sufficient absorption capacity demanded for their practical applicability, and more efficient materials cannot find widespread usage in these designs due to their rarity and cost. Here we suggest a novel and versatile nanoconcentrator scheme utilizing unique optical features of non-resonant Mie (NRM) scattering regime associated with low-index structures. The scattering regime is highly compatible with resonant Mie absorption effect taking place in nanowire absorbers. This technique in its optimized forms can provide up to 1500% total absorption enhancement, 400-fold material save and is suitable for large-area applications with significant area preservation compared to thin-film of same materials. Proposed superenhancer concept with its exceptional features such as broadband absorption enhancement, polarization immunity and material-independent manner paves the way for development of efficient nanowire photosensors or solar thermophotovoltaic devices and presents novel design opportunities for self-powered nanosystems

Disorder and localization in the lowest Landau level in the presence of dilute point scatterers

Cataloged from PDF version of article.We study the localization properties of a two-dimensional noninteracting electron gas in the presence of randomly distributed short-range scatterers in very high magnetic fields. We evaluate the participation number of the eigenstates obtained by exact diagonalization technique. At low impurity concentrations we obtain self-averaged values showing that all states, except those exactly at the Landau level, are localized with finite localization length. We conclude that in this dilute regime the localization length does not diverge. We also find that the maximum localization length increases exponentially with impurity concentration. Our calculations suggest that scaling behavior may be absent even for higher concentrations of scatterers. (C) 1999 Elsevier Science Ltd. All rights reserved

Photonic-crystal-based beam splitters

Cataloged from PDF version of article.We proposed and demonstrated two different methods to split electromagnetic waves in three-dimensional photonic crystals. By measuring transmission spectra, it was shown that the guided mode in a coupled-cavity waveguide can be splitted into the coupled-cavity or planar waveguide channels without radiation losses. The flow of electromagnetic waves through output waveguide ports can also be controlled by introducing extra defects into the crystals. Our results may have an important role in the design of efficient power splitters in a photonic circuit. (C) 2000 American Institute of Physics

Nanoconfinement of pyrene in mesostructured silica nanoparticles for trace detection of TNT in aqueous phase

Cataloged from PDF version of article.This article describes the preparation of pyrene confined mesostructured silica nanoparticles for the trace detection of trinitrotoluene (TNT) in the aqueous phase. Pyrene confined mesostructured silica nanoparticles were prepared using a facile one-pot method where pyrene molecules were first encapsulated in the hydrophobic parts of cetyltrimethylammonium micelles and then silica polymerized around these micelles. The resulting hybrid particles have sizes of around 75 nm with fairly good size distribution. Also, they are highly dispersible and colloidally stable in water. More importantly, they exhibit bright and highly stable pyrene excimer emission. We demonstrated that excimer emission of the particles exhibits a rapid, sensitive and visual quenching response against TNT. The detection limit for TNT was determined to be 12 nM. Furthermore, excimer emission of pyrene shows significantly high selectivity for TNT

Formation of pyrene excimers in mesoporous ormosil thin films for visual detection of nitro-explosives

Cataloged from PDF version of article.We report the preparation of mesoporous thin films with bright pyrene excimer emission and their application in visual and rapid detection of nitroaromatic explosive vapors. The fluorescent films were produced by physically encapsulating pyrene molecules in the organically modified silica (ormosil) networks which were prepared via a facile template-free sol-gel method. Formation and stability of pyrene excimer emission were investigated in both porous and nonporous ormosil thin films. Excimer emission was significantly brighter and excimer formation ability was more stable in porous films compared to nonporous films. Rapid and selective quenching was observed in the excimer emission against vapors of nitroaromatic molecules; trinitrotoluene (TNT), dinitrotoluene (DNT), and nitrobenzene (NB). Fluorescence quenching of the films can be easily observed under UV light, enabling the naked-eye detection of nitro-explosives. Furthermore, excimer emission signal can be recovered after quenching and the films can be reused at least five times