First observation of one noctilucent cloud by a twin lidar in two different directions

International audienceIn the early morning hours of 14 July 1999, a noctilucent cloud (NLC) was observed simultaneously by the two branches of a twin lidar system located at the ALOMAR observatory in northern Norway (69° N). The telescopes of the two lidars were pointing vertical (L^) and off the zenith by 30° (L30°). The two lidars detected an enhancement in the altitude profile of backscattered light (relative to the molecular background) for more than 5 h, starting approximately at 01:00 UT. These measurements constitute the detection of one NLC by two lidars under different directions and allow for a detailed study of the morphology of the NLC layer. A cross-correlation analysis of the NLC signals demonstrates that the main structures seen by both lidars are practically identical. This implies that a temporal evolution of the microphysics within the NLC during its drift from one lidar beam to the other is negligible. From the time delay of the NLC structures, a drift velocity of 55?65 m/s is derived which agrees nicely with radar wind measurements. During the observation period, the mean NLC altitude decreases by ~0.5 km/h (=14 cm/s) at both observation volumes. Further-more, the NLC is consistently observed approximately 500 m lower in altitude at L30° compared to L^. Supplementing these data by observations from rocket-borne and ground-based instruments, we show that the general downward progression of the NLC layer through the night, as seen by both lidars, is caused by a combination of particle sedimentation by 4?5 cm/s and a downward directed vertical wind by 9?10 cm/s, whereas a tilt of the layer in drift direction can be excluded

Simultaneous lidar observations of temperatures and waves in the polar middle atmosphere on the east and west side of the Scandinavian mountains: a case study on 19/20 January 2003

Atmospheric gravity waves have been the subject of intense research for several decades because of their extensive effects on the atmospheric circulation and the temperature structure. The U.&nbsp;Bonn&nbsp;lidar at the Esrange and the ALOMAR RMR lidar at the And&#248;ya Rocket Range are located in northern Scandinavia 250 km apart on the east and west side of the Scandinavian mountain ridge. During January and February&nbsp;2003 both lidar systems conducted measurements and retrieved atmospheric temperatures. On 19/20 January&nbsp;2003 simultaneous measurements for more than 7 h were possible. Although during most of the campaign time the atmosphere was not transparent for the propagation of orographically induced gravity waves, they were nevertheless observed at both lidar stations with considerable amplitudes during these simultaneous measurements. And while the source of the observed waves cannot be determined unambiguously, the observations show many characteristics of orographically excited gravity waves. The wave patterns at ALOMAR show a random distribution with time whereas at the Esrange a persistency in the wave patterns is observable. This persistency can also be found in the distribution of the most powerful vertical wavelengths. The mode values are both at about 5 km vertical wavelength, however the distributions are quite different, narrow at the Esrange with values from &lambda;<i>_z</i>=2&ndash;6 km and broad at ALOMAR, covering &lambda;<i>_z</i>=1&ndash;12 km vertical wavelength. In particular the difference between the observations at ALOMAR and at the Esrange can be understood by different orographic conditions while the propagation conditions were quite similar. At both stations the waves deposit energy in the atmosphere with increasing altitude, which leads to a decrease of the observed gravity wave potential energy density with altitude. The meteorological situation during these measurements was different from common winter situations. The ground winds were mostly northerlies, changed in the upper troposphere and lower stratosphere to westerlies and returned to northerlies in the middle stratosphere

Simultaneous lidar observations of temperatures and waves in the polar middle atmosphere on both sides of the Scandinavian mountains: a case study on 19/20 January 2003

International audienceAtmospheric gravity waves have been the subject of intense research for several decades because of their extensive effects on the atmospheric circulation and the temperature structure. The U. Bonn lidar at the Esrange and the ALOMAR RMR lidar at the Andøya Rocket Range are located in northern Scandinavia 250 km apart on either side of the Scandinavian mountain ridge. During January and February 2003 both lidar systems conducted measurements and retrieved atmospheric temperatures. On 19/20 January 2003 simultaneous measurements for more than 7 h were possible. Although during most of the campaign time the atmosphere was not transparent for the propagation of orographically induced gravity waves, they could propagate and were observed at both lidar stations during these simultaneous measurements. The wave patterns at ALOMAR show a random distribution with time whereas at the Esrange a persistency in the wave patterns is observable. This persistency can also be found in the distribution of the most powerful vertical wavelengths. The mode values are both at about 5 km vertical wavelength, however the distributions are quite different, narrow at the Esrange containing values from ?z=2?6 km and broad at ALOMAR, covering ?z=1?12 km vertical wavelength. At both stations the waves deposit energy in the atmosphere with increasing altitude, which leads to a decrease of the observed gravity wave potential energy density with altitude. These measurements show unambigiously orographically induced gravity waves on both sides of the mountains as well as a clear difference of the characteristics of these waves, which might be caused by different excitation and propagation conditions on either side of the Scandinavian mountain ridge

Mediterranean climate since the Middle Pleistocene: a 640 ka stable isotope record from Lake Ohrid (Albania/Macedonia)

Lake Ohrid (Macedonia/Albania) is an ancient lake with a unique biodiversity and a site of global significance for investigating the influence of climate, geological and tectonic events on the generation of endemic populations. Here, we present oxygen (δ18O) and carbon (δ13C) isotope data on carbonate from the upper ca. 248 m of sediment cores recovered as part of the Scientific Collaboration on Past Speciation Conditions in Lake Ohrid (SCOPSCO) project, covering the past 640 ka. Previous studies on short cores from the lake (up to 15 m, < 140 ka) have indicated the Total Inorganic Carbon (TIC) content of sediments to be highly sensitive to climate change over the last glacial–interglacial cycle, comprising abundant endogenic calcite through interglacials and being almost absent in glacials, apart from discrete bands of early diagenetic authigenic siderite. Isotope measurements on endogenic calcite (δ18Oc and δ13Cc) reveal variations both between and within interglacials that suggest the lake has been subject to hydroclimate fluctuations on orbital and millennial timescales. We also measured isotopes on authigenic siderite (δ18Os and δ13Cs) and, with the δ18OCc and δ18Os, reconstruct δ18O of lakewater (δ18Olw) through the 640 ka. Overall, glacials have lower δ18Olw when compared to interglacials, most likely due to cooler summer temperatures, a higher proportion of winter precipitation (snowfall), and a reduced inflow from adjacent Lake Prespa. The isotope stratigraphy suggests Lake Ohrid experienced a period of general stability through Marine Isotope Stage (MIS) 15 to MIS 13, highlighting MIS 14 as a particularly warm glacial, and was isotopically freshest during MIS 9. After MIS 9, the variability between glacial and interglacial δ18Olw is enhanced and the lake became increasingly evaporated through to present day with MIS 5 having the highest average δ18Olw. Our results provide new evidence for long-term climate change in the northern Mediterranean region, which will form the basis to better understand the influence of major environmental events on biological evolution within the lake

Mediterranean climate since the Middle Pleistocene: A 640 ka stable isotope record from Lake Ohrid (Albania/Macedonia)

Lake Ohrid (Macedonia/Albania) is an ancient lake with a unique biodiversity and a site of global significance for investigating the influence of climate, geological and tectonic events on the generation of endemic populations. Here, we present oxygen (δ18O) and carbon (δ13C) isotope data on carbonate from the upper ca. 248 m of sediment cores recovered as part of the Scientific Collaboration on Past Speciation Conditions in Lake Ohrid (SCOPSCO) project, covering the past 640 ka. Previous studies on short cores from the lake (up to 15 m, < 140 ka) have indicated the Total Inorganic Carbon (TIC) content of sediments to be highly sensitive to climate change over the last glacial-interglacial cycle, comprising abundant endogenic calcite through interglacials and being almost absent in glacials, apart from discrete bands of early diagenetic authigenic siderite. Isotope measurements on endogenic calcite(δ18Oc and δ13Cc) reveal variations both between and within interglacials that suggest the lake has been subject to hydroclimate fluctuations on orbital and millennial timescales. We also measured isotopes on authigenic siderite (δ18Os and δ13Cs) and, with the δ18OCc and δ18Os, reconstruct δ18O of lakewater (δ18Olw) through the 640 ka. Overall, glacials have lower δ18Olw when compared to interglacials, most likely due to cooler summer temperatures, a higher proportion of winter precipitation (snowfall), and a reduced inflow from adjacent Lake Prespa. The isotope stratigraphy suggests Lake Ohrid experienced a period of general stability through Marine Isotope Stage (MIS) 15 to MIS 13, highlighting MIS 14 as a particularly warm glacial, and was isotopically freshest during MIS 9. After MIS 9, the variability between glacial and interglacial δ18Olw is enhanced and the lake became increasingly evaporated through to present day with MIS 5 having the highest average δ18Olw. Our results provide new evidence for long-term climate change in the northern Mediterranean region, which will form the basis to better understand the influence of major environmental events on biological evolution within the lake

A new charge-transfer complex in UHV co-deposited tetramethoxypyrene and tetracyanoquinodimethane

UHV-deposited films of the mixed phase of tetramethoxypyrene and tetracyanoquinodimethane (TMP1-TCNQ1) on gold have been studied using ultraviolet photoelectron spectroscopy (UPS), X-ray-diffraction (XRD), infrared (IR) spectroscopy and scanning tunnelling spectroscopy (STS). The formation of an intermolecular charge-transfer (CT) compound is evident from the appearance of new reflexes in XRD (d1= 0.894 nm, d2= 0.677 nm). A softening of the CN stretching vibration (red-shift by 7 cm-1) of TCNQ is visible in the IR spectra, being indicative of a CT of the order of 0.3e from TMP to TCNQ in the complex. Characteristic shifts of the electronic level positions occur in UPS and STS that are in reasonable agreement with the prediction of from DFT calculations (Gaussian03 with hybrid functional B3LYP). STS reveals a HOMO-LUMO gap of the CT complex of about 1.25 eV being much smaller than the gaps (>3.0 eV) of the pure moieties. The electron-injection and hole-injection barriers are 0.3 eV and 0.5 eV, respectively. Systematic differences in the positions of the HOMOs determined by UPS and STS are discussed in terms of the different information content of the two methods.Comment: 20 pages, 6 figure