Identification and characterization of the dominant thermal resistance in lithium-ion batteries using operando 3-omega sensors

Poor thermal transport within lithium-ion batteries fundamentally limits their performance, safety, and lifetime, in spite of external thermal management systems. All prior efforts to understand the origin of batteries' mysteriously high thermal resistance have been confined to ex situ measurements without understanding the impact of battery operation. Here, we develop a frequency-domain technique that employs sensors capable of measuring spatially resolved intrinsic thermal transport properties within a live battery while it is undergoing cycling. Our results reveal that the poor battery thermal transport is due to high thermal contact resistance between the separator and both electrode layers and worsens as a result of formation cycling, degrading total battery thermal transport by up to 70%. We develop a thermal model of these contact resistances to explain their origin. These contacts account for up to 65% of the total thermal resistance inside the battery, leading to far-reaching consequences for the thermal design of batteries. Our technique unlocks new thermal measurement capabilities for future battery research

Testing the Higgs Mechanism in the Lepton Sector with multi-TeV e+e- Collisions

Multi-TeV e+e- collisions provide with a large enough sample of Higgs bosons to enable measurements of its suppressed decays. Results of a detailed study of the determination of the muon Yukawa coupling at 3 TeV, based on full detector simulation and event reconstruction, are presented. The muon Yukawa coupling can be determined with a relative accuracy of 0.04 to 0.08 for Higgs bosons masses from 120 GeV to 150 GeV, with an integrated luminosity of 5 inverse-ab. The result is not affected by overlapping two-photon background.Comment: 6 pages, 2 figures, submitted to J Phys G.: Nucl. Phy

Electron Power-Law Spectra in Solar and Space Plasmas

Particles are accelerated to very high, non-thermal energies in solar and space plasma environments. While energy spectra of accelerated electrons often exhibit a power law, it remains unclear how electrons are accelerated to high energies and what processes determine the power-law index $\delta$. Here, we review previous observations of the power-law index $\delta$ in a variety of different plasma environments with a particular focus on sub-relativistic electrons. It appears that in regions more closely related to magnetic reconnection (such as the `above-the-looptop' solar hard X-ray source and the plasma sheet in Earth's magnetotail), the spectra are typically soft ($\delta \gtrsim$ 4). This is in contrast to the typically hard spectra ($\delta \lesssim$ 4) that are observed in coincidence with shocks. The difference implies that shocks are more efficient in producing a larger non-thermal fraction of electron energies when compared to magnetic reconnection. A caveat is that during active times in Earth's magnetotail, $\delta$ values seem spatially uniform in the plasma sheet, while power-law distributions still exist even in quiet times. The role of magnetotail reconnection in the electron power-law formation could therefore be confounded with these background conditions. Because different regions have been studied with different instrumentations and methodologies, we point out a need for more systematic and coordinated studies of power-law distributions for a better understanding of possible scaling laws in particle acceleration as well as their universality.Comment: 67 pages, 15 figures; submitted to Space Science Reviews; comments welcom

Monodisperse core/shell and other complex structured nanocrystals and methods of preparing the same

Provides new compositions containing nearly monodisperse colloidal core/shell semiconductor nanocrystals with high photoluminescence quantum yields (PL QY), as well as other complex structured semiconductor nanocrystals. This invention also provides new synthetic methods for preparing these nanocrystals, and new devices comprising these compositions. In addition to core/shell semiconductor nanocrystals, this patent also provides complex semiconductor nanostructures, quantum shells, quantum wells, doped nanocrystals, and other multiple-shelled semiconductor nanocrystals

The early days of the Sculptor dwarf spheroidal galaxy

We present the high resolution spectroscopic study of five -3.9<=[Fe/H]<=-2.5 stars in the Local Group dwarf spheroidal, Sculptor, thereby doubling the number of stars with comparable observations in this metallicity range. We carry out a detailed analysis of the chemical abundances of alpha, iron peak, light and heavy elements, and draw comparisons with the Milky Way halo and the ultra faint dwarf stellar populations. We show that the bulk of the Sculptor metal-poor stars follows the same trends in abundance ratios versus metallicity as the Milky Way stars. This suggests similar early conditions of star formation and a high degree of homogeneity of the interstellar medium. We find an outlier to this main regime, which seems to miss the products of the most massive of the TypeII supernovae. In addition to its value to help refining galaxy formation models, this star provides clues to the production of cobalt and zinc. Two of our sample stars have low odd-to-even barium isotope abundance ratios, suggestive of a fair proportion of s-process; we discuss the implication for the nucleosynthetic origin of the neutron capture elements.Comment: Replacement after language editio

Renormalization of the Cabibbo-Kobayashi-Maskawa Quark Mixing Matrix

We have investigated the present renormalization prescriptions of Cabibbo-Kobayashi-Maskawa (CKM) matrix. When considering the prescription which is formulated with reference to the case of zero mixing we find it doesn't satisfy the unitary condition of the bare CKM matrix. After added a delicate patch this problem can be solved at one-loop level. In this paper We generalize this prescription to all loop levels and keep the unitarity of the bare CKM matrix, simultaneously make the amplitude of an arbitrary physical process involving quark mixing convergent and gauge independent. We also find that in order to keep the CKM counterterms gauge independent the unitarity of the bare CKM matrix must be preserved.Comment: has been revised, 8 pages, 1 figur

Analysis of the microphysical properties of snowfall using scanning polarimetric and vertically pointing multi-frequency Doppler radars

Radar dual-wavelength ratio (DWR) measurements from the Stony Brook Radar Observatory Ka-band scanning polarimetric radar (KASPR, 35 GHz), a W-band profiling radar (94 GHz), and a next-generation K-band (24 GHz) micro rain radar (MRRPro) were exploited for ice particle identification using triple-frequency approaches. The results indicated that two of the radar frequencies (K and Ka band) are not sufficiently separated; thus, the triple-frequency radar approaches had limited success. On the other hand, a joint analysis of DWR, mean Doppler velocity (MDV), and polarimetric radar variables indicated potential in identifying ice particle types and distinguishing among different ice growth processes and even in revealing additional microphysical details. We investigated all DWR pairs in conjunction with MDV from the KASPR profiling measurements and differential reflectivity (ZDR) and specific differential phase (KDP) from the KASPR quasi-vertical profiles. The DWR-versus-MDV diagrams coupled with the polarimetric observables exhibited distinct separations of particle populations attributed to different rime degrees and particle growth processes. In fallstreaks, the 35–94 GHz DWR pair increased with the magnitude of MDV corresponding to the scattering calculations for aggregates with lower degrees of riming. The DWR values further increased at lower altitudes while ZDR slightly decreased, indicating further aggregation. Particle populations with higher rime degrees had a similar increase in DWR but a 1–1.5 m s−1 larger magnitude of MDV and rapid decreases in KDP and ZDR. The analysis also depicted the early stage of riming where ZDR increased with the MDV magnitude collocated with small increases in DWR. This approach will improve quantitative estimations of snow amount and microphysical quantities such as rime mass fraction. The study suggests that triple-frequency measurements are not always necessary for in-depth ice microphysical studies and that dual-frequency polarimetric and Doppler measurements can successfully be used to gain insights into ice hydrometeor microphysics

Polypyrrole and polyaniline nanocomposites with high photothermal conversion efficiency

The simple and scalable synthesis of poly[2-(methacryloyloxy)ethyl phosphorylcholine] (PMPC)-coated conducting polymer (CP) nanocomposites is described. These functional nanocomposites exhibit tunable absorption in the near-infrared region with relatively high photothermal efficiencies. More importantly, their potential for bio-imaging and therapeutic treatment is proven by cellular uptake and cytotoxicity studies

Designing peptide nanoparticles for efficient brain delivery

The targeted delivery of therapeutic compounds to the brain is arguably the most significant open problem in drug delivery today. Nanoparticles (NPs) based on peptides and designed using the emerging principles of molecular engineering show enormous promise in overcoming many of the barriers to brain delivery faced by NPs made of more traditional materials. However, shortcomings in our understanding of peptide self-assembly and blood–brain barrier (BBB) transport mechanisms pose significant obstacles to progress in this area. In this review, we discuss recent work in engineering peptide nanocarriers for the delivery of therapeutic compounds to the brain, from synthesis, to self-assembly, to in vivo studies, as well as discussing in detail the biological hurdles that a nanoparticle must overcome to reach the brain