596 research outputs found
Picosecond real-time studies of mode-specific vibrational predissociation
The vibrational predissociation of several van der Waals complexes of t-stilbene has been studied by directly measuring, in real time, the fluorescence intensity from the initial reactant state and from the individual product states formed in the dissociation process after exciting single vibrational levels of the complex. With the aid of a kinetic model involving sequential processes, the individual rates for intramolecular vibrational redistribution and vibrational predissociation in the overall dissociation process are resolved and distinguished in several cases. In the stilbene–He complex, the dissociation is significantly faster from low energy out-of-plane modes than it is from a higher energy in-plane mode
Turning up by turning over : the change of scenery effect in major league baseball
Purpose: This study examined a “change of scenery” effect on performance in major league baseball (MLB). We also tested this effect for voluntary versus involuntary employee departures, as well as employees returning to a past employer.
Design/Methodology/Approach: This study uses publicly available MLB performance data from 2004 to 2015. The data comprise 712 team changes for players following two consecutive years with the same organization. Data were analyzed using MANCOVA to assess the impact of changing teams on player performance.
Findings: Results indicate players with declining performance benefited significantly from a change of scenery. Following a team change, these players experienced a significant increase in their performance that remained stable through a subsequent season. The effect was not different for players who changed teams via trade and free agency and was modest for those returning to a past organization. Analysis also showed that players leaving while their performance was improving suffered a subsequent performance drop-off in the new organization.
Implications: As the war for talent escalates and employees change jobs more frequently, extending our understanding of how performance can be influenced by work context may provide new insight into organization staffing policies.
Originality/Value: Results extend field theory by highlighting how past performance interacts with new work contexts to influence performance. This is one of the few studies evaluating the job change-performance relationship, and perhaps the first to account for the effects of performance trends prior to exit
Optical to near-infrared transmission spectrum of the warm sub-Saturn HAT-P-12b
We present the transmission spectrum of HAT-P-12b through a joint analysis of
data obtained from the Hubble Space Telescope Space Telescope Imaging
Spectrograph (STIS) and Wide Field Camera 3 (WFC3) and Spitzer, covering the
wavelength range 0.3-5.0 m. We detect a muted water vapor absorption
feature at 1.4 m attenuated by clouds, as well as a Rayleigh scattering
slope in the optical indicative of small particles. We interpret the
transmission spectrum using both the state-of-the-art atmospheric retrieval
code SCARLET and the aerosol microphysics model CARMA. These models indicate
that the atmosphere of HAT-P-12b is consistent with a broad range of
metallicities between several tens to a few hundred times solar, a roughly
solar C/O ratio, and moderately efficient vertical mixing. Cloud models that
include condensate clouds do not readily generate the sub-micron particles
necessary to reproduce the observed Rayleigh scattering slope, while models
that incorporate photochemical hazes composed of soot or tholins are able to
match the full transmission spectrum. From a complementary analysis of
secondary eclipses by Spitzer, we obtain measured depths of
and at 3.6 and 4.5 m, respectively, which are
consistent with a blackbody temperature of K and indicate
efficient day-night heat recirculation. HAT-P-12b joins the growing number of
well-characterized warm planets that underscore the importance of clouds and
hazes in our understanding of exoplanet atmospheres.Comment: 25 pages, 19 figures, accepted for publication in AJ, updated with
proof correction
van der Waals density functional calculations of binding in molecular crystals
A recent paper [J. Chem. Phys. 132, 134705 (2010)] illustrated the potential
of the van der Waals density functional (vdW-DF) method [Phys. Rev. Lett. 92,
246401 (2004)] for efficient first-principle accounts of structure and cohesion
in molecular crystals. Since then, modifications of the original vdW-DF version
(identified as vdW-DF1) has been proposed, and there is also a new version
called vdW-DF2 [ArXiv 1003.5255], within the vdW-DF framework. Here we
investigate the performance and nature of the modifications and the new version
for the binding of a set of simple molecular crystals: hexamine, dodecahedrane,
C60, and graphite. These extended systems provide benchmarks for computational
methods dealing with sparse matter. We show that a previously documented
enhancement of non-local correlations of vdW-DF1 over an asymptotic atom-based
account close to and a few A, beyond binding separation persists in vdW-DF2.
The calculation and analysis of the binding in molecular crystals requires
appropriate computational tools. In this paper, we also present details on our
real-space parallel implementation of the vdW-DF correlation and on the method
used to generate asymptotic atom-based pair potentials based on vdW-DF.Comment: 5 pages, 4 figure
Plasma Persistence of 2-Aminothiazoline-4-Carboxylic Acid in Rat System Determined by Liquid Chromatography Tandem Mass Spectrometry
2-Aminothiazoline-4-carboxylic acid (ATCA) was intravenously injected to rats in order to investigate its plasma distribution. ATCA was extracted from plasma samples by solid phase extraction (SPE) and molecularly imprinted polymer stir bar sorption extraction (MIP-SBSE). Detection and quantification of ATCA were achieved by using liquid chromatography–tandem mass spectrometry (LC–MS/MS). It was found that the intravenously injected ATCA concentration quickly decreased to half within 2.5 h in the rat system. However, after 2.5 h, the concentration of ATCA in plasma stayed constant at least 5 folds above the endogenous ATCA level for more then 48 h. This finding can be used for evaluating ATCA\u27s diagnostic and forensic value as a biomarker for cyanide exposure
Site Environmental Report for 2011, Volumes 1& 2
The Site Environmental Report for 2011 summarizes Berkeley Lab’s environmental management performance, presents environmental monitoring results, and describes significant programs for calendar year (CY) 2011. Throughout this report, “Berkeley Lab” or “LBNL” refers both to (1) the multiprogram scientific facility the UC manages and operates on the 202-acre university-owned site located in the hills above the UC Berkeley campus, and the site itself, and (2) the UC as managing and operating contractor for Ernest Orlando Lawrence Berkeley National Laboratory. The report is separated into two volumes. Volume I is organized into an executive summary followed by six chapters that include an overview of LBNL, a discussion of its Environmental Management System (EMS), the status of environmental programs, summarized results from surveillance and monitoring activities, and quality assurance (QA) measures. Volume II contains individual data results from surveillance and monitoring activities
Live-Cell Imaging of Cellular Proteins by a Strain-Promoted Azide–Alkyne Cycloaddition
Live and let dye: Three coumarin-cyclooctyne conjugates have been used to label proteins tagged with azidohomoalanine in Rat-1 fibroblasts. All three fluorophores labeled intracellular proteins with fluorescence enhancements ranging from eight- to 20-fold. These conjugates are powerful tools for visualizing biomolecule dynamics in living cells
An international survey and modified Delphi process revealed editors' perceptions, training needs, and ratings of competency-related statements for the development of core competencies for scientific editors of biomedical journals
Background: Scientific editors (i.e., those who make decisions on the content and policies of a journal) have a central role in the editorial process at biomedical journals. However, very little is known about the training needs of these editors or what competencies are required to perform effectively in this role. Methods: We conducted a survey of perceptions and training needs among scientific editors from major editorial organizations around the world, followed by a modified Delphi process in which we invited the same scientific editors to rate the importance of competency-related statements obtained from a previous scoping review. Results: A total of 148 participants completed the survey of perceptions and training needs. At least 80% of participants agreed on six of the 38 skill and expertise-related statements presented to them as being important or very important to their role as scientific editors. At least 80% agreed on three of the 38 statements as necessary skills they perceived themselves as possessing (well or very well). The top five items on participants’ list of top training needs were training in statistics, research methods, publication ethics, recruiting and dealing with peer reviewers, and indexing of journals. The three rounds of the Delphi were completed by 83, 83, and 73 participants, respectively, which ultimately produced a list of 23 “highly rated” competency-related statements and another 86 “included” items. Conclusion: Both the survey and the modified Delphi process will be critical for understanding knowledge and training gaps among scientific editors when designing curriculum around core competencies in the future
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