Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies

This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination not only has unexplored potential in traditional areas such as Boron Neutron Capture Therapy agents, but also as pharmacophores for the targeting of biologically important proteins and the development of targeted drugs. The synthetic pathways used for the syntheses of dicarba-closo-dodecarboranes-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium are also reviewed. Complexes with a wide variety of geometries and characteristics can be prepared. Examples of addition reactions on the metal centre, B–H activation, transmetalation reactions and/or direct formation of metal–metal bonds are discussed (103 references)

Equivalent random analysis of a buffered optical switch with general interarrival times

We propose an approximate analytic model of an optical switch with fibre delay lines and wavelength converters by employing Equivalent Random Theory. General arrival traffic is modelled by means of Gamma-distributed interarrival times. The analysis is formulated in terms of virtual traffic flows within the optical switch from which we derive expressions for burst blocking probability, fibre delay line occupancy and mean delay. Emphasis is on approximations that give good numerical efficiency so that the method can be useful for formulating dimensioning problems for large-scale networks. Numerical solution values from the proposed analysis method compare well with results from a discrete-event simulation of an optical burst switch

Tunable transform-limited pulse generation using self-injection locking of an FP laser

Wavelength-tunable, near transform-limited pulses have been generated using a Fabry-Perot laser diode coupled to a fiber loop containing a fiber Fabry-Perot resonator (FFPR) and a polarization controller. The ratio of transmitted to reflected light from the loop can be adjusted using the polarization controller. Single-mode operation of the gain-switched laser is achieved by self-injection locking, which is induced by light reflected from the fiber loop. The resulting output pulse has a time-bandwidth product of 0.4 and is tunable over about 15 nm by varying the tuning voltage of the FFPR

Ultra-narrow (sub-MHz) linewidth emission from discrete mode laser diodes

A class of laser which exhibits ultra-narrow sub MHz linewidth emission necessary for numerous applications in optical communications and sensors is described. The spectral performance of commercial discrete mode (DM) and distributed feedback (DFB) lasers is compared. The devices used in this work are asymmetrically coated ridge waveguide Fabry Perot lasers which incorporated etched slot features and emitting around lambda = 1.55 mum. The active region of the devices consisted of a strained compensated InAlGaAs MQW structure

Palliative care: promoting general practice participation

Specialist palliative care services and services involved in the pre-palliative phase of a patient’s disease must accept GPs as an integral part of the care tea

Nonlinear optical thresholding in a 4-Channel OCDMA system via two-photon absorption

We demonstrate the use of a Two-Photon Absorption based detector in an OCDMA system. This detector provides a significant performance improvement over standard linear detection

A high-speed optical star network using TDMA and all-optical demultiplexing techniques

The authors demonstrate the use of time-division multiplexing (TDM) to realize a high capacity optical star network. The fundamental element of the demonstration network is a 10 ps, wavelength tunable, low jitter, pulse source. Electrical data is encoded onto three optical pulse trains, and the resultant low duty cycle optical data channels are multiplexed together using 25 ps fiber delay lines. This gives an overall network capacity of 40 Gb/s. A nonlinear optical loop mirror (NOLM) is used to carry out the demultiplexing at the station receiver. The channel to be switched out can be selected by adjusting the phase of the electrical signal used to generate the control pulses for the NOLM. By using external injection into a gain-switched distributed feedback (DFB) laser we are able to obtain very low jitter control pulses of 4-ps duration (RMS jitter <1 ps) after compression of the highly chirped gain switched pulses in a normal dispersive fiber. This enables us to achieve excellent eye openings for the three demultiplexed channels. The difficulty in obtaining complete switching of the signal pulses is presented. This is shown to be due to the deformation of the control pulse in the NOLM (caused by the soliton effect compression). The use of optical time-division multiplexing (OTDM) with all-optical switching devices is shown to be an excellent method to allow us to exploit as efficiently as possible the available fiber bandwidth, and to achieve very high bit-rate optical networks

Low sensitivity to optical feedback and optical injection of discrete mode lasers

In this paper, we demonstrate the low sensitivity to both external optical feedback and external optical injection of a new type of extremely low cost single-mode lasers, called "discrete mode" (DM) lasers. The DM lasers are obtained from ridge waveguide Fabry Perot (FP) lasers, in which the effective refractive index of the lasing mode has been perturbed. These lasers exhibit a low sensitivity to external optical feedback since the coherence collapse threshold is around 5 dB higher in comparison to a commercial DFB laser

Numerical analysis of pulse pedestal and dynamic chirp formation on picosecond modelocked laser pulses after propagation through a semiconductor optical amplifier

A numerical analysis, based on a modified Schrodinger equation, of the formation of pulse pedestals and dynamic chirp formation on picosecond pulses after propagation through a semiconductor optical amplifier is presented. The numerical predictions are confirmed by an experiment that utilises the frequency resolved optical gating technique for the amplified pulse characterisation

Development of design criteria for an electrochemical water reclamation system

Electrochemical system design to recover water from human urin