Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle

This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries

Experimental configuration of direct drive cylindrical implosions on the Omega Laser

Details about the cylindrical implosions using direct-drive irradiation on the OMEGA Laser facility are provided. The experimental configuration, including orientation, construction, and mounting of the targets is described. An attempt to characterize the modulation transfer function of the primary x-ray framing camera diagnostic results in insufficient exposure contrast but relative agreement with other determinations. The x-ray intensity of the titanium backlighter driven by the 2.5-nsec linear ramp of the laser beams is described, and the relative intensity on film is compared to similar Nova experiments. The parallax effects of different length marker layers of high-opacity dichloropolystyrene is measured, resulting in the conclusion that the marker layer length should be matched to the laser drive illumination profile

Changes in orographic precipitation patterns caused by a shift from snow to rain

Climate warming will likely cause a shift from snow to rain in midlatitude mountains. Because rain falls faster than snow, it is not advected as far by prevailing winds before reaching the ground. A shift in precipitation phase thus may alter precipitation patterns. Using the Weather Research and Forecasting (WRF) regional climate model at 27-9-3 km resolutions over the California Sierra Nevada, we conducted an idealized experiment consisting of a present climate control run and two additional simulations in which (a) fall speed for snow is similar to rain and (b) all precipitation is constrained to fall as liquid. Rather than simulating future climates directly, these perturbation experiments allow us to test the potential impacts of changing precipitation phase in isolation from other factors such as variable large-scale atmospheric circulation. Relative to the control, both perturbations result in a rain shadow deepened by ̃30-60%, with increased focusing of precipitation on the western Sierra Nevada slopes best resolved at ≤9 km resolutions. Our results suggest that altered precipitation phase associated with climate change will likely affect spatial distributions of water resources, floods, and landslides in the Sierra Nevada and similar midlatitude mountain ranges. Citation: Pavelsky, T. M., S. Sobolowski, S. B. Kapnick, and J. B. Barnes (2012), Changes in orographic precipitation patterns caused by a shift from snow to rain, Geophys. Res. Lett., 39, L18706,

Lithologic and tectonic controls on bedrock channel form at the northwest Himalayan front

Recognition that channel form reflects a river's ability to erode rock and transport material has spawned stream-power models that estimate incision patterns by approximating energy dissipation within a channel. These models frequently assume that channel width scales as a power law with drainage area, partly because drainage area is easily extracted from digital elevation models (DEMs). However, this assumption is often confounded by local variations in rock strength and rock-uplift rate that can cause channel constriction downstream. Here we investigate the morphological response to spatial changes in rock strength and rock-uplift rate of 10 bedrock channels traversing the Mohand range along the northwest Himalayan front. We present a new method to continuously measure and compare channel width, slope, and other hydraulic parameters that integrate satellite imagery and DEM analysis. Our method corrects for an ∼13% overestimation of average channel gradient from a 90m resolution DEM that arises from short circuits of fine-scale meanders. We find that channels (1) narrow >1 km upstream from knickpoints formed by an increase in rock strength, (2) adjust laterally more than vertically in response to downstream decreases rock erodibility and uplift rate, and (3) meander where shear stresses are high and channel widths are low. We attribute these results to a high ratio of sediment supply to transport capacity, which enhances lateral erosion relative to vertical incision. Our results suggest that substrate strength and sediment supply substantially infl uence channel form and that channel width should be explicitly measured when interpreting tectonic signals from bedrock channel morphology

Heat Kernel Coefficients for Laplace Operators on the Spherical Suspension

In this paper we compute the coefficients of the heat kernel asymptotic expansion for Laplace operators acting on scalar functions defined on the so called spherical suspension (or Riemann cap) subjected to Dirichlet boundary conditions. By utilizing a contour integral representation of the spectral zeta function for the Laplacian on the spherical suspension we find its analytic continuation in the complex plane and its associated meromorphic structure. Thanks to the well known relation between the zeta function and the heat kernel obtainable via Mellin transform we compute the coefficients of the asymptotic expansion in arbitrary dimensions. The particular case of a $d$-dimensional sphere as the base manifold is studied as well and the first few heat kernel coefficients are given explicitly.Comment: 26 Pages, 1 Figur

Obtaining a class of Type O pure radiation metrics with a cosmological constant, using invariant operators

Using the generalised invariant formalism we derive a class of conformally flat spacetimes whose Ricci tensor has a pure radiation and a Ricci scalar component. The method used is a development of the methods used earlier for pure radiation spacetimes of Petrov types O and N respectively. In this paper we demonstrate how to handle, in the generalised invariant formalism, spacetimes with isotropy freedom and rich Killing vector structure. Once the spacetimes have been constructed, it is straightforward to deduce their Karlhede classification: the Karlhede algorithm terminates at the fourth derivative order, and the spacetimes all have one degree of null isotropy and three, four or five Killing vectors.Comment: 29 page

Totalitarianism and geography: L.S. Berg and the defence of an academic discipline in the age of Stalin

In considering the complex relationship between science and politics, the article focuses upon the career of the eminent Russian scholar, Lev Semenovich Berg (1876–1950), one of the leading geographers of the Stalin period. Already before the Russian Revolution, Berg had developed a naturalistic notion of landscape geography which later appeared to contradict some aspects of Marxist–Leninist ideology. Based partly upon Berg's personal archive, the article discusses the effects of the 1917 revolution, the radical changes which Stalin's cultural revolution (from the late 1920s) brought upon Soviet science, and the attacks made upon Berg and his concept of landscape geography thereafter. The ways in which Berg managed to defend his notion of geography (sometimes in surprisingly bold ways) are considered. It is argued that geography's position under Stalin was different from that of certain other disciplines in that its ideological disputes may have been regarded as of little significance by the party leaders, certainly by comparison with its practical importance, thus providing a degree of ‘freedom’ for some geographers at least analogous to that which has been described by Weiner (1999. A little corner of freedom: Russian nature protection from Stalin to Gorbachev. Berkeley: University of California Press) for conservationists. It is concluded that Berg and others successfully upheld a concept of scientific integrity and limited autonomy even under Stalinism, and that, in an era of ‘Big Science’, no modernizing state could or can afford to emasculate these things entirely

Roper Resonance and S_{11}(1535) from Lattice QCD

Using the constrained curve fitting method and overlap fermions with the lowest pion mass at $180 {\rm MeV}$, we observe that the masses of the first positive and negative parity excited states of the nucleon tend to cross over as the quark masses are taken to the chiral limit. Both results at the physical pion mass agree with the experimental values of the Roper resonance ($N^{1/2+}(1440)$) and $S_{11}$ ($N^{1/2-}(1535)$). This is seen for the first time in a lattice QCD calculation. These results are obtained on a quenched Iwasaki $16^3 \times 28$ lattice with $a = 0.2 {\rm fm}$. We also extract the ghost $\eta' N$ states (a quenched artifact) which are shown to decouple from the nucleon interpolation field above $m_{\pi} \sim 300 {\rm MeV}$. From the quark mass dependence of these states in the chiral region, we conclude that spontaneously broken chiral symmetry dictates the dynamics of light quarks in the nucleon.Comment: 10 pages, 5 figures, revised version to appear in PL

Impulsive waves in the Nariai universe

A new class of exact solutions is presented which describes impulsive waves propagating in the Nariai universe. It is constructed using a six-dimensional embedding formalism adapted to the background. Due to the topology of the latter, the wave front consists of two non-expanding spheres. Special sub-classes representing pure gravitational waves (generated by null particles with an arbitrary multipole structure) or shells of null dust are analyzed in detail. Smooth isometries of the metrics are briefly discussed. Furthermore, it is shown that the considered solutions are impulsive members of a more general family of radiative Kundt spacetimes of type-II. A straightforward generalization to impulsive waves in the anti-Nariai and Bertotti-Robinson backgrounds is described. For a vanishing cosmological constant and electromagnetic field, results for well known impulsive pp-waves are recovered.Comment: 9 pages, 4 figures, REVTeX 4. v3: added Appendix B, revised references, minor changes in the text. To appear in Phys. Rev.