Property control methods of diamond-like silicon-carbon films for micro- and nanoelectronics

Possible methods for controlling the properties of amorphous diamond-like silicon-carbon films are considered: physical or structural modification, chemical modification, and physical-chemical modification. It is shown that the method of physical modification allows controlling in a wide range the properties of diamondlike silicon-carbon films (electrophysical, mechanical properties and surface morphology) without changing the chemical composition of the material. Chemical modification was carried out by introducing transition metal into diamond-like silicon-carbon films. The dependences of the phase composition, electrophysical and mechanical properties on the content and type of metal are analyzed. The method of physical-chemical modification is considered, when the introduced impurity changes not only the chemical composition, but also the structure of the material

Indium selenide: An insight into electronic band structure and surface excitations

We have investigated the electronic response of single crystals of indium selenide by means of angle-resolved photoemission spectroscopy, electron energy loss spectroscopy and density functional theory. The loss spectrum of indium selenide shows the direct free exciton at similar to 1.3 eV and several other peaks, which do not exhibit dispersion with the momentum. The joint analysis of the experimental band structure and the density of states indicates that spectral features in the loss function are strictly related to single-particle transitions. These excitations cannot be considered as fully coherent plasmons and they are damped even in the optical limit, i.e. for small momenta. The comparison of the calculated symmetry-projected density of states with electron energy loss spectra enables the assignment of the spectral features to transitions between specific electronic states. Furthermore, the effects of ambient gases on the band structure and on the loss function have been probed

Spectromicroscopy of electronic phase separation in Kx_xFe2−y_{2-y}Se2_2 superconductor

Structural phase separation in A$_x$Fe$_{2-y}$Se$_2$ system has been studied by different experimental techniques, however, it should be important to know how the electronic uniformity is influenced, on which length scale the electronic phases coexist, and what is their spatial distribution. Here, we have used novel scanning photoelectron microscopy (SPEM) to study the electronic phase separation in K$_x$Fe$_{2-y}$Se$_2$, providing a direct measurement of the topological spatial distribution of the different electronic phases. The SPEM results reveal a peculiar interconnected conducting filamentary phase that is embedded in the insulating texture. The filamentary structure with a particular topological geometry could be important for the high T$_c$ superconductivity in the presence of a phase with a large magnetic moment in A$_x$Fe$_{2-y}$Se$_2$ materials.Comment: 14 pages,3 figure

Metallic phase in stoichiometric CeOBiS 2 revealed by space-resolved ARPES

Recently CeOBiS2 system without any fluorine doping is found to show superconductivity posing question on its origin. Using space resolved ARPES we have found a metallic phase embedded in the morphological defects and at the sample edges of stoichiometric CeOBiS2. While bulk of the sample is semiconducting, the embedded metallic phase is characterized by the usual electron pocket at X point, similar to the Fermi surface of doped BiS2-based superconductors. Typical size of the observed metallic domain is larger than the superconducting correlation length of the system suggesting that the observed superconductivity in undoped CeOBiS2 might be due to this embedded metallic phase at the defects. The results also suggest a possible way to develop new systems by manipulation of the defects in these chalcogenides with structural instability

Применение корреляционного метода определения скорости потока теплоносителя при исследованиях гидродинамики турбулентных потоков в элементах ядерных реакторов

The method of correlation measurement of the coolant flow rate, widely used for operational diagnostics of nuclear power plants, can be extensively used in research practice. The aim of this work was to apply a correlation method based on the conductometric measurement system with wire-mesh sensors for measuring a coolant flow rate. Insignificant concentration of a salt solution (NaCl or Na2SO4 ) creates a gradient of the conductivity in the flow, which is used as a passive scalar measured by the system. Authors used turbulent pulsations at the interface of two concurrent flows with identical velocities in a square channel as a signal source for the correlation method. The paper presents the methodology of the tests, test facility description, signalto- noise ratio estimation, the results of digital signal processing and comparison of the measured velocities in the model with the flowrate‒averaged velocity determined by the use of flowmeters. The measured velocity values give acceptable agreement for the turbulent flow modes. It was shown that the measurement accuracy drops sharply for low-Reynolds flows. The obtained results were used for flowrate measurements in core-imitator channels of the nuclear reactor test model. The presented paper is an approbation of this approach for its application as part of an test model of a nuclear reactor in order to determine the each duct flow rates in the channels of the core simulator using wire mesh sensors

Oxidation of methanol on Ru catalyst: Effect of the reagents partial pressures on the catalyst oxidation state and selectivity

In situ core level photoelectron spectroscopy and mass spectrometry have been utilized to study the methanol oxidation on a model RuO2 catalyst at pressures ranging from 10-6 to 10-1 mbar. The experiments were carried out varying the O2/CH3OH molecular mixing ratio from 0.25 to 3.3 and the reaction temperature from 350 to 720 K. The Ru 3d5/2 and O 1s core level spectra were used to characterise the dynamic changes in the Ru oxidation state by exposing the oxide pre-catalyst to different reagents partial pressures and temperatures. Full oxidation to CO2 + H2O or partial oxidation to CO + H2O + H2 have been observed in the whole pressure range for specific reaction conditions, which preserve the oxide catalyst state or reduce the oxide to metallic Ru. The selective oxidation to formaldehyde is observed only at pressures in the 10-1 mbar range, catalyzed by a RuO_x surface oxide formed by partial reduction of the oxide pre-catalyst

Strongly localized polaritons in an array of trapped two-level atoms interacting with a light field

We propose a new type of spatially periodic structure, i.e. polaritonic crystal (PolC), to observe a "slow"/"stopped" light phenomenon due to coupled atom-field states (polaritons) in a lattice. Under the tightbinding approximation, such a system realizes an array of weakly coupled trapped two-component atomic ensembles interacting with optical field in a tunnel-coupled one dimensional cavity array. We have shown that the phase transition to the superfluid Bardeen-Cooper-Schrieffer state, a so-called (BCS)-type state of low branch polaritons, occurs under the strong coupling condition. Such a transition results in the appearance of a macroscopic polarization of the atomic medium at non-zero frequency. The principal result is that the group velocity of polaritons depends essentially on the order parameter of the system, i.e. on the average photon number in the cavity array.Comment: 16 pages, 6 figure